CNCT ORG CHEM 6 2020
CNCT ORG CHEM 6 2020
6th Edition
ISBN: 9781266807244
Author: SMITH
Publisher: MCG
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Chapter 25.5, Problem 20P
Interpretation Introduction

Interpretation: The product formed on protonation of the intermediate enolate formed in anionic oxy-Cope rearrangement of given unsaturated alcohol is to be predicted.

Concept introduction: Anionic oxy-Cope rearrangement is a thermal [3,3] sigmatropic rearrangement. This rearrangement takes place in unsaturated alcohol to form more carbonyl compound.

Sigmatropic rearrangements are pericyclic reactions which takes place by concerted mechanism. In these rearrangements migration of sigma bond takes place.

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