The more stable chair conformation for the given compounds are needed to be drawn. Concept introduction: Haworth projection is used to represent sugars in their cyclic forms. In Haworth projection, α-indicates the –OH group of anomeric carbon C1 and CH 2 OH substituent on the C5 carbon is trans to each other. D indicates the CH 2 OH substituent on the C5 carbon is on up position. The right side and left side –OH groups of chiral carbons in fisher projection are drawn as down side and upward side respectively. Chair conformation is drawn according to the respective carbons in Haworth projection. Stability of chair conformation is depending upon the positions of bulky substituents whether on axial or equatorial , the location of bulky substituents on equatorial position is more stable than bulky substituents on axial position. To draw: the more stable chair conformation form for the given compound (a).

Question

Want to see the full answer?

Answer 1

Question

Chapter 24.5, Problem 16PTS

(a)

Interpretation Introduction

Interpretation:

The more stable chair conformation for the given compounds are needed to be drawn.

Concept introduction:

Haworth projection is used to represent sugars in their cyclic forms.

In Haworth projection,

α-indicates the –OH group of anomeric carbon C1 and CH2OH substituent on the C5 carbon is trans to each other.

D indicates the CH2OH substituent on the C5 carbon is on up position.

The right side and left side –OH groups of chiral carbons in fisher projection are drawn as down side and upward side respectively.

Chair conformation is drawn according to the respective carbons in Haworth projection.

Stability of chair conformation is depending upon the positions of bulky substituents whether on axial or equatorial, the location of bulky substituents on equatorial position is more stable than bulky substituents on axial position.

To draw: the more stable chair conformation form for the given compound (a).

(b)

Interpretation Introduction

Interpretation:

The more stable chair conformation for the given compounds are needed to be drawn.

Concept introduction:

Haworth projection is used to represent sugars in their cyclic forms.

In Haworth projection,

α-indicates the –OH group of anomeric carbon C1 and CH2OH substituent on the C5 carbon is trans to each other.

D indicates the CH2OH substituent on the C5 carbon is on up position.

The right side and left side –OH groups of chiral carbons in fisher projection are drawn as down side and upward side respectively.

Chair conformation is drawn according to the respective carbons in Haworth projection.

Stability of chair conformation is depending upon the positions of bulky substituents whether on axial or equatorial, the location of bulky substituents on equatorial position is more stable than bulky substituents on axial position.

To draw: the more stable chair conformation for the given compound (b).

(c)

Interpretation Introduction

Interpretation:

The more stable chair conformation for the given compounds are needed to be drawn.

Concept introduction:

Haworth projection is used to represent sugars in their cyclic forms.

In Haworth projection,

α-indicates the –OH group of anomeric carbon C1 and CH2OH substituent on the C5 carbon is trans to each other.

D indicates the CH2OH substituent on the C5 carbon is on up position.

The right side and left side –OH groups of chiral carbons in fisher projection are drawn as down side and upward side respectively.

Chair conformation is drawn according to the respective carbons in Haworth projection.

Stability of chair conformation is depending upon the positions of bulky substituents whether on axial or equatorial, the location of bulky substituents on equatorial position is more stable than bulky substituents on axial position.

To draw: the more stable chair conformation for the given compound (c).

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Students have asked these similar questions

An expression for the root mean square velocity, vrms, of a gas was derived. Using Maxwell’s velocity distribution, one can also calculate the mean velocity and the most probable velocity (mp) of a collection of molecules. The equations used for these two quantities are vmean=(8RT/πM)1/2 and vmp=(2RT/M)1/2 These values have a fixed relationship to each other.(a) Arrange these three quantities in order of increasing magnitude.(b) Show that the relative magnitudes are independent of the molar mass of the gas.(c) Use the smallest velocity as a reference for establishing the order of magnitude and determine the relationship between the larger and smaller values.

The reaction of solid dimethylhydrazine, (CH3)2N2H2, and liquefied dinitrogen tetroxide, N2O4, has been investigated for use as rocket fuel. The reaction produces the gases carbon dioxide (CO2), nitrogen (N2), and water vapor (H2O), which are ejected in the exhaust gases. In a controlled experiment, solid dimethylhydrazine was reacted with excess dinitrogen tetroxide, and the gases were collected in a closed balloon until a pressure of 2.50 atm and a temperature of 400.0 K were reached.(a) What are the partial pressures of CO2, N2, and H2O?(b) When the CO2 is removed by chemical reaction, what are the partial pressures of the remaining gases?

One liter of chlorine gas at 1 atm and 298 K reacts completely with 1.00 L of nitrogen gas and 2.00 L of oxygen gas at the same temperature and pressure. A single gaseous product is formed, which fills a 2.00 L flask at 1.00 atm and 298 K. Use this information to determine the following characteristics of the product:(a) its empirical formula;(b) its molecular formula;(c) the most favorable Lewis formula based on formal charge arguments (the central atom is N);(d) the shape of the molecule.

Answer 2

Question

Chapter 24.5, Problem 16PTS

(a)

Interpretation Introduction

Interpretation:

The more stable chair conformation for the given compounds are needed to be drawn.

Concept introduction:

Haworth projection is used to represent sugars in their cyclic forms.

In Haworth projection,

α-indicates the –OH group of anomeric carbon C1 and CH2OH substituent on the C5 carbon is trans to each other.

D indicates the CH2OH substituent on the C5 carbon is on up position.

The right side and left side –OH groups of chiral carbons in fisher projection are drawn as down side and upward side respectively.

Chair conformation is drawn according to the respective carbons in Haworth projection.

Stability of chair conformation is depending upon the positions of bulky substituents whether on axial or equatorial, the location of bulky substituents on equatorial position is more stable than bulky substituents on axial position.

To draw: the more stable chair conformation form for the given compound (a).

(b)

Interpretation Introduction

Interpretation:

The more stable chair conformation for the given compounds are needed to be drawn.

Concept introduction:

Haworth projection is used to represent sugars in their cyclic forms.

In Haworth projection,

α-indicates the –OH group of anomeric carbon C1 and CH2OH substituent on the C5 carbon is trans to each other.

D indicates the CH2OH substituent on the C5 carbon is on up position.

The right side and left side –OH groups of chiral carbons in fisher projection are drawn as down side and upward side respectively.

Chair conformation is drawn according to the respective carbons in Haworth projection.

Stability of chair conformation is depending upon the positions of bulky substituents whether on axial or equatorial, the location of bulky substituents on equatorial position is more stable than bulky substituents on axial position.

To draw: the more stable chair conformation for the given compound (b).

(c)

Interpretation Introduction

Interpretation:

The more stable chair conformation for the given compounds are needed to be drawn.

Concept introduction:

Haworth projection is used to represent sugars in their cyclic forms.

In Haworth projection,

α-indicates the –OH group of anomeric carbon C1 and CH2OH substituent on the C5 carbon is trans to each other.

D indicates the CH2OH substituent on the C5 carbon is on up position.

The right side and left side –OH groups of chiral carbons in fisher projection are drawn as down side and upward side respectively.

Chair conformation is drawn according to the respective carbons in Haworth projection.

Stability of chair conformation is depending upon the positions of bulky substituents whether on axial or equatorial, the location of bulky substituents on equatorial position is more stable than bulky substituents on axial position.

To draw: the more stable chair conformation for the given compound (c).

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 3

Question

Chapter 24.5, Problem 16PTS

(a)

Interpretation Introduction

Interpretation:

The more stable chair conformation for the given compounds are needed to be drawn.

Concept introduction:

Haworth projection is used to represent sugars in their cyclic forms.

In Haworth projection,

α-indicates the –OH group of anomeric carbon C1 and CH2OH substituent on the C5 carbon is trans to each other.

D indicates the CH2OH substituent on the C5 carbon is on up position.

The right side and left side –OH groups of chiral carbons in fisher projection are drawn as down side and upward side respectively.

Chair conformation is drawn according to the respective carbons in Haworth projection.

Stability of chair conformation is depending upon the positions of bulky substituents whether on axial or equatorial, the location of bulky substituents on equatorial position is more stable than bulky substituents on axial position.

To draw: the more stable chair conformation form for the given compound (a).

(b)

Interpretation Introduction

Interpretation:

The more stable chair conformation for the given compounds are needed to be drawn.

Concept introduction:

Haworth projection is used to represent sugars in their cyclic forms.

In Haworth projection,

α-indicates the –OH group of anomeric carbon C1 and CH2OH substituent on the C5 carbon is trans to each other.

D indicates the CH2OH substituent on the C5 carbon is on up position.

The right side and left side –OH groups of chiral carbons in fisher projection are drawn as down side and upward side respectively.

Chair conformation is drawn according to the respective carbons in Haworth projection.

Stability of chair conformation is depending upon the positions of bulky substituents whether on axial or equatorial, the location of bulky substituents on equatorial position is more stable than bulky substituents on axial position.

To draw: the more stable chair conformation for the given compound (b).

(c)

Interpretation Introduction

Interpretation:

The more stable chair conformation for the given compounds are needed to be drawn.

Concept introduction:

Haworth projection is used to represent sugars in their cyclic forms.

In Haworth projection,

α-indicates the –OH group of anomeric carbon C1 and CH2OH substituent on the C5 carbon is trans to each other.

D indicates the CH2OH substituent on the C5 carbon is on up position.

The right side and left side –OH groups of chiral carbons in fisher projection are drawn as down side and upward side respectively.

Chair conformation is drawn according to the respective carbons in Haworth projection.

Stability of chair conformation is depending upon the positions of bulky substituents whether on axial or equatorial, the location of bulky substituents on equatorial position is more stable than bulky substituents on axial position.

To draw: the more stable chair conformation for the given compound (c).

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 4

Question

Chapter 24.5, Problem 16PTS

(a)

Interpretation Introduction

Interpretation:

The more stable chair conformation for the given compounds are needed to be drawn.

Concept introduction:

Haworth projection is used to represent sugars in their cyclic forms.

In Haworth projection,

α-indicates the –OH group of anomeric carbon C1 and CH2OH substituent on the C5 carbon is trans to each other.

D indicates the CH2OH substituent on the C5 carbon is on up position.

The right side and left side –OH groups of chiral carbons in fisher projection are drawn as down side and upward side respectively.

Chair conformation is drawn according to the respective carbons in Haworth projection.

Stability of chair conformation is depending upon the positions of bulky substituents whether on axial or equatorial, the location of bulky substituents on equatorial position is more stable than bulky substituents on axial position.

To draw: the more stable chair conformation form for the given compound (a).

(b)

Interpretation Introduction

Interpretation:

The more stable chair conformation for the given compounds are needed to be drawn.

Concept introduction:

Haworth projection is used to represent sugars in their cyclic forms.

In Haworth projection,

α-indicates the –OH group of anomeric carbon C1 and CH2OH substituent on the C5 carbon is trans to each other.

D indicates the CH2OH substituent on the C5 carbon is on up position.

The right side and left side –OH groups of chiral carbons in fisher projection are drawn as down side and upward side respectively.

Chair conformation is drawn according to the respective carbons in Haworth projection.

Stability of chair conformation is depending upon the positions of bulky substituents whether on axial or equatorial, the location of bulky substituents on equatorial position is more stable than bulky substituents on axial position.

To draw: the more stable chair conformation for the given compound (b).

(c)

Interpretation Introduction

Interpretation:

The more stable chair conformation for the given compounds are needed to be drawn.

Concept introduction:

Haworth projection is used to represent sugars in their cyclic forms.

In Haworth projection,

α-indicates the –OH group of anomeric carbon C1 and CH2OH substituent on the C5 carbon is trans to each other.

D indicates the CH2OH substituent on the C5 carbon is on up position.

The right side and left side –OH groups of chiral carbons in fisher projection are drawn as down side and upward side respectively.

Chair conformation is drawn according to the respective carbons in Haworth projection.

Stability of chair conformation is depending upon the positions of bulky substituents whether on axial or equatorial, the location of bulky substituents on equatorial position is more stable than bulky substituents on axial position.

To draw: the more stable chair conformation for the given compound (c).

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 5

Chapter 24.5, Problem 16PTS

(a)

Interpretation Introduction

Interpretation:

The more stable chair conformation for the given compounds are needed to be drawn.

Concept introduction:

Haworth projection is used to represent sugars in their cyclic forms.

In Haworth projection,

α-indicates the –OH group of anomeric carbon C1 and CH2OH substituent on the C5 carbon is trans to each other.

D indicates the CH2OH substituent on the C5 carbon is on up position.

The right side and left side –OH groups of chiral carbons in fisher projection are drawn as down side and upward side respectively.

Chair conformation is drawn according to the respective carbons in Haworth projection.

Stability of chair conformation is depending upon the positions of bulky substituents whether on axial or equatorial, the location of bulky substituents on equatorial position is more stable than bulky substituents on axial position.

To draw: the more stable chair conformation form for the given compound (a).

(b)

Interpretation Introduction

Interpretation:

The more stable chair conformation for the given compounds are needed to be drawn.

Concept introduction:

Haworth projection is used to represent sugars in their cyclic forms.

In Haworth projection,

α-indicates the –OH group of anomeric carbon C1 and CH2OH substituent on the C5 carbon is trans to each other.

D indicates the CH2OH substituent on the C5 carbon is on up position.

The right side and left side –OH groups of chiral carbons in fisher projection are drawn as down side and upward side respectively.

Chair conformation is drawn according to the respective carbons in Haworth projection.

Stability of chair conformation is depending upon the positions of bulky substituents whether on axial or equatorial, the location of bulky substituents on equatorial position is more stable than bulky substituents on axial position.

To draw: the more stable chair conformation for the given compound (b).

(c)

Interpretation Introduction

Interpretation:

The more stable chair conformation for the given compounds are needed to be drawn.

Concept introduction:

Haworth projection is used to represent sugars in their cyclic forms.

In Haworth projection,

α-indicates the –OH group of anomeric carbon C1 and CH2OH substituent on the C5 carbon is trans to each other.

D indicates the CH2OH substituent on the C5 carbon is on up position.

The right side and left side –OH groups of chiral carbons in fisher projection are drawn as down side and upward side respectively.

Chair conformation is drawn according to the respective carbons in Haworth projection.

Stability of chair conformation is depending upon the positions of bulky substituents whether on axial or equatorial, the location of bulky substituents on equatorial position is more stable than bulky substituents on axial position.

To draw: the more stable chair conformation for the given compound (c).

Answer 6

Chapter 24.5, Problem 16PTS

(a)

Interpretation Introduction

Interpretation:

The more stable chair conformation for the given compounds are needed to be drawn.

Concept introduction:

Haworth projection is used to represent sugars in their cyclic forms.

In Haworth projection,

α-indicates the –OH group of anomeric carbon C1 and CH2OH substituent on the C5 carbon is trans to each other.

D indicates the CH2OH substituent on the C5 carbon is on up position.

The right side and left side –OH groups of chiral carbons in fisher projection are drawn as down side and upward side respectively.

Chair conformation is drawn according to the respective carbons in Haworth projection.

Stability of chair conformation is depending upon the positions of bulky substituents whether on axial or equatorial, the location of bulky substituents on equatorial position is more stable than bulky substituents on axial position.

To draw: the more stable chair conformation form for the given compound (a).

Answer 7

Chapter 24.5, Problem 16PTS

(a)

Interpretation Introduction

Interpretation:

The more stable chair conformation for the given compounds are needed to be drawn.

Concept introduction:

Haworth projection is used to represent sugars in their cyclic forms.

In Haworth projection,

α-indicates the –OH group of anomeric carbon C1 and CH2OH substituent on the C5 carbon is trans to each other.

D indicates the CH2OH substituent on the C5 carbon is on up position.

The right side and left side –OH groups of chiral carbons in fisher projection are drawn as down side and upward side respectively.

Chair conformation is drawn according to the respective carbons in Haworth projection.

Stability of chair conformation is depending upon the positions of bulky substituents whether on axial or equatorial, the location of bulky substituents on equatorial position is more stable than bulky substituents on axial position.

To draw: the more stable chair conformation form for the given compound (a).

Answer 8

(b)

Interpretation Introduction

Interpretation:

The more stable chair conformation for the given compounds are needed to be drawn.

Concept introduction:

Haworth projection is used to represent sugars in their cyclic forms.

In Haworth projection,

α-indicates the –OH group of anomeric carbon C1 and CH2OH substituent on the C5 carbon is trans to each other.

D indicates the CH2OH substituent on the C5 carbon is on up position.

The right side and left side –OH groups of chiral carbons in fisher projection are drawn as down side and upward side respectively.

Chair conformation is drawn according to the respective carbons in Haworth projection.

Stability of chair conformation is depending upon the positions of bulky substituents whether on axial or equatorial, the location of bulky substituents on equatorial position is more stable than bulky substituents on axial position.

To draw: the more stable chair conformation for the given compound (b).

Answer 9

(b)

Interpretation Introduction

Interpretation:

The more stable chair conformation for the given compounds are needed to be drawn.

Concept introduction:

Haworth projection is used to represent sugars in their cyclic forms.

In Haworth projection,

α-indicates the –OH group of anomeric carbon C1 and CH2OH substituent on the C5 carbon is trans to each other.

D indicates the CH2OH substituent on the C5 carbon is on up position.

The right side and left side –OH groups of chiral carbons in fisher projection are drawn as down side and upward side respectively.

Chair conformation is drawn according to the respective carbons in Haworth projection.

Stability of chair conformation is depending upon the positions of bulky substituents whether on axial or equatorial, the location of bulky substituents on equatorial position is more stable than bulky substituents on axial position.

To draw: the more stable chair conformation for the given compound (b).

Answer 10

(c)

Interpretation Introduction

Interpretation:

The more stable chair conformation for the given compounds are needed to be drawn.

Concept introduction:

Haworth projection is used to represent sugars in their cyclic forms.

In Haworth projection,

α-indicates the –OH group of anomeric carbon C1 and CH2OH substituent on the C5 carbon is trans to each other.

D indicates the CH2OH substituent on the C5 carbon is on up position.

The right side and left side –OH groups of chiral carbons in fisher projection are drawn as down side and upward side respectively.

Chair conformation is drawn according to the respective carbons in Haworth projection.

Stability of chair conformation is depending upon the positions of bulky substituents whether on axial or equatorial, the location of bulky substituents on equatorial position is more stable than bulky substituents on axial position.

To draw: the more stable chair conformation for the given compound (c).

Answer 11

(c)

Interpretation Introduction

Interpretation:

The more stable chair conformation for the given compounds are needed to be drawn.

Concept introduction:

Haworth projection is used to represent sugars in their cyclic forms.

In Haworth projection,

α-indicates the –OH group of anomeric carbon C1 and CH2OH substituent on the C5 carbon is trans to each other.

D indicates the CH2OH substituent on the C5 carbon is on up position.

The right side and left side –OH groups of chiral carbons in fisher projection are drawn as down side and upward side respectively.

Chair conformation is drawn according to the respective carbons in Haworth projection.

Stability of chair conformation is depending upon the positions of bulky substituents whether on axial or equatorial, the location of bulky substituents on equatorial position is more stable than bulky substituents on axial position.

To draw: the more stable chair conformation for the given compound (c).

Answer 12

Expert Solution & Answer

Answer 13

Expert Solution & Answer

Answer 14

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 15

Ch. 24.2 - Prob. 1CC Ch. 24.2 - Prob. 2CC Ch. 24.2 - Prob. 3CC Ch. 24.2 - Prob. 4CC Ch. 24.2 - Prob. 5CC Ch. 24.2 - Prob. 6CC Ch. 24.4 - Prob. 7CC Ch. 24.4 - Prob. 8CC Ch. 24.5 - Prob. 1LTS Ch. 24.5 - Prob. 9PTS

Want to see the full answer?

Chapter 24 Solutions