(a) Interpretation: Synthesis of the following compound using ethene and buta-1, 3-diene as the only source of carbon is to be proposed. Concept introduction: The product has 10 carbon atoms while the starting material has four and two carbon atoms. This means that the reaction that alters the carbon skeleton must occur. The retrosynthetic approach suggests the reaction to be two back-to-back Diels-Alder reaction.

Question

Blocking Group are use to put 2 large sterically repulsive group ortho. Show the correct sequence toconnect the reagent to product with the highest yield possible. * see image **NOTE: The compound on the left is the starting point, and the compound on the right is the final product. Please show the steps in between to get from start to final, please. These are not two different compounds that need to be worked.

Answer 1

Question

Chapter 24, Problem 24.79P

Interpretation Introduction

(a)

Interpretation:

Synthesis of the following compound using ethene and buta-1, 3-diene as the only source of carbon is to be proposed.

Concept introduction:

The product has 10 carbon atoms while the starting material has four and two carbon atoms. This means that the reaction that alters the carbon skeleton must occur. The retrosynthetic approach suggests the reaction to be two back-to-back Diels-Alder reaction.

Interpretation Introduction

(b)

Interpretation:

Synthesis of the following compound using ethene and buta-1, 3-diene as the only source of carbon is to be proposed.

Concept introduction:

The product has 6 carbon atoms while the starting material has four and two carbon atoms. Hence there must be one reaction that alters the carbon skeleton. Target product is a chain with OH functional group at the terminal position. Retrosynthetic approach suggests that the formation of the product through Diels-Alder reaction is followed by oxidative cleavage and reduction.

Interpretation Introduction

(c)

Interpretation:

Synthesis of the following compound using ethene and buta-1, 3-diene as the only source of carbon is to be proposed.

Concept introduction:

The product has 6 carbon atoms while the starting material has four and two carbon atoms. This suggests that one reaction to alter carbon skeleton must occur. Retrosynthesis suggests the formation of β- hydroxy aldehyde via aldol reaction. The precursor for this reaction must be 1, 6-dialdehyde.

Interpretation Introduction

(d)

Interpretation:

Synthesis of the following compound using ethene and buta-1, 3-diene as the only source of carbon is to be proposed.

Concept introduction:

The product has 10 carbon atoms while the starting material has four and two carbon atoms. This suggests that two reactions that alter carbon skeleton must occur. The retrosynthesis of the target suggests it to be a product of Diels-Alder reaction. The two precursors of Diels alder reaction must be butadiene and an aldehyde.

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Blocking Group are use to put 2 large sterically repulsive group ortho. Show the correct sequence toconnect the reagent to product with the highest yield possible. * see image **NOTE: The compound on the left is the starting point, and the compound on the right is the final product. Please show the steps in between to get from start to final, please. These are not two different compounds that need to be worked.

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Can you please explain this prooblem to me, show me how the conjugation is added, did I add them in the correct places and if so please show me. Thanks!

Answer 2

Question

Chapter 24, Problem 24.79P

Interpretation Introduction

(a)

Interpretation:

Synthesis of the following compound using ethene and buta-1, 3-diene as the only source of carbon is to be proposed.

Concept introduction:

The product has 10 carbon atoms while the starting material has four and two carbon atoms. This means that the reaction that alters the carbon skeleton must occur. The retrosynthetic approach suggests the reaction to be two back-to-back Diels-Alder reaction.

Interpretation Introduction

(b)

Interpretation:

Synthesis of the following compound using ethene and buta-1, 3-diene as the only source of carbon is to be proposed.

Concept introduction:

The product has 6 carbon atoms while the starting material has four and two carbon atoms. Hence there must be one reaction that alters the carbon skeleton. Target product is a chain with OH functional group at the terminal position. Retrosynthetic approach suggests that the formation of the product through Diels-Alder reaction is followed by oxidative cleavage and reduction.

Interpretation Introduction

(c)

Interpretation:

Synthesis of the following compound using ethene and buta-1, 3-diene as the only source of carbon is to be proposed.

Concept introduction:

The product has 6 carbon atoms while the starting material has four and two carbon atoms. This suggests that one reaction to alter carbon skeleton must occur. Retrosynthesis suggests the formation of β- hydroxy aldehyde via aldol reaction. The precursor for this reaction must be 1, 6-dialdehyde.

Interpretation Introduction

(d)

Interpretation:

Synthesis of the following compound using ethene and buta-1, 3-diene as the only source of carbon is to be proposed.

Concept introduction:

The product has 10 carbon atoms while the starting material has four and two carbon atoms. This suggests that two reactions that alter carbon skeleton must occur. The retrosynthesis of the target suggests it to be a product of Diels-Alder reaction. The two precursors of Diels alder reaction must be butadiene and an aldehyde.

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Answer 3

Question

Chapter 24, Problem 24.79P

Interpretation Introduction

(a)

Interpretation:

Synthesis of the following compound using ethene and buta-1, 3-diene as the only source of carbon is to be proposed.

Concept introduction:

The product has 10 carbon atoms while the starting material has four and two carbon atoms. This means that the reaction that alters the carbon skeleton must occur. The retrosynthetic approach suggests the reaction to be two back-to-back Diels-Alder reaction.

Interpretation Introduction

(b)

Interpretation:

Synthesis of the following compound using ethene and buta-1, 3-diene as the only source of carbon is to be proposed.

Concept introduction:

The product has 6 carbon atoms while the starting material has four and two carbon atoms. Hence there must be one reaction that alters the carbon skeleton. Target product is a chain with OH functional group at the terminal position. Retrosynthetic approach suggests that the formation of the product through Diels-Alder reaction is followed by oxidative cleavage and reduction.

Interpretation Introduction

(c)

Interpretation:

Synthesis of the following compound using ethene and buta-1, 3-diene as the only source of carbon is to be proposed.

Concept introduction:

The product has 6 carbon atoms while the starting material has four and two carbon atoms. This suggests that one reaction to alter carbon skeleton must occur. Retrosynthesis suggests the formation of β- hydroxy aldehyde via aldol reaction. The precursor for this reaction must be 1, 6-dialdehyde.

Interpretation Introduction

(d)

Interpretation:

Synthesis of the following compound using ethene and buta-1, 3-diene as the only source of carbon is to be proposed.

Concept introduction:

The product has 10 carbon atoms while the starting material has four and two carbon atoms. This suggests that two reactions that alter carbon skeleton must occur. The retrosynthesis of the target suggests it to be a product of Diels-Alder reaction. The two precursors of Diels alder reaction must be butadiene and an aldehyde.

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Answer 4

Question

Chapter 24, Problem 24.79P

Interpretation Introduction

(a)

Interpretation:

Synthesis of the following compound using ethene and buta-1, 3-diene as the only source of carbon is to be proposed.

Concept introduction:

The product has 10 carbon atoms while the starting material has four and two carbon atoms. This means that the reaction that alters the carbon skeleton must occur. The retrosynthetic approach suggests the reaction to be two back-to-back Diels-Alder reaction.

Interpretation Introduction

(b)

Interpretation:

Synthesis of the following compound using ethene and buta-1, 3-diene as the only source of carbon is to be proposed.

Concept introduction:

The product has 6 carbon atoms while the starting material has four and two carbon atoms. Hence there must be one reaction that alters the carbon skeleton. Target product is a chain with OH functional group at the terminal position. Retrosynthetic approach suggests that the formation of the product through Diels-Alder reaction is followed by oxidative cleavage and reduction.

Interpretation Introduction

(c)

Interpretation:

Synthesis of the following compound using ethene and buta-1, 3-diene as the only source of carbon is to be proposed.

Concept introduction:

The product has 6 carbon atoms while the starting material has four and two carbon atoms. This suggests that one reaction to alter carbon skeleton must occur. Retrosynthesis suggests the formation of β- hydroxy aldehyde via aldol reaction. The precursor for this reaction must be 1, 6-dialdehyde.

Interpretation Introduction

(d)

Interpretation:

Synthesis of the following compound using ethene and buta-1, 3-diene as the only source of carbon is to be proposed.

Concept introduction:

The product has 10 carbon atoms while the starting material has four and two carbon atoms. This suggests that two reactions that alter carbon skeleton must occur. The retrosynthesis of the target suggests it to be a product of Diels-Alder reaction. The two precursors of Diels alder reaction must be butadiene and an aldehyde.

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Answer 5

Chapter 24, Problem 24.79P

Interpretation Introduction

(a)

Interpretation:

Synthesis of the following compound using ethene and buta-1, 3-diene as the only source of carbon is to be proposed.

Concept introduction:

The product has 10 carbon atoms while the starting material has four and two carbon atoms. This means that the reaction that alters the carbon skeleton must occur. The retrosynthetic approach suggests the reaction to be two back-to-back Diels-Alder reaction.

Interpretation Introduction

(b)

Interpretation:

Synthesis of the following compound using ethene and buta-1, 3-diene as the only source of carbon is to be proposed.

Concept introduction:

The product has 6 carbon atoms while the starting material has four and two carbon atoms. Hence there must be one reaction that alters the carbon skeleton. Target product is a chain with OH functional group at the terminal position. Retrosynthetic approach suggests that the formation of the product through Diels-Alder reaction is followed by oxidative cleavage and reduction.

Interpretation Introduction

(c)

Interpretation:

Synthesis of the following compound using ethene and buta-1, 3-diene as the only source of carbon is to be proposed.

Concept introduction:

The product has 6 carbon atoms while the starting material has four and two carbon atoms. This suggests that one reaction to alter carbon skeleton must occur. Retrosynthesis suggests the formation of β- hydroxy aldehyde via aldol reaction. The precursor for this reaction must be 1, 6-dialdehyde.

Interpretation Introduction

(d)

Interpretation:

Synthesis of the following compound using ethene and buta-1, 3-diene as the only source of carbon is to be proposed.

Concept introduction:

The product has 10 carbon atoms while the starting material has four and two carbon atoms. This suggests that two reactions that alter carbon skeleton must occur. The retrosynthesis of the target suggests it to be a product of Diels-Alder reaction. The two precursors of Diels alder reaction must be butadiene and an aldehyde.

Answer 6

Chapter 24, Problem 24.79P

Interpretation Introduction

(a)

Interpretation:

Synthesis of the following compound using ethene and buta-1, 3-diene as the only source of carbon is to be proposed.

Concept introduction:

The product has 10 carbon atoms while the starting material has four and two carbon atoms. This means that the reaction that alters the carbon skeleton must occur. The retrosynthetic approach suggests the reaction to be two back-to-back Diels-Alder reaction.

Answer 7

Chapter 24, Problem 24.79P

Interpretation Introduction

(a)

Interpretation:

Synthesis of the following compound using ethene and buta-1, 3-diene as the only source of carbon is to be proposed.

Concept introduction:

The product has 10 carbon atoms while the starting material has four and two carbon atoms. This means that the reaction that alters the carbon skeleton must occur. The retrosynthetic approach suggests the reaction to be two back-to-back Diels-Alder reaction.

Answer 8

Interpretation Introduction

(b)

Interpretation:

Synthesis of the following compound using ethene and buta-1, 3-diene as the only source of carbon is to be proposed.

Concept introduction:

The product has 6 carbon atoms while the starting material has four and two carbon atoms. Hence there must be one reaction that alters the carbon skeleton. Target product is a chain with OH functional group at the terminal position. Retrosynthetic approach suggests that the formation of the product through Diels-Alder reaction is followed by oxidative cleavage and reduction.

Answer 9

Interpretation Introduction

(b)

Interpretation:

Synthesis of the following compound using ethene and buta-1, 3-diene as the only source of carbon is to be proposed.

Concept introduction:

The product has 6 carbon atoms while the starting material has four and two carbon atoms. Hence there must be one reaction that alters the carbon skeleton. Target product is a chain with OH functional group at the terminal position. Retrosynthetic approach suggests that the formation of the product through Diels-Alder reaction is followed by oxidative cleavage and reduction.

Answer 10

Interpretation Introduction

(c)

Interpretation:

Synthesis of the following compound using ethene and buta-1, 3-diene as the only source of carbon is to be proposed.

Concept introduction:

The product has 6 carbon atoms while the starting material has four and two carbon atoms. This suggests that one reaction to alter carbon skeleton must occur. Retrosynthesis suggests the formation of β- hydroxy aldehyde via aldol reaction. The precursor for this reaction must be 1, 6-dialdehyde.

Answer 11

Interpretation Introduction

(c)

Interpretation:

Synthesis of the following compound using ethene and buta-1, 3-diene as the only source of carbon is to be proposed.

Concept introduction:

The product has 6 carbon atoms while the starting material has four and two carbon atoms. This suggests that one reaction to alter carbon skeleton must occur. Retrosynthesis suggests the formation of β- hydroxy aldehyde via aldol reaction. The precursor for this reaction must be 1, 6-dialdehyde.

Answer 12

Interpretation Introduction

(d)

Interpretation:

Synthesis of the following compound using ethene and buta-1, 3-diene as the only source of carbon is to be proposed.

Concept introduction:

The product has 10 carbon atoms while the starting material has four and two carbon atoms. This suggests that two reactions that alter carbon skeleton must occur. The retrosynthesis of the target suggests it to be a product of Diels-Alder reaction. The two precursors of Diels alder reaction must be butadiene and an aldehyde.

Answer 13

Interpretation Introduction

(d)

Interpretation:

Synthesis of the following compound using ethene and buta-1, 3-diene as the only source of carbon is to be proposed.

Concept introduction:

The product has 10 carbon atoms while the starting material has four and two carbon atoms. This suggests that two reactions that alter carbon skeleton must occur. The retrosynthesis of the target suggests it to be a product of Diels-Alder reaction. The two precursors of Diels alder reaction must be butadiene and an aldehyde.

Answer 14

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Answer 25

Ch. 24 - Prob. 24.1P Ch. 24 - Prob. 24.2P Ch. 24 - Prob. 24.3P Ch. 24 - Prob. 24.4P Ch. 24 - Prob. 24.5P Ch. 24 - Prob. 24.6P Ch. 24 - Prob. 24.7P Ch. 24 - Prob. 24.8P Ch. 24 - Prob. 24.9P Ch. 24 - Prob. 24.10P

Chapter 24 Solutions