Chemistry & Chemical Reactivity, Hybrid Edition (with OWLv2 24-Months Printed Access Card)
9th Edition
ISBN: 9781285462530
Author: John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher: Cengage Learning
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Question
Chapter 25.3, Problem 1RC
Interpretation Introduction
Interpretation:
The highest binding energy per nucleon should be identified.
Concept introduction:
Binding energy can be calculated by using following formula,
C – velocity of light.
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A solution contains 0.097 M Ce3+, 1.55x10-3 M Ce4+, 1.55x10-3 M Mn2+, 0.097 M MnO4-, and 1.00 M HClO4 (F= 9.649 x 104 C/mol).
a) Write a balanced net reaction that can occur between species in this solution.
b) Calculate deltaG0 and K for the reaction.
c) Calculate E and deltaG for the conditions given.
Ce4+ + e- = Ce3+ E0= 1.70 V
MnO4- + 8H+ + 5e- = Mn2+ + 4H2O E0= 1.507 V
1. Provide a step-by-step mechanism for formation of ALL STEREOISOMERS in
the following reaction.
Na HCO3 (Sodium bicarbonate, baking soda) is not soluble in CH2Cl2. The powder is
a weak base used to neutralize strong acid (pKa < 0) produced by the reaction.
Redraw the product to show the configuration(s) that form at C-2 and C-4.
Br2
OH
CH2Cl2
Na* HCO3
Br
HO
OH
+ Na Br +
2. Specify the solvent and reagent(s) required to carry out each of the following FGI. If
two reagent sets must be used for the FGI, specify the solvent and reagent(s) for each
reagent set. If a reaction cannot be carried out with reagents (sets)
class, write NP (not possible) in the solvent box for reagent set #1.
Use the letter abbreviation for each solvent; use a number abbreviation for reagent(s).
Solvents: CH2Cl2 (A);
H₂O (B);
Reagents:
HBr (1);
R₂BH (6);
H2SO4 (2);
CH3OH (C);
Br₂ (3);
CH3CO₂H (D)
NaHCO3 (4);
Hg(OAc)2 (5);
H₂O2/HO (7);
NaBH4 (8)
Reagent Set #1
Reagent Set #2
FGI
+ enant
OH
Solvent Reagent(s) Solvent Reagent(s)
Chapter 25 Solutions
Chemistry & Chemical Reactivity, Hybrid Edition (with OWLv2 24-Months Printed Access Card)
Ch. 25.2 - Prob. 1CYUCh. 25.2 - Prob. 2CYUCh. 25.2 - Prob. 1RCCh. 25.2 - Prob. 2RCCh. 25.2 - Prob. 3RCCh. 25.3 - Prob. 1CYUCh. 25.3 - Prob. 2CYUCh. 25.3 - Prob. 1RCCh. 25.4 - Prob. 1CYUCh. 25.4 - Prob. 2CYU
Ch. 25.4 - Prob. 3CYUCh. 25.4 - Prob. 1RCCh. 25.4 - Prob. 2RCCh. 25.5 - Prob. 1CYUCh. 25.5 - Prob. 1RCCh. 25.6 - Prob. 1RCCh. 25.9 - Prob. 1CYUCh. 25.9 - Prob. 1QCh. 25.9 - Prob. 2QCh. 25.9 - Prob. 3QCh. 25.9 - Prob. 4QCh. 25.9 - Prob. 5QCh. 25.9 - Prob. 6QCh. 25.A - Prob. 1QCh. 25.A - Prob. 2QCh. 25.A - Prob. 3QCh. 25.A - Prob. 4QCh. 25 - Prob. 1PSCh. 25 - Prob. 4PSCh. 25 - Prob. 5PSCh. 25 - Prob. 6PSCh. 25 - Prob. 7PSCh. 25 - Prob. 8PSCh. 25 - Prob. 9PSCh. 25 - Prob. 11PSCh. 25 - Prob. 12PSCh. 25 - Prob. 13PSCh. 25 - Prob. 14PSCh. 25 - Prob. 15PSCh. 25 - Prob. 16PSCh. 25 - Prob. 17PSCh. 25 - Prob. 18PSCh. 25 - Prob. 19PSCh. 25 - Prob. 20PSCh. 25 - Prob. 21PSCh. 25 - Prob. 22PSCh. 25 - Prob. 23PSCh. 25 - Prob. 24PSCh. 25 - Prob. 25PSCh. 25 - Prob. 26PSCh. 25 - Prob. 27PSCh. 25 - Prob. 28PSCh. 25 - Prob. 29PSCh. 25 - Prob. 30PSCh. 25 - Prob. 31PSCh. 25 - Prob. 32PSCh. 25 - Prob. 33PSCh. 25 - Prob. 34PSCh. 25 - Prob. 35PSCh. 25 - Prob. 36PSCh. 25 - Prob. 37PSCh. 25 - Prob. 38PSCh. 25 - Prob. 39PSCh. 25 - Prob. 40PSCh. 25 - Prob. 41PSCh. 25 - Prob. 42PSCh. 25 - Prob. 43PSCh. 25 - Prob. 44PSCh. 25 - Prob. 45PSCh. 25 - Some of the reactions explored by Ernest...Ch. 25 - Prob. 47GQCh. 25 - Prob. 48GQCh. 25 - Prob. 49GQCh. 25 - Prob. 50GQCh. 25 - Prob. 51GQCh. 25 - Prob. 52GQCh. 25 - Prob. 53GQCh. 25 - Prob. 54GQCh. 25 - Prob. 55ILCh. 25 - Prob. 56ILCh. 25 - Prob. 57ILCh. 25 - Prob. 58ILCh. 25 - Prob. 59ILCh. 25 - Prob. 60ILCh. 25 - Prob. 61SCQCh. 25 - Prob. 62SCQCh. 25 - Prob. 63SCQCh. 25 - Prob. 64SCQCh. 25 - Prob. 66SCQCh. 25 - Prob. 67SCQCh. 25 - Prob. 68SCQCh. 25 - Prob. 69SCQ
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- 2. Specify the solvent and reagent(s) required to carry out each of the following FGI. If two reagent sets must be used for the FGI, specify the solvent and reagent(s) for each reagent set. If a reaction cannot be carried out with reagents (sets) class, write NP (not possible) in the solvent box for reagent set #1. Use the letter abbreviation for each solvent; use a number abbreviation for reagent(s). Solvents: CH2Cl2 (A); Reagents: H₂O (B); CH3CO₂H (D) NaHCO3 (4); Hg(OAc)2 (5); HBr (1); R₂BH (6); H2SO4 (2); CH3OH (C); Br₂ (3); H₂O₂ / HO- (7); NaBH4 (8) Reagent Set #1 Reagent Set #2 FGI OH - α-α Br + enant Solvent Reagent(s) Solvent Reagent(s)arrow_forwardBased on concepts from Lecture 3-5, which of the following ionic compounds should be most soluble in water? Group of answer choices MgO BeO CaO BaOarrow_forwardFrom an energy standpoint, which two process - in the correct order - are involved in the dissolving of an ionic compound crystal? Group of answer choices Water coordination to the ions followed by sublimation into the gas phase Sublimation of the crystal into gas-phase ions followed by water coordination to the ions Ion dissociation from the crystal followed by water coordination to the ions Water coordination to the ions followed by ion dissociation from the crystalarrow_forward
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