The mechanism for the reaction of the N terminus of the peptide with 2,4-dinitrofluorobenzene. Interpretation: The mechanism for the reaction of the N terminus of the peptide with 2,4-dinitrofluorobenzene is to be determined. Concept introduction: The process in which a proper series of amino acids is maintained in the peptide chain is known as edmann degradation. this process includes the labelling of terminal amino residue followed by the cleavage of this terminal amino residue from the peptide chain. the peptide bonds between other amino acids do not get disturb during this process.

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Answer 1

Question

Chapter 24.9C, Problem 24.21P

(a)

Interpretation Introduction

To determine: The mechanism for the reaction of the N terminus of the peptide with 2,4-dinitrofluorobenzene.

Interpretation: The mechanism for the reaction of the N terminus of the peptide with 2,4-dinitrofluorobenzene is to be determined.

Concept introduction: The process in which a proper series of amino acids is maintained in the peptide chain is known as edmann degradation. this process includes the labelling of terminal amino residue followed by the cleavage of this terminal amino residue from the peptide chain. the peptide bonds between other amino acids do not get disturb during this process.

(b)

Interpretation Introduction

To determine: The reason that the Edman degradation is usually preferred over the Sanger method.

Interpretation: The reason that the Edman degradation is usually preferred over the Sanger method is to be determined.

Concept introduction: The process in which a proper series of amino acids is maintained in the peptide chain is known as edmann degradation. this process includes the labelling of terminal amino residue followed by the cleavage of this terminal amino residue from the peptide chain. the peptide bonds between other amino acids do not get disturb during this process.

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4. Experimental Procedure. a. How many (total) data plots are to be completed for this experiment? Account for each. b. What information is to be extracted from each data plot?

Provide the IUPAC name of the following molecule. Don't forget to include the proper stereochemistry where appropriate.

Answer 2

Question

Chapter 24.9C, Problem 24.21P

(a)

Interpretation Introduction

To determine: The mechanism for the reaction of the N terminus of the peptide with 2,4-dinitrofluorobenzene.

Interpretation: The mechanism for the reaction of the N terminus of the peptide with 2,4-dinitrofluorobenzene is to be determined.

Concept introduction: The process in which a proper series of amino acids is maintained in the peptide chain is known as edmann degradation. this process includes the labelling of terminal amino residue followed by the cleavage of this terminal amino residue from the peptide chain. the peptide bonds between other amino acids do not get disturb during this process.

(b)

Interpretation Introduction

To determine: The reason that the Edman degradation is usually preferred over the Sanger method.

Interpretation: The reason that the Edman degradation is usually preferred over the Sanger method is to be determined.

Concept introduction: The process in which a proper series of amino acids is maintained in the peptide chain is known as edmann degradation. this process includes the labelling of terminal amino residue followed by the cleavage of this terminal amino residue from the peptide chain. the peptide bonds between other amino acids do not get disturb during this process.

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Answer 3

Question

Chapter 24.9C, Problem 24.21P

(a)

Interpretation Introduction

To determine: The mechanism for the reaction of the N terminus of the peptide with 2,4-dinitrofluorobenzene.

Interpretation: The mechanism for the reaction of the N terminus of the peptide with 2,4-dinitrofluorobenzene is to be determined.

Concept introduction: The process in which a proper series of amino acids is maintained in the peptide chain is known as edmann degradation. this process includes the labelling of terminal amino residue followed by the cleavage of this terminal amino residue from the peptide chain. the peptide bonds between other amino acids do not get disturb during this process.

(b)

Interpretation Introduction

To determine: The reason that the Edman degradation is usually preferred over the Sanger method.

Interpretation: The reason that the Edman degradation is usually preferred over the Sanger method is to be determined.

Concept introduction: The process in which a proper series of amino acids is maintained in the peptide chain is known as edmann degradation. this process includes the labelling of terminal amino residue followed by the cleavage of this terminal amino residue from the peptide chain. the peptide bonds between other amino acids do not get disturb during this process.

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Answer 4

Question

Chapter 24.9C, Problem 24.21P

(a)

Interpretation Introduction

To determine: The mechanism for the reaction of the N terminus of the peptide with 2,4-dinitrofluorobenzene.

Interpretation: The mechanism for the reaction of the N terminus of the peptide with 2,4-dinitrofluorobenzene is to be determined.

Concept introduction: The process in which a proper series of amino acids is maintained in the peptide chain is known as edmann degradation. this process includes the labelling of terminal amino residue followed by the cleavage of this terminal amino residue from the peptide chain. the peptide bonds between other amino acids do not get disturb during this process.

(b)

Interpretation Introduction

To determine: The reason that the Edman degradation is usually preferred over the Sanger method.

Interpretation: The reason that the Edman degradation is usually preferred over the Sanger method is to be determined.

Concept introduction: The process in which a proper series of amino acids is maintained in the peptide chain is known as edmann degradation. this process includes the labelling of terminal amino residue followed by the cleavage of this terminal amino residue from the peptide chain. the peptide bonds between other amino acids do not get disturb during this process.

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Answer 5

Chapter 24.9C, Problem 24.21P

(a)

Interpretation Introduction

To determine: The mechanism for the reaction of the N terminus of the peptide with 2,4-dinitrofluorobenzene.

Interpretation: The mechanism for the reaction of the N terminus of the peptide with 2,4-dinitrofluorobenzene is to be determined.

Concept introduction: The process in which a proper series of amino acids is maintained in the peptide chain is known as edmann degradation. this process includes the labelling of terminal amino residue followed by the cleavage of this terminal amino residue from the peptide chain. the peptide bonds between other amino acids do not get disturb during this process.

(b)

Interpretation Introduction

To determine: The reason that the Edman degradation is usually preferred over the Sanger method.

Interpretation: The reason that the Edman degradation is usually preferred over the Sanger method is to be determined.

Concept introduction: The process in which a proper series of amino acids is maintained in the peptide chain is known as edmann degradation. this process includes the labelling of terminal amino residue followed by the cleavage of this terminal amino residue from the peptide chain. the peptide bonds between other amino acids do not get disturb during this process.

Answer 6

Chapter 24.9C, Problem 24.21P

(a)

Interpretation Introduction

To determine: The mechanism for the reaction of the N terminus of the peptide with 2,4-dinitrofluorobenzene.

Interpretation: The mechanism for the reaction of the N terminus of the peptide with 2,4-dinitrofluorobenzene is to be determined.

Concept introduction: The process in which a proper series of amino acids is maintained in the peptide chain is known as edmann degradation. this process includes the labelling of terminal amino residue followed by the cleavage of this terminal amino residue from the peptide chain. the peptide bonds between other amino acids do not get disturb during this process.

Answer 7

Chapter 24.9C, Problem 24.21P

(a)

Interpretation Introduction

To determine: The mechanism for the reaction of the N terminus of the peptide with 2,4-dinitrofluorobenzene.

Interpretation: The mechanism for the reaction of the N terminus of the peptide with 2,4-dinitrofluorobenzene is to be determined.

Concept introduction: The process in which a proper series of amino acids is maintained in the peptide chain is known as edmann degradation. this process includes the labelling of terminal amino residue followed by the cleavage of this terminal amino residue from the peptide chain. the peptide bonds between other amino acids do not get disturb during this process.

Answer 8

(b)

Interpretation Introduction

To determine: The reason that the Edman degradation is usually preferred over the Sanger method.

Interpretation: The reason that the Edman degradation is usually preferred over the Sanger method is to be determined.

Concept introduction: The process in which a proper series of amino acids is maintained in the peptide chain is known as edmann degradation. this process includes the labelling of terminal amino residue followed by the cleavage of this terminal amino residue from the peptide chain. the peptide bonds between other amino acids do not get disturb during this process.

Answer 9

(b)

Interpretation Introduction

To determine: The reason that the Edman degradation is usually preferred over the Sanger method.

Interpretation: The reason that the Edman degradation is usually preferred over the Sanger method is to be determined.

Concept introduction: The process in which a proper series of amino acids is maintained in the peptide chain is known as edmann degradation. this process includes the labelling of terminal amino residue followed by the cleavage of this terminal amino residue from the peptide chain. the peptide bonds between other amino acids do not get disturb during this process.

Answer 10

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Answer 11

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Answer 12

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Answer 13

Ch. 24.2A - Draw three-dimensional representations of the...Ch. 24.2A - Prob. 24.2P Ch. 24.2B - The herbicide glyphosate (Roundup) kills plants by...Ch. 24.4 - Draw the structure of the predominant form of a....Ch. 24.4 - Draw the resonance forms of a protonated guanidino...Ch. 24.4 - Although tryptophan contains a heterocyclic amine,...Ch. 24.4 - Prob. 24.7P Ch. 24.4 - Prob. 24.8P Ch. 24.5A - Show how the following amino acids might be formed...Ch. 24.5B - Prob. 24.10P

Solution Summary: The author explains that the mechanism for the reaction of the N terminus of a peptide with 2,4-dinitrofluorobenzene is to be determined.

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