ORGANIC CHEMISTRY SAPLING ACCESS + ETEX
ORGANIC CHEMISTRY SAPLING ACCESS + ETEX
6th Edition
ISBN: 9781319306977
Author: LOUDON
Publisher: INTER MAC
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Chapter 25, Problem 25.27AP
Interpretation Introduction

(a)

Interpretation:

The structure of more reactive enantiomer of sarin is to be drawn.

Concept introduction:

The phosphorous atom in the sarin is the chiral center having three different groups bonded to it. The stereochemistry of at the chiral center can be determined by assigning the priority to the groups attached according to the Cahn Ingold Prelog rules.

Interpretation Introduction

(b)

Interpretation:

The product formed in the reaction of (S)-sarin with serine is to be determined.

Concept introduction:

The enzyme catalyzed substitution reaction of phosphate ester derivate at phosphate proceeds through SN2 reaction and results in inversion of stereochemistry.

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2. Name the following hydrocarbons. (9 marks) a) HHHHHHHH H-C-C- H-O-S b) HCEC-CH3 H H H H H d) c) H C=C- H H H e) CH3 CH3 CH2CH=CH-CH=CHCH3 HHHH H-C-C-C-C-H H HH H f) large CH2CH3 pola H3C section lovels tower, able ocart firs g) Tower H3C-CH2 then in H3C-CH-CH-CH3 enblbano bne noitsidab Copyright © 2008. Durham Continuing Education CH3
Name the molecules & Identify any chiral center CH3CH2CH2CHCH₂CH₂CH₂CH₂ OH CH₂CHCH2CH3 Br CH3 CH3CHCH2CHCH2CH3 CH3
Curved arrows are used to illustrate the flow of electrons. Using the provided starting and product structures, draw the curved electrons-pushing arrows for the following reaction or mechanistic step(s).
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