EBK ORGANIC CHEMISTRY AS A SECOND LANGU
EBK ORGANIC CHEMISTRY AS A SECOND LANGU
4th Edition
ISBN: 9781119234715
Author: Klein
Publisher: VST
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Chapter 26.8, Problem 4LTS
Interpretation Introduction

Interpretation:

Isoprene units in camphor need to be identified.

Concept introduction:

Terpenes are naturally occurring compounds which share a common feature.  All terpenes are thought to be assembled from isoprene units having five carbon atoms.  So the structure of terpenes has the carbon atoms in multiples of five only.

EBK ORGANIC CHEMISTRY AS A SECOND LANGU, Chapter 26.8, Problem 4LTS

The isoprene units are identified by following few steps namely,

  • Identify the number of isoprene units
  • Look for methyl group
  • Trial and error to find isoprene unit

To identify: the isoprene units in camphor

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20.33 Think-Pair-Share (a) Rank the following dienes and dienophiles in order of increasing reactivity in the Diels-Alder reaction. (i) CO₂Et (ii) COEt || CO₂Et MeO MeO (b) Draw the product that results from the most reactive diene and most reactive dienophile shown in part (a). (c) Draw a depiction of the orbital overlap involved in the pericyclic reaction that oc- curs between the diene and dienophile in part (b). (d) Is the major product formed in part (b) the endo or exo configuration? Explain your reasoning.
20.40 The following compound undergoes an intramolecular Diels-Alder reaction to give a tricyclic product. Propose a structural formula for the product. CN heat An intramolecular Diels-Alder adduct
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