a) p -Nitroaniline, p -aminobenzaldehyde, p -bromoaniline Interpretation: The compounds p-nitroaniline, p-aminobenzaldehyde and p-bromoaniline are to be arranged in the increasing order of their basicity. Concept introduction: Amines are basic as they can donate the lone pair if electrons on the N atom. Generally aryl amines are less basic than alkyl amines. An electron withdrawing substituent present on the aromatic ring reduces the base strength while an electron releasing substituent present on the aromatic ring enhances the base strength.

Question

The photolysis of H3C–N=N–C2H5 involves the breaking of the single bonds shown. According to this, in addition to N2, what products would be obtained primarily if the reaction were carried out in the gas phase or in solution in an inert solvent?

Answer 1

Question

Chapter 24.4, Problem 6P

Interpretation Introduction

a) p-Nitroaniline, p-aminobenzaldehyde, p-bromoaniline

Interpretation:

The compounds p-nitroaniline, p-aminobenzaldehyde and p-bromoaniline are to be arranged in the increasing order of their basicity.

Concept introduction:

Amines are basic as they can donate the lone pair if electrons on the N atom. Generally aryl amines are less basic than alkyl amines. An electron withdrawing substituent present on the aromatic ring reduces the base strength while an electron releasing substituent present on the aromatic ring enhances the base strength.

Interpretation Introduction

b) p-Chloroaniline, p-aminoacetophenone, p-methylaniline

Interpretation:

The compounds p-chloroaniline, p-aminoacetophenone and p-methylaniline are to be arranged in the increasing order of their basicity.

Concept introduction:

Amines are basic as they can donate the lone pair if electrons on the N atom. Generally aryl amines are less basic than alkyl amines. An electron withdrawing substituent present on the aromatic ring reduces the base strength while an electron releasing substituent present on the aromatic ring enhances the base strength.

Interpretation Introduction

c) p-(trifluoromethyl)aniline, p-methylaniline, p-(fluoromethyl)aniline

Interpretation:

The compounds p-(trifluoromethyl)aniline, p-methylaniline and p-(fluoromethyl) aniline are to be arranged in the increasing order of their basicity.

Concept introduction:

Amines are basic as they can donate the lone pair if electrons on the N atom. Generally aryl amines are less basic than alkyl amines. An electron withdrawing substituent present on the aromatic ring reduces the base strength while an electron releasing substituent present on the aromatic ring enhances the base strength.

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The photolysis of H3C–N=N–C2H5 involves the breaking of the single bonds shown. According to this, in addition to N2, what products would be obtained primarily if the reaction were carried out in the gas phase or in solution in an inert solvent?

Given a keto-enol tautomerization reaction, which is greatly influenced by the type of solvent, indicate which of the following solvent properties cannot be considered a "solvent effect"?(A) Dielectric constant(B) Polarity(C) Hydrogen bonding capacity(D) Temperature

In solution reactions, what does "solvent effect" mean?

Answer 2

Question

Chapter 24.4, Problem 6P

Interpretation Introduction

a) p-Nitroaniline, p-aminobenzaldehyde, p-bromoaniline

Interpretation:

The compounds p-nitroaniline, p-aminobenzaldehyde and p-bromoaniline are to be arranged in the increasing order of their basicity.

Concept introduction:

Amines are basic as they can donate the lone pair if electrons on the N atom. Generally aryl amines are less basic than alkyl amines. An electron withdrawing substituent present on the aromatic ring reduces the base strength while an electron releasing substituent present on the aromatic ring enhances the base strength.

Interpretation Introduction

b) p-Chloroaniline, p-aminoacetophenone, p-methylaniline

Interpretation:

The compounds p-chloroaniline, p-aminoacetophenone and p-methylaniline are to be arranged in the increasing order of their basicity.

Concept introduction:

Amines are basic as they can donate the lone pair if electrons on the N atom. Generally aryl amines are less basic than alkyl amines. An electron withdrawing substituent present on the aromatic ring reduces the base strength while an electron releasing substituent present on the aromatic ring enhances the base strength.

Interpretation Introduction

c) p-(trifluoromethyl)aniline, p-methylaniline, p-(fluoromethyl)aniline

Interpretation:

The compounds p-(trifluoromethyl)aniline, p-methylaniline and p-(fluoromethyl) aniline are to be arranged in the increasing order of their basicity.

Concept introduction:

Amines are basic as they can donate the lone pair if electrons on the N atom. Generally aryl amines are less basic than alkyl amines. An electron withdrawing substituent present on the aromatic ring reduces the base strength while an electron releasing substituent present on the aromatic ring enhances the base strength.

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Answer 3

Question

Chapter 24.4, Problem 6P

Interpretation Introduction

a) p-Nitroaniline, p-aminobenzaldehyde, p-bromoaniline

Interpretation:

The compounds p-nitroaniline, p-aminobenzaldehyde and p-bromoaniline are to be arranged in the increasing order of their basicity.

Concept introduction:

Amines are basic as they can donate the lone pair if electrons on the N atom. Generally aryl amines are less basic than alkyl amines. An electron withdrawing substituent present on the aromatic ring reduces the base strength while an electron releasing substituent present on the aromatic ring enhances the base strength.

Interpretation Introduction

b) p-Chloroaniline, p-aminoacetophenone, p-methylaniline

Interpretation:

The compounds p-chloroaniline, p-aminoacetophenone and p-methylaniline are to be arranged in the increasing order of their basicity.

Concept introduction:

Amines are basic as they can donate the lone pair if electrons on the N atom. Generally aryl amines are less basic than alkyl amines. An electron withdrawing substituent present on the aromatic ring reduces the base strength while an electron releasing substituent present on the aromatic ring enhances the base strength.

Interpretation Introduction

c) p-(trifluoromethyl)aniline, p-methylaniline, p-(fluoromethyl)aniline

Interpretation:

The compounds p-(trifluoromethyl)aniline, p-methylaniline and p-(fluoromethyl) aniline are to be arranged in the increasing order of their basicity.

Concept introduction:

Amines are basic as they can donate the lone pair if electrons on the N atom. Generally aryl amines are less basic than alkyl amines. An electron withdrawing substituent present on the aromatic ring reduces the base strength while an electron releasing substituent present on the aromatic ring enhances the base strength.

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Answer 4

Question

Chapter 24.4, Problem 6P

Interpretation Introduction

a) p-Nitroaniline, p-aminobenzaldehyde, p-bromoaniline

Interpretation:

The compounds p-nitroaniline, p-aminobenzaldehyde and p-bromoaniline are to be arranged in the increasing order of their basicity.

Concept introduction:

Amines are basic as they can donate the lone pair if electrons on the N atom. Generally aryl amines are less basic than alkyl amines. An electron withdrawing substituent present on the aromatic ring reduces the base strength while an electron releasing substituent present on the aromatic ring enhances the base strength.

Interpretation Introduction

b) p-Chloroaniline, p-aminoacetophenone, p-methylaniline

Interpretation:

The compounds p-chloroaniline, p-aminoacetophenone and p-methylaniline are to be arranged in the increasing order of their basicity.

Concept introduction:

Amines are basic as they can donate the lone pair if electrons on the N atom. Generally aryl amines are less basic than alkyl amines. An electron withdrawing substituent present on the aromatic ring reduces the base strength while an electron releasing substituent present on the aromatic ring enhances the base strength.

Interpretation Introduction

c) p-(trifluoromethyl)aniline, p-methylaniline, p-(fluoromethyl)aniline

Interpretation:

The compounds p-(trifluoromethyl)aniline, p-methylaniline and p-(fluoromethyl) aniline are to be arranged in the increasing order of their basicity.

Concept introduction:

Amines are basic as they can donate the lone pair if electrons on the N atom. Generally aryl amines are less basic than alkyl amines. An electron withdrawing substituent present on the aromatic ring reduces the base strength while an electron releasing substituent present on the aromatic ring enhances the base strength.

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Answer 5

Chapter 24.4, Problem 6P

Interpretation Introduction

a) p-Nitroaniline, p-aminobenzaldehyde, p-bromoaniline

Interpretation:

The compounds p-nitroaniline, p-aminobenzaldehyde and p-bromoaniline are to be arranged in the increasing order of their basicity.

Concept introduction:

Amines are basic as they can donate the lone pair if electrons on the N atom. Generally aryl amines are less basic than alkyl amines. An electron withdrawing substituent present on the aromatic ring reduces the base strength while an electron releasing substituent present on the aromatic ring enhances the base strength.

Interpretation Introduction

b) p-Chloroaniline, p-aminoacetophenone, p-methylaniline

Interpretation:

The compounds p-chloroaniline, p-aminoacetophenone and p-methylaniline are to be arranged in the increasing order of their basicity.

Concept introduction:

Amines are basic as they can donate the lone pair if electrons on the N atom. Generally aryl amines are less basic than alkyl amines. An electron withdrawing substituent present on the aromatic ring reduces the base strength while an electron releasing substituent present on the aromatic ring enhances the base strength.

Interpretation Introduction

c) p-(trifluoromethyl)aniline, p-methylaniline, p-(fluoromethyl)aniline

Interpretation:

The compounds p-(trifluoromethyl)aniline, p-methylaniline and p-(fluoromethyl) aniline are to be arranged in the increasing order of their basicity.

Concept introduction:

Amines are basic as they can donate the lone pair if electrons on the N atom. Generally aryl amines are less basic than alkyl amines. An electron withdrawing substituent present on the aromatic ring reduces the base strength while an electron releasing substituent present on the aromatic ring enhances the base strength.

Answer 6

Chapter 24.4, Problem 6P

Interpretation Introduction

a) p-Nitroaniline, p-aminobenzaldehyde, p-bromoaniline

Interpretation:

The compounds p-nitroaniline, p-aminobenzaldehyde and p-bromoaniline are to be arranged in the increasing order of their basicity.

Concept introduction:

Amines are basic as they can donate the lone pair if electrons on the N atom. Generally aryl amines are less basic than alkyl amines. An electron withdrawing substituent present on the aromatic ring reduces the base strength while an electron releasing substituent present on the aromatic ring enhances the base strength.

Answer 7

Chapter 24.4, Problem 6P

Interpretation Introduction

a) p-Nitroaniline, p-aminobenzaldehyde, p-bromoaniline

Interpretation:

The compounds p-nitroaniline, p-aminobenzaldehyde and p-bromoaniline are to be arranged in the increasing order of their basicity.

Concept introduction:

Amines are basic as they can donate the lone pair if electrons on the N atom. Generally aryl amines are less basic than alkyl amines. An electron withdrawing substituent present on the aromatic ring reduces the base strength while an electron releasing substituent present on the aromatic ring enhances the base strength.

Answer 8

Interpretation Introduction

b) p-Chloroaniline, p-aminoacetophenone, p-methylaniline

Interpretation:

The compounds p-chloroaniline, p-aminoacetophenone and p-methylaniline are to be arranged in the increasing order of their basicity.

Concept introduction:

Amines are basic as they can donate the lone pair if electrons on the N atom. Generally aryl amines are less basic than alkyl amines. An electron withdrawing substituent present on the aromatic ring reduces the base strength while an electron releasing substituent present on the aromatic ring enhances the base strength.

Answer 9

Interpretation Introduction

b) p-Chloroaniline, p-aminoacetophenone, p-methylaniline

Interpretation:

The compounds p-chloroaniline, p-aminoacetophenone and p-methylaniline are to be arranged in the increasing order of their basicity.

Concept introduction:

Amines are basic as they can donate the lone pair if electrons on the N atom. Generally aryl amines are less basic than alkyl amines. An electron withdrawing substituent present on the aromatic ring reduces the base strength while an electron releasing substituent present on the aromatic ring enhances the base strength.

Answer 10

Interpretation Introduction

c) p-(trifluoromethyl)aniline, p-methylaniline, p-(fluoromethyl)aniline

Interpretation:

The compounds p-(trifluoromethyl)aniline, p-methylaniline and p-(fluoromethyl) aniline are to be arranged in the increasing order of their basicity.

Concept introduction:

Amines are basic as they can donate the lone pair if electrons on the N atom. Generally aryl amines are less basic than alkyl amines. An electron withdrawing substituent present on the aromatic ring reduces the base strength while an electron releasing substituent present on the aromatic ring enhances the base strength.

Answer 11

Interpretation Introduction

c) p-(trifluoromethyl)aniline, p-methylaniline, p-(fluoromethyl)aniline

Interpretation:

The compounds p-(trifluoromethyl)aniline, p-methylaniline and p-(fluoromethyl) aniline are to be arranged in the increasing order of their basicity.

Concept introduction:

Amines are basic as they can donate the lone pair if electrons on the N atom. Generally aryl amines are less basic than alkyl amines. An electron withdrawing substituent present on the aromatic ring reduces the base strength while an electron releasing substituent present on the aromatic ring enhances the base strength.

Answer 12

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Ch. 24.1 - Name the following compounds:Ch. 24.1 - Prob. 2P Ch. 24.1 - Prob. 3P Ch. 24.3 - Prob. 4P Ch. 24.3 - The benzylammonium ion (C6H5CH2NH3+) has pKa =...Ch. 24.4 - Prob. 6P Ch. 24.5 - Prob. 7P Ch. 24.6 - Prob. 8P Ch. 24.6 - Prob. 9P Ch. 24.6 - Show two methods for the synthesis of dopamine, a...

Chapter 24 Solutions