ORGANIC CHEMISTRY (LL)-W/WILEYPLUS
ORGANIC CHEMISTRY (LL)-W/WILEYPLUS
4th Edition
ISBN: 9781119659556
Author: Klein
Publisher: WILEY
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Chapter 24.5, Problem 22CC
Interpretation Introduction

Interpretation:

Open chain for the given carbohydrate that undergo acid-catalyzed cyclization to form α-D-fructopyranose should be drawn.

Concept introduction:

  • Hemiacetal are formed for the compound having both hydroxyl group and aldehyde group in acidic condition.
  • The –OH group of compound attacks the carbonyl group of the same compound, thereby a ring is formed by the carbon atoms and oxygen atom of –OH group with incorporating into the ring.
  • Acid catalyzed reaction are followed by the deprotonation of Hydronium ion to water molecule and then protonation of this water molecule will return to Hydronium ion will take place.
  • Pyranose: A six-member cyclic form of a monosaccharide is called as pyronose.

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3. Name this ether correctly. H₁C H3C CH3 CH3 4. Show the best way to make the ether in #3 by a Williamson Ether Synthesis. Start from an alcohol or phenol. 5. Draw the structure of an example of a sulfide.
1. Which one(s) of these can be oxidized with CrO3 ? (could be more than one) a) triphenylmethanol b) 2-pentanol c) Ethyl alcohol d) CH3 2. Write in all the product(s) of this reaction. Label them as "major" or "minor". 2-methyl-2-hexanol H2SO4, heat
3) Determine if the pairs are constitutional isomers, enantiomers, diastereomers, or mesocompounds. (4 points)

Chapter 24 Solutions

ORGANIC CHEMISTRY (LL)-W/WILEYPLUS

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