Chemistry: Atoms First
3rd Edition
ISBN: 9781259638138
Author: Julia Burdge, Jason Overby Professor
Publisher: McGraw-Hill Education
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Chapter 2.7, Problem 3PPB
Calculate (a) the number of atoms in 1.05 × 10−6 mole of helium and (b) the number of moles of helium that contains 2.33 × 1021 atoms.
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5. A solution of sucrose is fermented in a vessel until the evolution of CO2 ceases. Then, the
product solution is analyzed and found to contain, 45% ethanol; 5% acetic acid; and 15%
glycerin by weight.
If the original charge is 500 kg, evaluate;
e. The ratio of sucrose to water in the original charge (wt/wt).
f. Moles of CO2 evolved.
g. Maximum possible amount of ethanol that could be formed.
h. Conversion efficiency.
i. Per cent excess of excess reactant.
Reactions:
Inversion reaction: C12H22O11 + H2O →2C6H12O6
Fermentation reaction: C6H12O6 →→2C2H5OH + 2CO2
Formation of acetic acid and glycerin: C6H12O6 + C2H5OH + H₂O→ CH3COOH + 2C3H8O3
Show work. don't give Ai generated solution. How many carbons and hydrogens are in the structure?
13. (11pts total) Consider the arrows pointing at three different carbon-carbon bonds in the
molecule depicted below.
Bond B
2°C. +2°C. cleavage
Bond A
•CH3 + 26.← Cleavage
2°C. +
Bond C
+3°C•
CH3 2C
Cleavage
E
2°C. 26.
weakest bond
Intact molecule
Strongest 3°C 20.
Gund
Largest
argest
a. (2pts) Which bond between A-C is weakest? Which is strongest? Place answers in
appropriate boxes.
C
Weakest
bond
A
Produces
Most
Bond
Strongest
Bond
Strongest Gund
produces least stable
radicals
Weakest
Stable radical
b. (4pts) Consider the relative stability of all cleavage products that form when bonds A,
B, AND C are homolytically cleaved/broken. Hint: cleavage products of bonds A, B,
and C are all carbon radicals.
i. Which ONE cleavage product is the most stable? A condensed or bond line
representation is fine.
13°C. formed in
bound C
cleavage
ii. Which ONE cleavage product is the least stable? A condensed or bond line
representation is fine.
• CH3
methyl radical
Formed in Gund A Cleavage
c.…
Chapter 2 Solutions
Chemistry: Atoms First
Ch. 2.3 - Determine the numbers of protons, neutrons, and...Ch. 2.3 - Prob. 1PPACh. 2.3 - Prob. 1PPBCh. 2.3 - Prob. 1PPCCh. 2.3 - Prob. 2.3.1SRCh. 2.3 - An atom with a mass number of 114 has 66 neutrons...Ch. 2.4 - Prob. 2.4.1SRCh. 2.4 - Prob. 2.4.2SRCh. 2.5 - Prob. 2.2WECh. 2.5 - Prob. 2PPA
Ch. 2.5 - The average atomic mass of nitrogen is 14.0067....Ch. 2.5 - Prob. 2PPCCh. 2.5 - Boron has two naturally occurring isotopes, 10B...Ch. 2.5 - The two naturally occurring isotopes of antimony,...Ch. 2.6 - Prob. 2.6.1SRCh. 2.6 - Prob. 2.6.2SRCh. 2.7 - Calcium is the most abundant metal in the human...Ch. 2.7 - Prob. 3PPACh. 2.7 - Calculate (a) the number of atoms in 1.05 106...Ch. 2.7 - Prob. 3PPCCh. 2.7 - Prob. 2.4WECh. 2.7 - Prob. 4PPACh. 2.7 - Prob. 4PPBCh. 2.7 - Prob. 4PPCCh. 2.7 - Prob. 2.5WECh. 2.7 - Prob. 5PPACh. 2.7 - Prob. 5PPBCh. 2.7 - Prob. 5PPCCh. 2.7 - Prob. 2.7.1SRCh. 2.7 - Prob. 2.7.2SRCh. 2.7 - Prob. 2.7.3SRCh. 2 - Define the terms atom and element.Ch. 2 - Use a familiar macroscopic example as an analogy...Ch. 2 - Prob. 2.3QPCh. 2 - Prob. 2.4QPCh. 2 - Prob. 2.5QPCh. 2 - Prob. 2.6QPCh. 2 - Describe the experimental basis for believing that...Ch. 2 - Prob. 2.8QPCh. 2 - Prob. 2.9QPCh. 2 - Prob. 2.10QPCh. 2 - Prob. 2.11QPCh. 2 - Prob. 2.12QPCh. 2 - Prob. 2.13QPCh. 2 - Prob. 2.14QPCh. 2 - Prob. 2.15QPCh. 2 - Prob. 2.16QPCh. 2 - Prob. 2.17QPCh. 2 - Prob. 2.18QPCh. 2 - Prob. 2.19QPCh. 2 - Determine the mass number of (a) a beryllium atom...Ch. 2 - Prob. 2.21QPCh. 2 - The following radioactive isotopes are used in...Ch. 2 - Prob. 2.23QPCh. 2 - Prob. 2.24QPCh. 2 - Prob. 2.25QPCh. 2 - Prob. 2.26QPCh. 2 - Prob. 2.27QPCh. 2 - Prob. 2.28QPCh. 2 - Prob. 2.29QPCh. 2 - In each pair of isotopes shown, indicate which one...Ch. 2 - What is the mass (in amu) of a carbon-12 atom? Why...Ch. 2 - Prob. 2.32QPCh. 2 - What information would you need to calculate the...Ch. 2 - Prob. 2.34QPCh. 2 - Prob. 2.35QPCh. 2 - Prob. 2.36QPCh. 2 - Prob. 2.37QPCh. 2 - The element rubidium has two naturally occurring...Ch. 2 - Prob. 2.39QPCh. 2 - Prob. 2.40QPCh. 2 - Prob. 2.41QPCh. 2 - Give two examples of each of the following: (a)...Ch. 2 - Prob. 2.43QPCh. 2 - Prob. 2.44QPCh. 2 - Describe the changes in properties (from metals to...Ch. 2 - Consult the WebElements Periodic Table of the...Ch. 2 - Group the following elements in pairs that you...Ch. 2 - Prob. 2.48QPCh. 2 - Prob. 2.49QPCh. 2 - Prob. 2.50QPCh. 2 - Prob. 2.51QPCh. 2 - Prob. 2.52QPCh. 2 - Prob. 2.53QPCh. 2 - Prob. 2.54QPCh. 2 - Prob. 2.55QPCh. 2 - Prob. 2.56QPCh. 2 - Prob. 2.57QPCh. 2 - Prob. 2.58QPCh. 2 - Prob. 2.59QPCh. 2 - Prob. 2.60QPCh. 2 - Prob. 2.61QPCh. 2 - Prob. 2.62QPCh. 2 - Prob. 2.63QPCh. 2 - Prob. 2.64QPCh. 2 - The element francium (Fr) was the last element of...Ch. 2 - Prob. 2.66QPCh. 2 - Prob. 2.67QPCh. 2 - Prob. 2.68QPCh. 2 - Prob. 2.69QPCh. 2 - Prob. 2.70QPCh. 2 - Discuss the significance of assigning an atomic...Ch. 2 - Prob. 2.72QPCh. 2 - Prob. 2.73QPCh. 2 - Prob. 2.74QPCh. 2 - Prob. 2.75QPCh. 2 - One atom of a particular element with only one...Ch. 2 - Identify each of the following elements: (a) a...Ch. 2 - Prob. 2.78QPCh. 2 - Prob. 2.79QPCh. 2 - Prob. 2.80QPCh. 2 - Prob. 2.81QPCh. 2 - Prob. 2.82QPCh. 2 - Prob. 2.83QPCh. 2 - Prob. 2.84QP
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