Organic Chemistry
Organic Chemistry
2nd Edition
ISBN: 9781118452288
Author: David R. Klein
Publisher: WILEY
Question
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Chapter 27, Problem 37PP
Interpretation Introduction

Interpretation:

The given monomer can be polymerized in both acidic and basic condition need to be explained.

Concept introduction:

Polymerization is a reaction when monomer molecules are reacted to form a polymer chain.  Polymerization can occur via three ways,

  • Cationic polymerization
  • Radical polymerization
  • Anionic polymerization

Cationic polymerization is the polymerization of the monomer (vinyl) with strong electron donating groups.  In this method cationic initiator transfers charge to the monomer which becomes active and further propagates with another molecules.

Anionic polymerization is the polymerization of the monomer (vinyl) with strong electron attracting groups (electronegative groups).  In this polymerization carbanion is the active species.

Radical polymerization is a type of polymerization where the reaction occurs by successive addition of free-radicals.

To explain: why the given compound undergoes polymerization in either acidic and basic conditions.

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