The number of geometric isomers present in each of the given ions are to be listed. a. square planar [NiWXYZ] 2+ b. tetrahedral [ZnWXYZ] 2+ Concept Introduction: Geometrical isomerism is a type of stereoisomerism that results when the ligands bonded to the metal have a different spatial arrangement. Geometrical isomerism (cis–trans isomerism) occurs in the square planar complexes of the type M A 2 B 2 and octahedral complexes of the M A 4 B 2 . Geometrical isomerism does not occur in tetrahedral complexes because all the bond angles around the central metal are 109.5 ° and each comer of a tetrahedron can be considered to be adjacent to all other corners. Similarly, a linear complex cannot exhibit cis–trans isomerism.

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Answer 1

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Chapter 25, Problem 35E

Interpretation Introduction

Interpretation: The number of geometric isomers present in each of the given ions are to be listed.

a. square planar [NiWXYZ]²⁺

b. tetrahedral [ZnWXYZ]²⁺

Concept Introduction: Geometrical isomerism is a type of stereoisomerism that results when the ligands bonded to the metal have a different spatial arrangement. Geometrical isomerism (cis–trans isomerism) occurs in the square planar complexes of the type MA2B2 and octahedral complexes of the MA4B2. Geometrical isomerism does not occur in tetrahedral complexes because all the bond angles around the central metal are 109.5° and each comer of a tetrahedron can be considered to be adjacent to all other corners. Similarly, a linear complex cannot exhibit cis–trans isomerism.

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Answer 2

Question

Chapter 25, Problem 35E

Interpretation Introduction

Interpretation: The number of geometric isomers present in each of the given ions are to be listed.

a. square planar [NiWXYZ]²⁺

b. tetrahedral [ZnWXYZ]²⁺

Concept Introduction: Geometrical isomerism is a type of stereoisomerism that results when the ligands bonded to the metal have a different spatial arrangement. Geometrical isomerism (cis–trans isomerism) occurs in the square planar complexes of the type MA2B2 and octahedral complexes of the MA4B2. Geometrical isomerism does not occur in tetrahedral complexes because all the bond angles around the central metal are 109.5° and each comer of a tetrahedron can be considered to be adjacent to all other corners. Similarly, a linear complex cannot exhibit cis–trans isomerism.

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Answer 3

Question

Chapter 25, Problem 35E

Interpretation Introduction

Interpretation: The number of geometric isomers present in each of the given ions are to be listed.

a. square planar [NiWXYZ]²⁺

b. tetrahedral [ZnWXYZ]²⁺

Concept Introduction: Geometrical isomerism is a type of stereoisomerism that results when the ligands bonded to the metal have a different spatial arrangement. Geometrical isomerism (cis–trans isomerism) occurs in the square planar complexes of the type MA2B2 and octahedral complexes of the MA4B2. Geometrical isomerism does not occur in tetrahedral complexes because all the bond angles around the central metal are 109.5° and each comer of a tetrahedron can be considered to be adjacent to all other corners. Similarly, a linear complex cannot exhibit cis–trans isomerism.

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Answer 4

Question

Chapter 25, Problem 35E

Interpretation Introduction

Interpretation: The number of geometric isomers present in each of the given ions are to be listed.

a. square planar [NiWXYZ]²⁺

b. tetrahedral [ZnWXYZ]²⁺

Concept Introduction: Geometrical isomerism is a type of stereoisomerism that results when the ligands bonded to the metal have a different spatial arrangement. Geometrical isomerism (cis–trans isomerism) occurs in the square planar complexes of the type MA2B2 and octahedral complexes of the MA4B2. Geometrical isomerism does not occur in tetrahedral complexes because all the bond angles around the central metal are 109.5° and each comer of a tetrahedron can be considered to be adjacent to all other corners. Similarly, a linear complex cannot exhibit cis–trans isomerism.

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Answer 5

Chapter 25, Problem 35E

Interpretation Introduction

Interpretation: The number of geometric isomers present in each of the given ions are to be listed.

a. square planar [NiWXYZ]²⁺

b. tetrahedral [ZnWXYZ]²⁺

Concept Introduction: Geometrical isomerism is a type of stereoisomerism that results when the ligands bonded to the metal have a different spatial arrangement. Geometrical isomerism (cis–trans isomerism) occurs in the square planar complexes of the type MA2B2 and octahedral complexes of the MA4B2. Geometrical isomerism does not occur in tetrahedral complexes because all the bond angles around the central metal are 109.5° and each comer of a tetrahedron can be considered to be adjacent to all other corners. Similarly, a linear complex cannot exhibit cis–trans isomerism.

Answer 6

Chapter 25, Problem 35E

Interpretation Introduction

Interpretation: The number of geometric isomers present in each of the given ions are to be listed.

a. square planar [NiWXYZ]²⁺

b. tetrahedral [ZnWXYZ]²⁺

Concept Introduction: Geometrical isomerism is a type of stereoisomerism that results when the ligands bonded to the metal have a different spatial arrangement. Geometrical isomerism (cis–trans isomerism) occurs in the square planar complexes of the type MA2B2 and octahedral complexes of the MA4B2. Geometrical isomerism does not occur in tetrahedral complexes because all the bond angles around the central metal are 109.5° and each comer of a tetrahedron can be considered to be adjacent to all other corners. Similarly, a linear complex cannot exhibit cis–trans isomerism.

Answer 7

Chapter 25, Problem 35E

Interpretation Introduction

Interpretation: The number of geometric isomers present in each of the given ions are to be listed.

a. square planar [NiWXYZ]²⁺

b. tetrahedral [ZnWXYZ]²⁺

Concept Introduction: Geometrical isomerism is a type of stereoisomerism that results when the ligands bonded to the metal have a different spatial arrangement. Geometrical isomerism (cis–trans isomerism) occurs in the square planar complexes of the type MA2B2 and octahedral complexes of the MA4B2. Geometrical isomerism does not occur in tetrahedral complexes because all the bond angles around the central metal are 109.5° and each comer of a tetrahedron can be considered to be adjacent to all other corners. Similarly, a linear complex cannot exhibit cis–trans isomerism.

Answer 8

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Answer 10

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Answer 11

Ch. 25 - Prob. 1SAQ Ch. 25 - Q2. Which metal has the highest first ionization...Ch. 25 - Prob. 3SAQ Ch. 25 - Prob. 4SAQ Ch. 25 - Prob. 5SAQ Ch. 25 - Prob. 6SAQ Ch. 25 - Prob. 7SAQ Ch. 25 - Prob. 8SAQ Ch. 25 - Prob. 9SAQ Ch. 25 - Prob. 10SAQ

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