
(a)
Interpretation:
The synthesis of given set of
Concept introduction:
- Cationic polymerization
- Radical polymerization
- Anionic polymerization
Cationic polymerization is the polymerization of the monomer (vinyl) with strong electron donating groups. In this method cationic initiator transfers charge to the monomer which becomes active and further propagates with another molecules.
Anionic polymerization is the polymerization of the monomer (vinyl) with strong electron attracting groups (electronegative groups). In this polymerization carbanion is the active species.
Radical polymerization is a type of polymerization where the reaction occurs by successive addition of free-radicals.
To identify: whether the given polymer can be achieved best via cationic addition or anionic addition
(b)
Interpretation:
The synthesis of given set of polymers can be achieved best via cationic addition or anionic addition should be determined.
Concept introduction:
Polymerization is a reaction when monomer molecules are reacted to form a polymer chain. Polymerization can occur via three ways,
- Cationic polymerization
- Radical polymerization
- Anionic polymerization
Cationic polymerization is the polymerization of the monomer (vinyl) with strong electron donating groups. In this method cationic initiator transfers charge to the monomer which becomes active and further propagates with another molecules.
Anionic polymerization is the polymerization of the monomer (vinyl) with strong electron attracting groups (electronegative groups). In this polymerization carbanion is the active species.
Radical polymerization is a type of polymerization where the reaction occurs by successive addition of free-radicals.
To identify: To identify whether the given polymer can be achieved best via cationic addition or anionic addition
(c)
Interpretation:
The synthesis of given set of polymers can be achieved best via cationic addition or anionic addition should be determined.
Concept introduction:
Polymerization is a reaction when monomer molecules are reacted to form a polymer chain. Polymerization can occur via three ways,
- Cationic polymerization
- Radical polymerization
- Anionic polymerization
Cationic polymerization is the polymerization of the monomer (vinyl) with strong electron donating groups. In this method cationic initiator transfers charge to the monomer which becomes active and further propagates with another molecules.
Anionic polymerization is the polymerization of the monomer (vinyl) with strong electron attracting groups (electronegative groups). In this polymerization carbanion is the active species.
Radical polymerization is a type of polymerization where the reaction occurs by successive addition of free-radicals.
To identify: whether the given polymer can be achieved best via cationic addition or anionic addition
(d)
Interpretation:
The synthesis of given set of polymers can be achieved best via cationic addition or anionic addition should be determined.
Concept introduction:
Polymerization is a reaction when monomer molecules are reacted to form a polymer chain. Polymerization can occur via three ways,
- Cationic polymerization
- Radical polymerization
- Anionic polymerization
Cationic polymerization is the polymerization of the monomer (vinyl) with strong electron donating groups. In this method cationic initiator transfers charge to the monomer which becomes active and further propagates with another molecules.
Anionic polymerization is the polymerization of the monomer (vinyl) with strong electron attracting groups (electronegative groups). In this polymerization carbanion is the active species.
Radical polymerization is a type of polymerization where the reaction occurs by successive addition of free-radicals.
To identify : whether the given polymer can be achieved best via cationic addition or anionic addition
(e)
Interpretation:
The synthesis of given set of polymers can be achieved best via cationic addition or anionic addition should be determined.
Concept introduction:
Polymerization is a reaction when monomer molecules are reacted to form a polymer chain. Polymerization can occur via three ways,
- Cationic polymerization
- Radical polymerization
- Anionic polymerization
Cationic polymerization is the polymerization of the monomer (vinyl) with strong electron donating groups. In this method cationic initiator transfers charge to the monomer which becomes active and further propagates with another molecules.
Anionic polymerization is the polymerization of the monomer (vinyl) with strong electron attracting groups (electronegative groups). In this polymerization carbanion is the active species.
Radical polymerization is a type of polymerization where the reaction occurs by successive addition of free-radicals.
To identify: whether the given polymer can be achieved best via cationic addition or anionic addition
(f)
Interpretation:
The synthesis of given set of polymers can be achieved best via cationic addition or anionic addition should be determined.
Concept introduction:
Polymerization is a reaction when monomer molecules are reacted to form a polymer chain. Polymerization can occur via three ways,
- Cationic polymerization
- Radical polymerization
- Anionic polymerization
Cationic polymerization is the polymerization of the monomer (vinyl) with strong electron donating groups. In this method cationic initiator transfers charge to the monomer which becomes active and further propagates with another molecules.
Anionic polymerization is the polymerization of the monomer (vinyl) with strong electron attracting groups (electronegative groups). In this polymerization carbanion is the active species.
Radical polymerization is a type of polymerization where the reaction occurs by successive addition of free-radicals.
To identify : To identify whether the given polymer can be achieved best via cationic addition or anionic addition

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Chapter 27 Solutions
ORGANIC CHEMISTRY-PRINT (LL)-W/WILEY
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- 5 What would the complete ionic reaction be if aqueous solutions of potassium sulfate and barium acetate were mixed? ed of Select one: O a 2 K SO4 + Ba2 +2 C₂H3O21 K+SO4 + Ba2+ + 2 C2H3O21 K+SO42 + Ba2 +2 C2H3O2 BaSO4 +2 K+ + 2 C2H3O estion Ob. O c. Od. 2 K SO4 +Ba2 +2 C₂H₂O₂ BaSO4 + K+ + 2 C2H3O BaSO4 + K + 2 C2H301 →Ba² +SO42 +2 KC2H3O s pagearrow_forward(28 pts.) 7. Propose a synthesis for each of the following transformations. You must include the reagents and product(s) for each step to receive full credit. The number of steps is provided. (OC 4) 4 steps 4 steps OH b.arrow_forwardLTS Solid: AT=Te-Ti Trial 1 Trial 2 Trial 3 Average ΔΗ Mass water, g 24.096 23.976 23.975 Moles of solid, mol 0.01763 001767 0101781 Temp. change, °C 2.9°C 11700 2.0°C Heat of reaction, J -292.37J -170.473 -193.26J AH, kJ/mole 16.58K 9.647 kJ 10.85 kr 16.58K59.64701 KJ mol 12.35k Minimum AS, J/mol K 41.582 mol-k Remember: q = mCsAT (m = mass of water, Cs=4.184J/g°C) & qsin =-qrxn & Show your calculations for: AH in J and then in kJ/mole for Trial 1: qa (24.0969)(4.1845/g) (-2.9°C)=-292.37J qsin = qrxn = 292.35 292.37J AH in J = 292.375 0.2923kJ 0.01763m01 =1.65×107 AH in kJ/mol = = 16.58K 0.01763mol mol qrx Minimum AS in J/mol K (Hint: use the average initial temperature of the three trials, con Kelvin.) AS=AHIT (1.65×10(9.64×103) + (1.0 Jimaiarrow_forward
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