Physical Chemistry
Physical Chemistry
3rd Edition
ISBN: 9780321812001
Author: ENGEL, Thomas/ Reid
Publisher: Pearson College Div
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Chapter 25, Problem 25.11CP
Interpretation Introduction

Interpretation: The orbital needs to be identified from the given contour plot, radial function and the radial probability distribution for a one electron orbital.

Concept Introduction: In orbitals, there are two types of nodes present; radial and angular. The number of angular node is determined byazimuthal quantum number (l) . The principle quantum number, n tells about the number of radial nodes. The total number of nodes will be sum of these two nodes that is angular nodes and radial nodes.

Since, number of nodes is represented as

  number of nodes=n1

Therefore, the principle quantum number can be represented as follows:

  n=number of nodes+1

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