Connect Online Access 1-Semester for Organic Chemistry
Connect Online Access 1-Semester for Organic Chemistry
6th Edition
ISBN: 9781260475609
Author: SMITH, Janice
Publisher: Mcgraw-hill Higher Education (us)
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Chapter 25, Problem 41P
Interpretation Introduction

Interpretation: The preparation of X from a constitutional isomer by a series of [2+2] cycloaddition reaction is to be predicted.

Concept introduction: Curved arrows aid in determining the movement and flow of electrons in the reaction. The electrons that take part in the chemical reactions are shown by the curved arrows.

Electrocyclic reactions involve the conversion of σ bonds into π bonds or π bonds into σ bonds.

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Calculate the packing factor of CaTiO3. It has a perovskite structure. Data: ionic radii Co²+ = 0.106 nm, Ti4+ = 0.064 nm, O² = 0.132 nm; lattice constant is a = 2(rTi4+ + ro2-). Ca2+ 02- T14+ Consider the ions as rigid spheres. 1. 0.581 or 58.1% 2. -0.581 or -58.1 % 3. 0.254 or 25.4%
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