Bond-line structure of given set of peptides need to be drawn. Concept introduction: Bond-line structure is the representation of organic structural formulas in a shorthand manner. In this case only the bond between carbon and other atoms are shown except hydrogen. It is understood that all the remaining valency to be filled by hydrogen. Apart from carbon atoms the other atoms are shown along with hydrogen. For drawing a peptide sequence in bond-line structure the steps need to be followed are, Draw the peptide with correct number of residues The side chain associated with the residue has to be identified Assign proper configuration for the residues To draw : bond-line structure of peptide Leu-Ala-Gly

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Answer 1

Question

Chapter 25.4, Problem 21PTS

(a)

Interpretation Introduction

Interpretation:

Bond-line structure of given set of peptides need to be drawn.

Concept introduction:

Bond-line structure is the representation of organic structural formulas in a shorthand manner. In this case only the bond between carbon and other atoms are shown except hydrogen. It is understood that all the remaining valency to be filled by hydrogen. Apart from carbon atoms the other atoms are shown along with hydrogen. For drawing a peptide sequence in bond-line structure the steps need to be followed are,

Draw the peptide with correct number of residues

The side chain associated with the residue has to be identified

Assign proper configuration for the residues

To draw: bond-line structure of peptide Leu-Ala-Gly

(b)

Interpretation Introduction

Interpretation:

Bond-line structure of given set of peptides need to be drawn.

Concept introduction:

Bond-line structure is the representation of organic structural formulas in a shorthand manner. In this case only the bond between carbon and other atoms are shown except hydrogen. It is understood that all the remaining valency to be filled by hydrogen. Apart from carbon atoms the other atoms are shown along with hydrogen. For drawing a peptide sequence in bond-line structure the steps need to be followed are,

Draw the peptide with correct number of residues

The side chain associated with the residue has to be identified

Assign proper configuration for the residues

To draw: bond-line structure of peptide Cys-Asp-Ala-Gly

(c)

Interpretation Introduction

Interpretation:

Bond-line structure of given set of peptides need to be drawn.

Concept introduction:

Bond-line structure is the representation of organic structural formulas in a shorthand manner. In this case only the bond between carbon and other atoms are shown except hydrogen. It is understood that all the remaining valency to be filled by hydrogen. Apart from carbon atoms the other atoms are shown along with hydrogen. For drawing a peptide sequence in bond-line structure the steps need to be followed are,

Draw the peptide with correct number of residues

The side chain associated with the residue has to be identified

Assign proper configuration for the residues

To draw: bond-line structure of peptide Met-Lys-His-Tyr-Ser-Phe-Val

Expert Solution & Answer

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2. Predict the NMR spectra for each of these two compounds by listing, in the NMR tables below, the chemical shift, the splitting, and the number of hydrogens associated with each predicted peak. Sort the peaks from largest chemical shift to lowest. **Not all slots must be filled** Peak Chemical Shift (d) 5.7 1 Multiplicity multiplate .......... 5.04 double of doublet 2 4.98 double of doublet 3 4.05 doublet of quartet 4 5 LO 3.80 quartet 1.3 doublet 6 Peak Chemical Shift (d) Multiplicity

Interpreting NMR spectra is a skill that often requires some amount of practice, which, in turn, necessitates access to a collection of NMR spectra. Beyond Labz Organic Synthesis and Organic Qualitative Analysis have spectral libraries containing over 700 1H NMR spectra. In this assignment, you will take advantage of this by first predicting the NMR spectra for two closely related compounds and then checking your predictions by looking up the actual spectra in the spectra library. After completing this assignment, you may wish to select other compounds for additional practice. 1. Write the IUPAC names for the following two structures: Question 2 Question 3 2. Predict the NMR spectra for each of these two compounds by listing, in the NMR tables below, the chemical shift, the splitting, and the number of hydrogens associated with each predicted peak. Sort the peaks from largest chemical shift to lowest. **Not all slots must be filled**

11:14 ... worksheets.beyondlabz.com 3. To check your predictions, click this link for Interpreting NMR Spectra 1. You will see a list of all the - compounds in the spectra library in alphabetical order by IUPAC name. Hovering over a name in the list will show the structure on the chalkboard. The four buttons on the top of the Spectra tab in the tray are used to select the different spectroscopic techniques for the selected compound. Make sure the NMR button has been selected. 4. Scroll through the list of names to find the names for the two compounds you have been given and click on the name to display the NMR spectrum for each. In the NMR tables below, list the chemical shift, the splitting, and the number of hydrogens associated with each peak for each compound. Compare your answers to your predictions. **Not all slots must be filled** Peak Chemical Shift (d) Multiplicity 1 2 3 4 5

Answer 2

Question

Chapter 25.4, Problem 21PTS

(a)

Interpretation Introduction

Interpretation:

Bond-line structure of given set of peptides need to be drawn.

Concept introduction:

Bond-line structure is the representation of organic structural formulas in a shorthand manner. In this case only the bond between carbon and other atoms are shown except hydrogen. It is understood that all the remaining valency to be filled by hydrogen. Apart from carbon atoms the other atoms are shown along with hydrogen. For drawing a peptide sequence in bond-line structure the steps need to be followed are,

Draw the peptide with correct number of residues

The side chain associated with the residue has to be identified

Assign proper configuration for the residues

To draw: bond-line structure of peptide Leu-Ala-Gly

(b)

Interpretation Introduction

Interpretation:

Bond-line structure of given set of peptides need to be drawn.

Concept introduction:

Bond-line structure is the representation of organic structural formulas in a shorthand manner. In this case only the bond between carbon and other atoms are shown except hydrogen. It is understood that all the remaining valency to be filled by hydrogen. Apart from carbon atoms the other atoms are shown along with hydrogen. For drawing a peptide sequence in bond-line structure the steps need to be followed are,

Draw the peptide with correct number of residues

The side chain associated with the residue has to be identified

Assign proper configuration for the residues

To draw: bond-line structure of peptide Cys-Asp-Ala-Gly

(c)

Interpretation Introduction

Interpretation:

Bond-line structure of given set of peptides need to be drawn.

Concept introduction:

Bond-line structure is the representation of organic structural formulas in a shorthand manner. In this case only the bond between carbon and other atoms are shown except hydrogen. It is understood that all the remaining valency to be filled by hydrogen. Apart from carbon atoms the other atoms are shown along with hydrogen. For drawing a peptide sequence in bond-line structure the steps need to be followed are,

Draw the peptide with correct number of residues

The side chain associated with the residue has to be identified

Assign proper configuration for the residues

To draw: bond-line structure of peptide Met-Lys-His-Tyr-Ser-Phe-Val

Expert Solution & Answer

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Check out a sample textbook solution

See solution

Answer 3

Question

Chapter 25.4, Problem 21PTS

(a)

Interpretation Introduction

Interpretation:

Bond-line structure of given set of peptides need to be drawn.

Concept introduction:

Bond-line structure is the representation of organic structural formulas in a shorthand manner. In this case only the bond between carbon and other atoms are shown except hydrogen. It is understood that all the remaining valency to be filled by hydrogen. Apart from carbon atoms the other atoms are shown along with hydrogen. For drawing a peptide sequence in bond-line structure the steps need to be followed are,

Draw the peptide with correct number of residues

The side chain associated with the residue has to be identified

Assign proper configuration for the residues

To draw: bond-line structure of peptide Leu-Ala-Gly

(b)

Interpretation Introduction

Interpretation:

Bond-line structure of given set of peptides need to be drawn.

Concept introduction:

Bond-line structure is the representation of organic structural formulas in a shorthand manner. In this case only the bond between carbon and other atoms are shown except hydrogen. It is understood that all the remaining valency to be filled by hydrogen. Apart from carbon atoms the other atoms are shown along with hydrogen. For drawing a peptide sequence in bond-line structure the steps need to be followed are,

Draw the peptide with correct number of residues

The side chain associated with the residue has to be identified

Assign proper configuration for the residues

To draw: bond-line structure of peptide Cys-Asp-Ala-Gly

(c)

Interpretation Introduction

Interpretation:

Bond-line structure of given set of peptides need to be drawn.

Concept introduction:

Bond-line structure is the representation of organic structural formulas in a shorthand manner. In this case only the bond between carbon and other atoms are shown except hydrogen. It is understood that all the remaining valency to be filled by hydrogen. Apart from carbon atoms the other atoms are shown along with hydrogen. For drawing a peptide sequence in bond-line structure the steps need to be followed are,

Draw the peptide with correct number of residues

The side chain associated with the residue has to be identified

Assign proper configuration for the residues

To draw: bond-line structure of peptide Met-Lys-His-Tyr-Ser-Phe-Val

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 4

Question

Chapter 25.4, Problem 21PTS

(a)

Interpretation Introduction

Interpretation:

Bond-line structure of given set of peptides need to be drawn.

Concept introduction:

Bond-line structure is the representation of organic structural formulas in a shorthand manner. In this case only the bond between carbon and other atoms are shown except hydrogen. It is understood that all the remaining valency to be filled by hydrogen. Apart from carbon atoms the other atoms are shown along with hydrogen. For drawing a peptide sequence in bond-line structure the steps need to be followed are,

Draw the peptide with correct number of residues

The side chain associated with the residue has to be identified

Assign proper configuration for the residues

To draw: bond-line structure of peptide Leu-Ala-Gly

(b)

Interpretation Introduction

Interpretation:

Bond-line structure of given set of peptides need to be drawn.

Concept introduction:

Bond-line structure is the representation of organic structural formulas in a shorthand manner. In this case only the bond between carbon and other atoms are shown except hydrogen. It is understood that all the remaining valency to be filled by hydrogen. Apart from carbon atoms the other atoms are shown along with hydrogen. For drawing a peptide sequence in bond-line structure the steps need to be followed are,

Draw the peptide with correct number of residues

The side chain associated with the residue has to be identified

Assign proper configuration for the residues

To draw: bond-line structure of peptide Cys-Asp-Ala-Gly

(c)

Interpretation Introduction

Interpretation:

Bond-line structure of given set of peptides need to be drawn.

Concept introduction:

Bond-line structure is the representation of organic structural formulas in a shorthand manner. In this case only the bond between carbon and other atoms are shown except hydrogen. It is understood that all the remaining valency to be filled by hydrogen. Apart from carbon atoms the other atoms are shown along with hydrogen. For drawing a peptide sequence in bond-line structure the steps need to be followed are,

Draw the peptide with correct number of residues

The side chain associated with the residue has to be identified

Assign proper configuration for the residues

To draw: bond-line structure of peptide Met-Lys-His-Tyr-Ser-Phe-Val

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 5

Chapter 25.4, Problem 21PTS

(a)

Interpretation Introduction

Interpretation:

Bond-line structure of given set of peptides need to be drawn.

Concept introduction:

Bond-line structure is the representation of organic structural formulas in a shorthand manner. In this case only the bond between carbon and other atoms are shown except hydrogen. It is understood that all the remaining valency to be filled by hydrogen. Apart from carbon atoms the other atoms are shown along with hydrogen. For drawing a peptide sequence in bond-line structure the steps need to be followed are,

Draw the peptide with correct number of residues

The side chain associated with the residue has to be identified

Assign proper configuration for the residues

To draw: bond-line structure of peptide Leu-Ala-Gly

(b)

Interpretation Introduction

Interpretation:

Bond-line structure of given set of peptides need to be drawn.

Concept introduction:

Bond-line structure is the representation of organic structural formulas in a shorthand manner. In this case only the bond between carbon and other atoms are shown except hydrogen. It is understood that all the remaining valency to be filled by hydrogen. Apart from carbon atoms the other atoms are shown along with hydrogen. For drawing a peptide sequence in bond-line structure the steps need to be followed are,

Draw the peptide with correct number of residues

The side chain associated with the residue has to be identified

Assign proper configuration for the residues

To draw: bond-line structure of peptide Cys-Asp-Ala-Gly

(c)

Interpretation Introduction

Interpretation:

Bond-line structure of given set of peptides need to be drawn.

Concept introduction:

Bond-line structure is the representation of organic structural formulas in a shorthand manner. In this case only the bond between carbon and other atoms are shown except hydrogen. It is understood that all the remaining valency to be filled by hydrogen. Apart from carbon atoms the other atoms are shown along with hydrogen. For drawing a peptide sequence in bond-line structure the steps need to be followed are,

Draw the peptide with correct number of residues

The side chain associated with the residue has to be identified

Assign proper configuration for the residues

To draw: bond-line structure of peptide Met-Lys-His-Tyr-Ser-Phe-Val

Answer 6

Chapter 25.4, Problem 21PTS

(a)

Interpretation Introduction

Interpretation:

Bond-line structure of given set of peptides need to be drawn.

Concept introduction:

Bond-line structure is the representation of organic structural formulas in a shorthand manner. In this case only the bond between carbon and other atoms are shown except hydrogen. It is understood that all the remaining valency to be filled by hydrogen. Apart from carbon atoms the other atoms are shown along with hydrogen. For drawing a peptide sequence in bond-line structure the steps need to be followed are,

Draw the peptide with correct number of residues

The side chain associated with the residue has to be identified

Assign proper configuration for the residues

To draw: bond-line structure of peptide Leu-Ala-Gly

Answer 7

Chapter 25.4, Problem 21PTS

(a)

Interpretation Introduction

Interpretation:

Bond-line structure of given set of peptides need to be drawn.

Concept introduction:

Bond-line structure is the representation of organic structural formulas in a shorthand manner. In this case only the bond between carbon and other atoms are shown except hydrogen. It is understood that all the remaining valency to be filled by hydrogen. Apart from carbon atoms the other atoms are shown along with hydrogen. For drawing a peptide sequence in bond-line structure the steps need to be followed are,

Draw the peptide with correct number of residues

The side chain associated with the residue has to be identified

Assign proper configuration for the residues

To draw: bond-line structure of peptide Leu-Ala-Gly

Answer 8

(b)

Interpretation Introduction

Interpretation:

Bond-line structure of given set of peptides need to be drawn.

Concept introduction:

Bond-line structure is the representation of organic structural formulas in a shorthand manner. In this case only the bond between carbon and other atoms are shown except hydrogen. It is understood that all the remaining valency to be filled by hydrogen. Apart from carbon atoms the other atoms are shown along with hydrogen. For drawing a peptide sequence in bond-line structure the steps need to be followed are,

Draw the peptide with correct number of residues

The side chain associated with the residue has to be identified

Assign proper configuration for the residues

To draw: bond-line structure of peptide Cys-Asp-Ala-Gly

Answer 9

(b)

Interpretation Introduction

Interpretation:

Bond-line structure of given set of peptides need to be drawn.

Concept introduction:

Bond-line structure is the representation of organic structural formulas in a shorthand manner. In this case only the bond between carbon and other atoms are shown except hydrogen. It is understood that all the remaining valency to be filled by hydrogen. Apart from carbon atoms the other atoms are shown along with hydrogen. For drawing a peptide sequence in bond-line structure the steps need to be followed are,

Draw the peptide with correct number of residues

The side chain associated with the residue has to be identified

Assign proper configuration for the residues

To draw: bond-line structure of peptide Cys-Asp-Ala-Gly

Answer 10

(c)

Interpretation Introduction

Interpretation:

Bond-line structure of given set of peptides need to be drawn.

Concept introduction:

Bond-line structure is the representation of organic structural formulas in a shorthand manner. In this case only the bond between carbon and other atoms are shown except hydrogen. It is understood that all the remaining valency to be filled by hydrogen. Apart from carbon atoms the other atoms are shown along with hydrogen. For drawing a peptide sequence in bond-line structure the steps need to be followed are,

Draw the peptide with correct number of residues

The side chain associated with the residue has to be identified

Assign proper configuration for the residues

To draw: bond-line structure of peptide Met-Lys-His-Tyr-Ser-Phe-Val

Answer 11

(c)

Interpretation Introduction

Interpretation:

Bond-line structure of given set of peptides need to be drawn.

Concept introduction:

Bond-line structure is the representation of organic structural formulas in a shorthand manner. In this case only the bond between carbon and other atoms are shown except hydrogen. It is understood that all the remaining valency to be filled by hydrogen. Apart from carbon atoms the other atoms are shown along with hydrogen. For drawing a peptide sequence in bond-line structure the steps need to be followed are,

Draw the peptide with correct number of residues

The side chain associated with the residue has to be identified

Assign proper configuration for the residues

To draw: bond-line structure of peptide Met-Lys-His-Tyr-Ser-Phe-Val

Answer 12

Expert Solution & Answer

Answer 13

Expert Solution & Answer

Answer 14

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Check out a sample textbook solution

See solution

Answer 15

Ch. 25.2 - Prob. 1CC Ch. 25.2 - Prob. 2CC Ch. 25.2 - Prob. 3CC Ch. 25.2 - Prob. 1LTS Ch. 25.2 - Prob. 4PTS Ch. 25.2 - Prob. 7CC Ch. 25.2 - Prob. 8CC Ch. 25.2 - Prob. 9CC Ch. 25.2 - Prob. 10CC Ch. 25.2 - Prob. 11CC

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Chapter 25 Solutions