Modified Mastering Chemistry with Pearson eText -- Standalone Access Card -- for Chemistry: A Molecular Approach (4th Edition)
Modified Mastering Chemistry with Pearson eText -- Standalone Access Card -- for Chemistry: A Molecular Approach (4th Edition)
4th Edition
ISBN: 9780134162430
Author: Nivaldo J. Tro
Publisher: PEARSON
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Coordination Chemistry
It is a part of chemistry, in which the study of compounds that have central atoms surrounded by molecules or ions, known as ligand, is known as coordination chemistry.
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Chapter 25, Problem 72E
Interpretation Introduction

Interpretation: The reason why Ni(NH3)4]2+ is paramagnetic, while [Ni(CN)4]2– is diamagnetic is to be explained.

Concept Introduction: The strength of the crystal field can affects the magnetic properties of the complex ions.

Strong field ligands produce large amount of crystal field splitting energy, Δ which is less than the pairing energy, thereby pairing of electrons takes place and hence, the complex ion would be diamagnetic.

Weak field ligands produce small amount of crystal field splitting energy, Δ which is more than the pairing energy, thereby pairing of electrons does not takes place and hence, the complex ion would be paramagnetic.

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Chapter 25 Solutions

Modified Mastering Chemistry with Pearson eText -- Standalone Access Card -- for Chemistry: A Molecular Approach (4th Edition)

Ch. 25 - Prob. 1SAQCh. 25 - Q2. Which metal has the highest first ionization...Ch. 25 - Prob. 3SAQCh. 25 - Prob. 4SAQCh. 25 - Prob. 5SAQCh. 25 - Prob. 6SAQCh. 25 - Prob. 7SAQCh. 25 - Prob. 8SAQCh. 25 - Prob. 9SAQCh. 25 - Prob. 10SAQ
Ch. 25 - Prob. 1ECh. 25 - Prob. 2ECh. 25 - 3. Why is the +2 oxidation state so common for...Ch. 25 - 4. Explain why atomic radii of elements in the...Ch. 25 - 5. Gold is the most electronegative transition...Ch. 25 - Prob. 6ECh. 25 - Prob. 7ECh. 25 - Prob. 8ECh. 25 - Prob. 9ECh. 25 - Prob. 10ECh. 25 - Prob. 11ECh. 25 - Prob. 12ECh. 25 - Prob. 13ECh. 25 - Prob. 14ECh. 25 - Prob. 15ECh. 25 - Prob. 16ECh. 25 - 17. Write the ground state electron configuration...Ch. 25 - 18. Write the ground state electron configuration...Ch. 25 - Prob. 19ECh. 25 - Prob. 20ECh. 25 - Prob. 21ECh. 25 - Prob. 22ECh. 25 - Prob. 23ECh. 25 - Prob. 24ECh. 25 - Prob. 25ECh. 25 - Prob. 26ECh. 25 - Prob. 27ECh. 25 - Prob. 28ECh. 25 - Prob. 29ECh. 25 - Prob. 30ECh. 25 - Prob. 31ECh. 25 - Prob. 32ECh. 25 - Prob. 33ECh. 25 - Prob. 34ECh. 25 - Prob. 35ECh. 25 - Prob. 36ECh. 25 - Prob. 37ECh. 25 - Prob. 38ECh. 25 - Prob. 39ECh. 25 - Prob. 40ECh. 25 - Prob. 41ECh. 25 - Prob. 42ECh. 25 - Prob. 43ECh. 25 - Prob. 44ECh. 25 - Prob. 45ECh. 25 - Prob. 46ECh. 25 - Prob. 47ECh. 25 - Prob. 48ECh. 25 - Prob. 49ECh. 25 - Prob. 50ECh. 25 - Prob. 51ECh. 25 - Prob. 52ECh. 25 - Prob. 53ECh. 25 - Prob. 54ECh. 25 - Prob. 55ECh. 25 - Prob. 56ECh. 25 - 57. Recall from Chapter 8 that Cr and Cu are...Ch. 25 - 58. Most of the second row transition metals do...Ch. 25 - Prob. 59ECh. 25 - Prob. 60ECh. 25 - Prob. 61ECh. 25 - Prob. 62ECh. 25 - Prob. 63ECh. 25 - Prob. 64ECh. 25 - Prob. 65ECh. 25 - Prob. 66ECh. 25 - Prob. 67ECh. 25 - Prob. 68ECh. 25 - 69. When a solution of PtCl2 reacts with the...Ch. 25 - Prob. 70ECh. 25 - Prob. 71ECh. 25 - Prob. 72ECh. 25 - Prob. 73ECh. 25 - Prob. 74ECh. 25 - Prob. 75ECh. 25 - Prob. 76ECh. 25 - Prob. 77ECh. 25 - Prob. 78ECh. 25 - 79. Which element has the higher ionization...Ch. 25 - Prob. 80ECh. 25 - Prob. 81QGWCh. 25 - Prob. 82QGWCh. 25 - Prob. 83QGWCh. 25 - Prob. 84QGWCh. 25 - Prob. 85QGWCh. 25 - Prob. 86DIA
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