
Concept explainers
(a)
Interpretation:
The formula of the complex ion of name cupric tetraamine ion needs to be determined.
Concept introduction:
Naming of complex ions is done as per the set of rules wherein the oxidation number of metal ions are needed to be indicated in the form of a Roman numeral. Besides, ligands are to be named before the metal ion and in a specific order as neutral, negative and positive. The number of ligands is indicated by prefix di, tri, tetra, penta, etc. The anions end with −ido that replaces ‘e’ and in some cases ‘o’ replaces ‘e’. For example,
(b)
Interpretation:
The formula of the complex ion of name dichlorotetraammine cobaltic chloride needs to be determined.
Concept introduction:
There are a certain set of rules for naming complex in which the oxidation number of metal ions is depicted as Roman numerals. Ligands are named in order of neutral, negative and positive and are before the metal ions as well. The number of ligands is indicated by prefix di, tri, tetra, penta, etc. For example: amines are termed as ammine, water as aqua and NO as nitrosyl and CO and carbonyl.
(c)
Interpretation:
The formula of the complex ion of name platinic(IV) hexachloride ion needs to be determined.
Concept introduction:
As per naming rules, the metal ions are depicted with its oxidation number in the form of a Roman numeral. Ligands are identified in their specific order as neutral, negative and positive. Besides, it is named before the metal ion. The number of ligands is identified using terms like di, tri, tetra, Penta, etc. Also, anions ending with ‘e’ are changed with ‘o’. Also, molecules like amine are called as ammine, water molecules called as aqua.
(d)
Interpretation:
The formula of the complex ion of the name disodium copper tetrachloride needs to be determined.
Concept introduction:
The metal ions are depicted with its oxidation number in the form of the Roman numeral as per naming rules. Ligands are usually named after metal ions and are identified in order as neutral, negative and positive. The numbering of ligands is termed as di, tri, tetra, penta, etc. Anions that end with ‘e’ are changed with an ‘o’. Molecules like amine when in the ligand is called as ammine, water molecules are called as aqua.
(e)
Interpretation:
The formula of the complex ion of the name dipotassium antimony(III) pentachloride needs to be determined.
Concept introduction:
Based on naming rules, the metal ions are depicted with its oxidation number in the form of a Roman numeral. Also, the ligands are named after metal ions and are identified in order as neutral, negative and positive. The numbering of ligands is di, tri, tetra, penta, etc based on the number of ligands attached. Anions ending with ‘e’ gets changed with an ‘o’. Molecules like amine is called as ammine, water molecules are called as aqua.

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Chapter 24 Solutions
EBK GENERAL CHEMISTRY
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- DE d. Draw an arrow pushing mechanism for the following IN O CI N fo 人 P Polle DELL prt sc home end ins F5 F6 F7 F8 F9 F10 F11 F12arrow_forwardPredict the products of this organic reaction: + H₂O H* ? A Specifically, in the drawing area below draw the skeletal ("line") structure of the product, or products, of this reaction. (If there's more than one product, draw them in any arrangement you like, so long as they aren't touching.) If there aren't any products because this reaction won't happen, check the No reaction box under the drawing area. No Reaction Click and drag to start drawing a structure.arrow_forwardPredict the major organic products of the reaction below and draw them on right side of the arrow. If there will be no significant reaction, check the box below the drawing area instead. C Cl CH, OH There will be no significant reaction. + pyridine G Click and drag to start drawing a structure.arrow_forward
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