
Concept explainers
(a)
Interpretation:
Nuclear reaction for the alpha decay of
Concept Introduction:
Balancing nuclear reaction equation: The balanced nuclear reaction should conserve both mass number and atomic number.
- The sum of the mass numbers of the reactants should be equal to the sum of mass numbers of the products in the reaction.
- The sum of
atomic numbers (or the atomic charge) of the reactants should be equal to the sum of atomic numbers (or the atomic charge) of the products in the reaction.
(b)
Interpretation:
Nuclear reaction for the electron capture by neptunium-232 has to be balanced.
Concept Introduction:
Balancing nuclear reaction equation: The balanced nuclear reaction should conserve both mass number and atomic number.
- The sum of the mass numbers of the reactants should be equal to the sum of mass numbers of the products in the reaction.
- The sum of atomic numbers (or the atomic charge) of the reactants should be equal to the sum of atomic numbers (or the atomic charge) of the products in the reaction.
(c)
Interpretation:
Nuclear reaction for the positron emission of
Concept Introduction:
Balancing nuclear reaction equation: The balanced nuclear reaction should conserve both mass number and atomic number.
- The sum of the mass numbers of the reactants should be equal to the sum of mass numbers of the products in the reaction.
- The sum of atomic numbers (or the atomic charge) of the reactants should be equal to the sum of atomic numbers (or the atomic charge) of the products in the reaction.

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Chapter 24 Solutions
CONNECT ACCESS CARD FOR CHEMISTRY: MOLECULAR NATURE OF MATTER AND CHANGE
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- Draw the mechanism for the following Friedel-Craft reaction. AlBr3 Brarrow_forward(a) Draw the structures of A and B in the following reaction. (i) NaNH2, NH3(1) A + B (ii) H3O+arrow_forwardFor the reaction 2 N2O5(g) → 4 NO2(g) + O2(g), the following mechanism has been proposed: N2O5 →> NO₂+ NO3_(K1) NO2 + NO3 → N2O5 (k-1) NO2 + NO3 → → NO2 + O2 + NO (K2) NO + N2O5- NO2 + NO2 + NO2 (K3) d[N₂O5] __2k‚k₂[N2O5] Indicate whether the following rate expression is acceptable: dt k₁₁+ k₂arrow_forward
- Consider the following decomposition reaction of N2O5(g): For the reaction 2 N2O5(g) → 4 NO2(g) + O2(g), the following mechanism has been proposed: N2O5 → NO2 + NO3 (K1) NO2 + NO3 → N2O5 (k-1) NO2 + NO3 → NO2 + O2 + NO (K2) NO + N2O5 → NO2 + NO2 + NO2 (K3) Indicate whether the following rate expression is acceptable: d[N2O5] = -k₁[N₂O₂] + K¸₁[NO₂][NO3] - K¸[NO₂]³ dtarrow_forwardIn a reaction of A + B to give C, another compound other than A, B or C may appear in the kinetic equation.arrow_forwardFor the reaction 2 N2O5(g) → 4 NO2(g) + O2(g), the following mechanism has been proposed: N2O5 →> NO₂+ NO3_(K1) NO2 + NO3 → N2O5 (k-1) NO2 + NO3 → → NO2 + O2 + NO (K2) NO + N2O5- NO2 + NO2 + NO2 (K3) d[N₂O5] __2k‚k₂[N2O5] Indicate whether the following rate expression is acceptable: dt k₁₁+ k₂arrow_forward
- Given the reaction R + Q → P, indicate the rate law with respect to R, with respect to P and with respect to P.arrow_forwardSteps and explanations. Also provide, if possible, ways to adress this kind of problems in general.arrow_forwardk₁ Given the reaction A B, indicate k-1 d[A] (A). the rate law with respect to A: (B). the rate law with respect to B: d[B] dt dtarrow_forward
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