MASTERING CHEMISTRY:THE CENTRAL SCIENCE
13th Edition
ISBN: 9781269712538
Author: Brown
Publisher: PEARSON
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Chapter 24, Problem 72E
Interpretation Introduction
To determine: The hydrogen ion concentration, hydroxyl ion concentration and
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2. Provide a clear arrow-pushing mechanism for the following reactions. Do not skip proton
transfers, do not combine steps, and make sure your arrows are clear enough to be interpreted
without ambiguity.
a.
CH3
Ph
OEt
هد
Ph
CH3
Hint: the species on the left is an ynolate, which behaves a lot like an enolate.
b.
CH3
H3C
CH3
CH3
H3C
an unexpected product,
containing a single 9-
membered ring
the expected product,
containing two fused rings
H3C-I
(H3C)2CuLi
an enolate
b.
H3C
CH3
1.
2. H3O+
H3C
MgBr
H3C
Chapter 24 Solutions
MASTERING CHEMISTRY:THE CENTRAL SCIENCE
Ch. 24.2 - Prob. 24.1.1PECh. 24.2 - The equilibrium constant Kc for C(s) +CO2 2CO(g)...Ch. 24.2 - Prob. 24.2.1PECh. 24.2 - Le Chatelier noted that many industrial processes...Ch. 24.3 - Prob. 24.3.1PECh. 24.3 - Prob. 24.3.2PECh. 24.3 - [15.91] An equilibrium mixture of H2, I2, and HI...Ch. 24.3 - Consider the hypothetical reaction A(g) + 2B(g) 2...Ch. 24.3 - Prob. 24.5.1PECh. 24.3 - Prob. 24.5.2PE
Ch. 24.4 - Prob. 24.6.1PECh. 24.4 - The following equilibria were measured at 823 K:...Ch. 24.7 - Prob. 24.7.1PECh. 24.7 - Prob. 24.7.2PECh. 24.7 - At 800 K, the equilibrium constant for the...Ch. 24.7 - Prob. 24.8.2PECh. 24 - Practice Exercise 1 A solution at 25° C has pOH =...Ch. 24 - Prob. 1ECh. 24 - Prob. 2ECh. 24 - Practice Exercise 2 Predict whether the...Ch. 24 - Prob. 4ECh. 24 - Prob. 5ECh. 24 - Prob. 6ECh. 24 - Prob. 7ECh. 24 - Prob. 8ECh. 24 - Prob. 9ECh. 24 - Prob. 10ECh. 24 - Prob. 11ECh. 24 - Prob. 12ECh. 24 - Practice Exercise 2 For each reaction, use Figure...Ch. 24 - Practice Exercise 1 In a certain acidic solution...Ch. 24 - Prob. 15ECh. 24 - Prob. 16ECh. 24 - Prob. 17ECh. 24 - Practice Exercise 1 A solution at 250C has [OH-] =...Ch. 24 - Practice Exercise 2 In a sample of lemon juice,...Ch. 24 - Prob. 20ECh. 24 - Prob. 21ECh. 24 - Prob. 22ECh. 24 - Prob. 23ECh. 24 - Practice Exercise 2 Niacin, one of the B vitamins,...Ch. 24 - Prob. 25ECh. 24 - Practice Exercise 2 A 0.020 M solution of niacin...Ch. 24 - Practice Exercise 1 What is the pH of a 0.40 M...Ch. 24 - Practice Exercise 2 The Ka for niacin (Sample...Ch. 24 - Prob. 29ECh. 24 - Practice Exercise 2 Calculate the pH of a 0.020 M...Ch. 24 - Prob. 31ECh. 24 - Practice Exercise 2 Which of the following...Ch. 24 - Prob. 33ECh. 24 - Practice Exercise 2 What is the morality of an...Ch. 24 - Practice Exercise 1 By using information from...Ch. 24 - Practice Exercise 2 Based on information in...Ch. 24 - Prob. 37ECh. 24 - Prob. 38ECh. 24 - Practice Exercise 1 How many of the following...Ch. 24 - In each pair, choose the compound that gives the...Ch. 24 - Prob. 41ECh. 24 - a. Identify the Br ted-Lowry acid and base in the...Ch. 24 - Prob. 43ECh. 24 - Prob. 44ECh. 24 - Prob. 45ECh. 24 - 16.5 The following diagrams represent aqueous...Ch. 24 - Prob. 47ECh. 24 - Which of these statements about how the percent...Ch. 24 - 16.8 Each of the three molecules shown here...Ch. 24 - Prob. 50ECh. 24 - Prob. 51ECh. 24 - Prob. 52ECh. 24 - 16.14 Which of the following statements is...Ch. 24 - Prob. 54ECh. 24 - Prob. 55ECh. 24 - Identify the Bronsted-Lowry acid and the...Ch. 24 - Prob. 57ECh. 24 - Prob. 58ECh. 24 - Prob. 59ECh. 24 - Prob. 60ECh. 24 - Prob. 61ECh. 24 - Prob. 62ECh. 24 - Prob. 63ECh. 24 - Prob. 64ECh. 24 - Prob. 65ECh. 24 - 16.29 Calcualte [H +] for each of the following...Ch. 24 - Prob. 67ECh. 24 - 16.31 At the freezing point of water (0 o C), K10...Ch. 24 - Prob. 69ECh. 24 - 16.35 Complete the following table by calculating...Ch. 24 - Prob. 71ECh. 24 - Prob. 72ECh. 24 - 16.38 Carbon dioxide in the atmosphere dissolves...Ch. 24 - Prob. 74ECh. 24 - Prob. 75ECh. 24 - Prob. 76ECh. 24 - Prob. 77ECh. 24 - Prob. 78ECh. 24 - Prob. 79ECh. 24 - Prob. 80ECh. 24 - Prob. 81AECh. 24 - Prob. 82AECh. 24 - write the chemical equation and the Ka expression...Ch. 24 - Prob. 84AECh. 24 - Prob. 85AECh. 24 - Prob. 86AECh. 24 - Prob. 87AECh. 24 - Prob. 88AECh. 24 - Prob. 89AECh. 24 - Prob. 90AECh. 24 - Prob. 91AECh. 24 - Prob. 92AECh. 24 - Prob. 93AECh. 24 - Calculate the percent ionization of hydrazoic acid...Ch. 24 - Prob. 95IECh. 24 - Prob. 96IECh. 24 - Prob. 97IECh. 24 - Prob. 98IECh. 24 - 16.68 The hypochlorite ion, CIO- , acts as a weak...Ch. 24 - Prob. 100IECh. 24 - Practice Exercise 1 Consider the following...Ch. 24 - Prob. 102IE
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- Predict the major products of this reaction: excess H+ NaOH ? A Note that the first reactant is used in excess, that is, there is much more of the first reactant than the second. If there won't be any products, just check the box under the drawing area instead. Explanation Check Click and drag to start drawing a structure. © 2025 McGraw Hill LLC. All Rights Reserved. Terms of Use Privarrow_forward1. For each of the reaction "railroads" below, you are either asked to give the structure(s) of the starting material(s) or product(s), or provide reagents/conditions to accomplish the transformation, as indicated by the boxes. a. NaOMe H+ .CO,H HO₂C MeOH (excess) MeOH H3C Br يع CH3 1. LiAlH4 2. H3O+ 3. PBг3 H3C 1. Et-Li 2. H3O+ -CO₂Me -CO₂Me OH CH3 CH3 ল CH3arrow_forwardPredict the intermediate 1 and final product 2 of this organic reaction: NaOMe ག1, ད།་, - + H You can draw 1 and 2 in any arrangement you like. 2 work up Note: if either 1 or 2 consists of a pair of enantiomers, just draw one structure using line bonds instead of 3D (dash and wedge) bonds at the chiral center. Explanation Check Click and drag to start drawing a structure. Х © 2025 McGraw Hill LLC. All Rights Reserved. Terms of Use | Parrow_forward
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- Rank the following compounds in order of decreasing boiling point. ннннн -С-С-Н . н-с- ННННН H ΗΤΗ НННН TTTĪ н-с-с-с-с-о-н НННН НН C' Н н-с-с-с-с-н НН || Ш НННН H-C-C-C-C-N-H ННННН IVarrow_forwardRank the following compounds in order of decreasing dipole moment. |>||>||| ||>|||>| |>|||>|| |||>||>| O ||>>||| H F H F H c=c || H c=c F F IIIarrow_forwardchoose the description that best describes the geometry for the following charged species ch3-arrow_forward
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