ORGANIC CHEMISTRY-ACCESS
ORGANIC CHEMISTRY-ACCESS
6th Edition
ISBN: 9781260475586
Author: SMITH
Publisher: MCG
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Chapter 25.3, Problem 8P
Interpretation Introduction

Interpretation: The structure of provitamin D3 is to be drawn.

Concept introduction: Electrocyclic reactions involve the conversion of σ bonds into π bonds or π bonds into σ bonds. These reactions can take place in photochemical and as well as thermal conditions. The photochemical and thermal reactions take place in the presence of light and heat respectively.

Curved arrows aid in determining the movement and flow of electrons in the reaction. The electrons that take part in the chemical reactions are shown by the curved arrows.

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What would be the best choices for the missing reagents 1 and 3 in this synthesis? 1. PPh3 3 2. n-BuLi • Draw the missing reagents in the drawing area below. You can draw them in any arrangement you like. • Do not draw the missing reagent 2. If you draw 1 correctly, we'll know what it is. • Note: if one of your reagents needs to contain a halogen, use bromine. Click and drag to start drawing a structure.
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