Chemistry: A Molecular Approach Selected Solutions Manual, Books a la Carte Edition
Chemistry: A Molecular Approach Selected Solutions Manual, Books a la Carte Edition
4th Edition
ISBN: 9780134554259
Author: Nivaldo J. Tro
Publisher: PEARSON
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Chapter 25, Problem 42E
Interpretation Introduction

Interpretation: The octahedral crystal field splitting diagram for each of the given metal ion is to be drawn.

Concept Introduction: In octahedral complexes the dxy,dyz,dxz orbitals have same energy while dz2anddx2y2 have same energy. Electrons are filled in orbitals of equivalent energy in an aufbau manner but for the configurations, d4d7 there are two possible filling schemes depending on the magnitude of splitting field energy relative to the mean pairing energy, P.

• The metal ions with d4,d5,d6 and d7 configuration have low-spin and high-spin possibilities.

• As there are three lower-energy d-orbitals, the d1,d2andd3 metal ions have unpaired electrons.

• The metal ions with d8,d9andd10 configuration have completely filled three lower energy orbitals, thus, the remaining electrons fill the two higher energy orbitals (in accordance to Hund's rule).

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Chapter 25 Solutions

Chemistry: A Molecular Approach Selected Solutions Manual, Books a la Carte Edition

Ch. 25 - Prob. 1ECh. 25 - Prob. 2ECh. 25 - 3. Why is the +2 oxidation state so common for...Ch. 25 - 4. Explain why atomic radii of elements in the...Ch. 25 - 5. Gold is the most electronegative transition...Ch. 25 - Prob. 6ECh. 25 - Prob. 7ECh. 25 - Prob. 8ECh. 25 - Prob. 9ECh. 25 - Prob. 10ECh. 25 - Prob. 11ECh. 25 - Prob. 12ECh. 25 - Prob. 13ECh. 25 - Prob. 14ECh. 25 - Prob. 15ECh. 25 - Prob. 16ECh. 25 - 17. Write the ground state electron configuration...Ch. 25 - 18. Write the ground state electron configuration...Ch. 25 - Prob. 19ECh. 25 - Prob. 20ECh. 25 - Prob. 21ECh. 25 - Prob. 22ECh. 25 - Prob. 23ECh. 25 - Prob. 24ECh. 25 - Prob. 25ECh. 25 - Prob. 26ECh. 25 - Prob. 27ECh. 25 - Prob. 28ECh. 25 - Prob. 29ECh. 25 - Prob. 30ECh. 25 - Prob. 31ECh. 25 - Prob. 32ECh. 25 - Prob. 33ECh. 25 - Prob. 34ECh. 25 - Prob. 35ECh. 25 - Prob. 36ECh. 25 - Prob. 37ECh. 25 - Prob. 38ECh. 25 - Prob. 39ECh. 25 - Prob. 40ECh. 25 - Prob. 41ECh. 25 - Prob. 42ECh. 25 - Prob. 43ECh. 25 - Prob. 44ECh. 25 - Prob. 45ECh. 25 - Prob. 46ECh. 25 - Prob. 47ECh. 25 - Prob. 48ECh. 25 - Prob. 49ECh. 25 - Prob. 50ECh. 25 - Prob. 51ECh. 25 - Prob. 52ECh. 25 - Prob. 53ECh. 25 - Prob. 54ECh. 25 - Prob. 55ECh. 25 - Prob. 56ECh. 25 - 57. Recall from Chapter 8 that Cr and Cu are...Ch. 25 - 58. Most of the second row transition metals do...Ch. 25 - Prob. 59ECh. 25 - Prob. 60ECh. 25 - Prob. 61ECh. 25 - Prob. 62ECh. 25 - Prob. 63ECh. 25 - Prob. 64ECh. 25 - Prob. 65ECh. 25 - Prob. 66ECh. 25 - Prob. 67ECh. 25 - Prob. 68ECh. 25 - 69. When a solution of PtCl2 reacts with the...Ch. 25 - Prob. 70ECh. 25 - Prob. 71ECh. 25 - Prob. 72ECh. 25 - Prob. 73ECh. 25 - Prob. 74ECh. 25 - Prob. 75ECh. 25 - Prob. 76ECh. 25 - Prob. 77ECh. 25 - Prob. 78ECh. 25 - 79. Which element has the higher ionization...Ch. 25 - Prob. 80ECh. 25 - Prob. 81QGWCh. 25 - Prob. 82QGWCh. 25 - Prob. 83QGWCh. 25 - Prob. 84QGWCh. 25 - Prob. 85QGWCh. 25 - Prob. 86DIA
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