EBK ORGANIC CHEMISTRY
EBK ORGANIC CHEMISTRY
6th Edition
ISBN: 8220103151757
Author: LOUDON
Publisher: MAC HIGHER
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Chapter 25, Problem 25.8P
Interpretation Introduction

Interpretation:

The splitting expected in the proton resonance of the -CH2- group in triethyl phosphate, given that the coupling constants for the H-H splitting and P-H splitting happen to be identical.

Concept Introduction:

Phosphorus  31P has a ±12 nuclear spin. Therefore, when protons or  13C nuclei are being observed, a nearby phosphorus atom can cause splitting.

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Transmitance 3. Which one of the following compounds corresponds to this IR spectrum? Point out the absorption band(s) that helped you decide. OH H3C OH H₂C CH3 H3C CH3 H3C INFRARED SPECTRUM 0.8- 0.6 0.4- 0.2 3000 2000 1000 Wavenumber (cm-1) 4. Consider this compound: H3C On the structure above, label the different types of H's as A, B, C, etc. In table form, list the labeled signals, and for each one state the number of hydrogens, their shifts, and the splitting you would observe for these hydrogens in the ¹H NMR spectrum. Label # of hydrogens splitting Shift (2)
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