Study Guide for Chemistry: The Central Science
13th Edition
ISBN: 9780321949288
Author: Theodore E. Brown, James C. Hill
Publisher: PEARSON
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Chapter 24.4, Problem 24.6.1PE
Interpretation Introduction
To determine: The concentration of H4IO6− at equilibrium for the given ionic reaction.
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Come and compare the Bronsted-Bjerrum calculation, the Debye and Hückel calculation, and the Davies calculation.
plz watch the youtube video (the title of this topic) by roxi H. she explains it step by step but i get the wrong answer
Writing the rate law implied by a simple mechanism
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Suppose the decomposition of ozone proceeds by the following mechanism:
step
elementary reaction
rate constant
1
→>>
O3(9) O2(g) + O(g)
k₁
2
03(g) + O(g)
→
202(g)
k2
Suppose also k₁ »k2. That is, the first step is much faster than the second.
Write the balanced
chemical equation for the
overall chemical reaction:
Write the experimentally-
observable rate law for the
overall chemical reaction.
☐
rate
=
☐
Note: your answer should
not contain the
concentrations of any
intermediates.
Express the rate constant
k for the overall chemical
reaction in terms of K1, K2,
and (if necessary) the rate
constants k-1 and K-2 for
the reverse of the two
elementary reactions in
the mechanism.
k =
☐
000
18
ローロ
Ar
OO
Chapter 24 Solutions
Study Guide for Chemistry: The Central Science
Ch. 24.2 - Prob. 24.1.1PECh. 24.2 - The equilibrium constant Kc for C(s) +CO2 2CO(g)...Ch. 24.2 - Prob. 24.2.1PECh. 24.2 - Le Chatelier noted that many industrial processes...Ch. 24.3 - Prob. 24.3.1PECh. 24.3 - Prob. 24.3.2PECh. 24.3 - [15.91] An equilibrium mixture of H2, I2, and HI...Ch. 24.3 - Consider the hypothetical reaction A(g) + 2B(g) 2...Ch. 24.3 - Prob. 24.5.1PECh. 24.3 - Prob. 24.5.2PE
Ch. 24.4 - Prob. 24.6.1PECh. 24.4 - The following equilibria were measured at 823 K:...Ch. 24.7 - Prob. 24.7.1PECh. 24.7 - Prob. 24.7.2PECh. 24.7 - At 800 K, the equilibrium constant for the...Ch. 24.7 - Prob. 24.8.2PECh. 24 - Practice Exercise 1 A solution at 25° C has pOH =...Ch. 24 - Prob. 1ECh. 24 - Prob. 2ECh. 24 - Practice Exercise 2 Predict whether the...Ch. 24 - Prob. 4ECh. 24 - Prob. 5ECh. 24 - Prob. 6ECh. 24 - Prob. 7ECh. 24 - Prob. 8ECh. 24 - Prob. 9ECh. 24 - Prob. 10ECh. 24 - Prob. 11ECh. 24 - Prob. 12ECh. 24 - Practice Exercise 2 For each reaction, use Figure...Ch. 24 - Practice Exercise 1 In a certain acidic solution...Ch. 24 - Prob. 15ECh. 24 - Prob. 16ECh. 24 - Prob. 17ECh. 24 - Practice Exercise 1 A solution at 250C has [OH-] =...Ch. 24 - Practice Exercise 2 In a sample of lemon juice,...Ch. 24 - Prob. 20ECh. 24 - Prob. 21ECh. 24 - Prob. 22ECh. 24 - Prob. 23ECh. 24 - Practice Exercise 2 Niacin, one of the B vitamins,...Ch. 24 - Prob. 25ECh. 24 - Practice Exercise 2 A 0.020 M solution of niacin...Ch. 24 - Practice Exercise 1 What is the pH of a 0.40 M...Ch. 24 - Practice Exercise 2 The Ka for niacin (Sample...Ch. 24 - Prob. 29ECh. 24 - Practice Exercise 2 Calculate the pH of a 0.020 M...Ch. 24 - Prob. 31ECh. 24 - Practice Exercise 2 Which of the following...Ch. 24 - Prob. 33ECh. 24 - Practice Exercise 2 What is the morality of an...Ch. 24 - Practice Exercise 1 By using information from...Ch. 24 - Practice Exercise 2 Based on information in...Ch. 24 - Prob. 37ECh. 24 - Prob. 38ECh. 24 - Practice Exercise 1 How many of the following...Ch. 24 - In each pair, choose the compound that gives the...Ch. 24 - Prob. 41ECh. 24 - a. Identify the Br ted-Lowry acid and base in the...Ch. 24 - Prob. 43ECh. 24 - Prob. 44ECh. 24 - Prob. 45ECh. 24 - 16.5 The following diagrams represent aqueous...Ch. 24 - Prob. 47ECh. 24 - Which of these statements about how the percent...Ch. 24 - 16.8 Each of the three molecules shown here...Ch. 24 - Prob. 50ECh. 24 - Prob. 51ECh. 24 - Prob. 52ECh. 24 - 16.14 Which of the following statements is...Ch. 24 - Prob. 54ECh. 24 - Prob. 55ECh. 24 - Identify the Bronsted-Lowry acid and the...Ch. 24 - Prob. 57ECh. 24 - Prob. 58ECh. 24 - Prob. 59ECh. 24 - Prob. 60ECh. 24 - Prob. 61ECh. 24 - Prob. 62ECh. 24 - Prob. 63ECh. 24 - Prob. 64ECh. 24 - Prob. 65ECh. 24 - 16.29 Calcualte [H +] for each of the following...Ch. 24 - Prob. 67ECh. 24 - 16.31 At the freezing point of water (0 o C), K10...Ch. 24 - Prob. 69ECh. 24 - 16.35 Complete the following table by calculating...Ch. 24 - Prob. 71ECh. 24 - Prob. 72ECh. 24 - 16.38 Carbon dioxide in the atmosphere dissolves...Ch. 24 - Prob. 74ECh. 24 - Prob. 75ECh. 24 - Prob. 76ECh. 24 - Prob. 77ECh. 24 - Prob. 78ECh. 24 - Prob. 79ECh. 24 - Prob. 80ECh. 24 - Prob. 81AECh. 24 - Prob. 82AECh. 24 - write the chemical equation and the Ka expression...Ch. 24 - Prob. 84AECh. 24 - Prob. 85AECh. 24 - Prob. 86AECh. 24 - Prob. 87AECh. 24 - Prob. 88AECh. 24 - Prob. 89AECh. 24 - Prob. 90AECh. 24 - Prob. 91AECh. 24 - Prob. 92AECh. 24 - Prob. 93AECh. 24 - Calculate the percent ionization of hydrazoic acid...Ch. 24 - Prob. 95IECh. 24 - Prob. 96IECh. 24 - Prob. 97IECh. 24 - Prob. 98IECh. 24 - 16.68 The hypochlorite ion, CIO- , acts as a weak...Ch. 24 - Prob. 100IECh. 24 - Practice Exercise 1 Consider the following...Ch. 24 - Prob. 102IE
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- Deducing a rate law from the change in concentration over time To exit full screen, press and hold esc A chemistry graduate student is studying the rate of this reaction: H2CO3(aq) → H₂O(aq) +CO₂ (aq) - She fills a reaction vessel with H2CO3 and measures its concentration as the reaction proceeds: time (milliseconds) [H2CO3] 0 0.0500 M 10. 0.0266M 20. 0.0181 M 30. 0.0138M 40. 0.0111 M Use this data to answer the following questions. Write the rate law for this reaction. Calculate the value of the rate constant k. Round your answer to 2 significant digits. Also be sure your answer has the correct unit symbol. rate ☐ x10 k = Х 000 18 Ararrow_forwardWriting the rate law implied by a simple mechanism Suppose the formation of tert-butanol proceeds by the following mechanism: step elementary reaction 1 (CH3)3 CBr(aq) → (CH3)2 C* (aq) + Br (aq) 2 (CH3)2C (aq) + OH¯ (aq) → (CH3)2COH(aq) rate constant k₁ k₂ Suppose also k₁ »k2. That is, the first step is much faster than the second. Write the balanced chemical equation for the overall chemical reaction: Write the experimentally- observable rate law for the overall chemical reaction. Note: your answer should not contain the concentrations of any intermediates. rate = k ☐ Express the rate constant k for the overall chemical reaction in terms of K1, K2, and (if necessary) the rate constants k-1 and K-2 for the reverse of the two elementary reactions in the mechanism. k = ☐ □ ☑ G ? 00. 18 Ar Barrow_forwardDeducing a rate law from the change in concentration over time A chemistry graduate student is studying the rate of this reaction: 2SO3 (g) →>> 2SO2 (g) + O2(g) He fills a reaction vessel with SO3 and measures its concentration as the reaction proceeds: ? time (minutes) [SO3] 0 0.0200M 1.0 0.0105 M 2.0 0.00552M 3.0 0.00290M 4.0 0.00152M Use this data to answer the following questions. Write the rate law for this reaction. rate = k ☐ x10 Calculate the value of the rate constant k. Round your answer to 2 significant digits. Also be sure your answer has the correct unit symbol. k = ☐ Х 000 18 Ar BAarrow_forward
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