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CHEMISTRY:MOLECULAR...(LL)-W/CONNECT
9th Edition
ISBN: 9781264094202
Author: SILBERBERG
Publisher: MCG
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Question
Chapter 24, Problem 24.135P
Interpretation Introduction
Interpretation:
Age of the Egyptian mummy case has to be determined using the given information.
Concept Introduction:
The half–life period for first order reaction is as follows:
Integrated rate law for a first order reaction is given below
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Students have asked these similar questions
Use the References to access important values if needed for this question.
What is the IUPAC name of each of the the following?
0
CH3CHCNH₂
CH3
CH3CHCNHCH2CH3
CH3
You have now performed a liquid-liquid extraction protocol in Experiment 4. In doing so, you
manipulated and exploited the acid-base chemistry of one or more of the compounds in your
mixture to facilitate their separation into different phases. The key to understanding how liquid-
liquid extractions work is by knowing which layer a compound is in, and in what protonation state.
The following liquid-liquid extraction is different from the one you performed in Experiment
4, but it uses the same type of logic. Your task is to show how to separate apart Compound
A and Compound B.
. Complete the following flowchart of a liquid-liquid extraction. Handwritten work is
encouraged.
•
Draw by hand (neatly) only the appropriate organic compound(s) in the boxes.
.
Specify the reagent(s)/chemicals (name is fine) and concentration as required in Boxes 4
and 5.
•
Box 7a requires the solvent (name is fine).
•
Box 7b requires one inorganic compound.
• You can neatly complete this assignment by hand and…
b) Elucidate compound D w) mt at 170 nd shows c-1 stretch at 550cm;'
The compound has the ff electronic transitions: 0%o* and no a*
1H NMR Spectrum
(CDCl3, 400 MHz)
3.5
3.0
2.5
2.0
1.5
1.0
0.5 ppm
13C{H} NMR Spectrum
(CDCl3, 100 MHz)
Solvent
80
70
60
50
40
30
20
10
0 ppm
ppm
¹H-13C me-HSQC Spectrum
ppm
(CDCl3, 400 MHz)
5
¹H-¹H COSY Spectrum
(CDCl3, 400 MHz)
0.5
10
3.5
3.0
2.5
2.0
1.5 1.0
10
15
20
20
25
30
30
-35
-1.0
1.5
-2.0
-2.5
3.0
-3.5
0.5
ppm
3.5
3.0
2.5
2.0
1.5
1.0
0.5
ppm
Chapter 24 Solutions
CHEMISTRY:MOLECULAR...(LL)-W/CONNECT
Ch. 24.1 - Prob. 24.1AFPCh. 24.1 - Prob. 24.1BFPCh. 24.1 - Prob. 24.2AFPCh. 24.1 - Why is stable but unstable?
Ch. 24.1 - Prob. 24.3AFPCh. 24.1 - Prob. 24.3BFPCh. 24.2 - Prob. 24.4AFPCh. 24.2 - Prob. 24.4BFPCh. 24.2 - Prob. 24.5AFPCh. 24.2 - Prob. 24.5BFP
Ch. 24.2 - Prob. 24.6AFPCh. 24.2 - Prob. 24.6BFPCh. 24.3 - Prob. 24.7AFPCh. 24.3 - Prob. 24.7BFPCh. 24.6 - Prob. 24.8AFPCh. 24.6 - Prob. 24.8BFPCh. 24 - Prob. 24.1PCh. 24 - Prob. 24.2PCh. 24 - Prob. 24.3PCh. 24 - Prob. 24.4PCh. 24 - Prob. 24.5PCh. 24 - Prob. 24.6PCh. 24 - Prob. 24.7PCh. 24 - Prob. 24.8PCh. 24 - Prob. 24.9PCh. 24 - Prob. 24.10PCh. 24 - Prob. 24.11PCh. 24 - Prob. 24.12PCh. 24 - Prob. 24.13PCh. 24 - Prob. 24.14PCh. 24 - Prob. 24.15PCh. 24 - Prob. 24.16PCh. 24 - Prob. 24.17PCh. 24 - Prob. 24.18PCh. 24 - Prob. 24.19PCh. 24 - Prob. 24.20PCh. 24 - Prob. 24.21PCh. 24 - Prob. 24.22PCh. 24 - Prob. 24.23PCh. 24 - Prob. 24.24PCh. 24 - Prob. 24.25PCh. 24 - Prob. 24.26PCh. 24 - Prob. 24.27PCh. 24 - Prob. 24.28PCh. 24 - Prob. 24.29PCh. 24 - Prob. 24.30PCh. 24 - Prob. 24.31PCh. 24 - Prob. 24.32PCh. 24 - Prob. 24.33PCh. 24 - Prob. 24.34PCh. 24 - Prob. 24.35PCh. 24 - Prob. 24.36PCh. 24 - Prob. 24.37PCh. 24 - Prob. 24.38PCh. 24 - Prob. 24.39PCh. 24 - Prob. 24.40PCh. 24 - Prob. 24.41PCh. 24 - Prob. 24.42PCh. 24 - Prob. 24.43PCh. 24 - Prob. 24.44PCh. 24 - Prob. 24.45PCh. 24 - Prob. 24.46PCh. 24 - Prob. 24.47PCh. 24 - Prob. 24.48PCh. 24 - Prob. 24.49PCh. 24 - Prob. 24.50PCh. 24 - Prob. 24.51PCh. 24 - Prob. 24.52PCh. 24 - Prob. 24.53PCh. 24 - Prob. 24.54PCh. 24 - Prob. 24.55PCh. 24 - Prob. 24.56PCh. 24 - Prob. 24.57PCh. 24 - Prob. 24.58PCh. 24 - Prob. 24.59PCh. 24 - Prob. 24.60PCh. 24 - Prob. 24.61PCh. 24 - Prob. 24.62PCh. 24 - Prob. 24.63PCh. 24 - Prob. 24.64PCh. 24 - Prob. 24.65PCh. 24 - Prob. 24.66PCh. 24 - Prob. 24.67PCh. 24 - Prob. 24.68PCh. 24 - Prob. 24.69PCh. 24 - Prob. 24.70PCh. 24 - Prob. 24.71PCh. 24 - Prob. 24.72PCh. 24 - Prob. 24.73PCh. 24 - Prob. 24.74PCh. 24 - Prob. 24.75PCh. 24 - Prob. 24.76PCh. 24 - Prob. 24.77PCh. 24 - Prob. 24.78PCh. 24 - Prob. 24.79PCh. 24 - Prob. 24.80PCh. 24 - Prob. 24.81PCh. 24 - Prob. 24.82PCh. 24 - Prob. 24.83PCh. 24 - Prob. 24.84PCh. 24 - Prob. 24.85PCh. 24 - Prob. 24.86PCh. 24 - Prob. 24.87PCh. 24 - Prob. 24.88PCh. 24 - Prob. 24.89PCh. 24 - Prob. 24.90PCh. 24 - Prob. 24.91PCh. 24 - Prob. 24.92PCh. 24 - Prob. 24.93PCh. 24 - Prob. 24.94PCh. 24 - Prob. 24.95PCh. 24 - Prob. 24.96PCh. 24 - Prob. 24.97PCh. 24 - Prob. 24.98PCh. 24 - Prob. 24.99PCh. 24 - Prob. 24.100PCh. 24 - Prob. 24.101PCh. 24 - Prob. 24.102PCh. 24 - Prob. 24.103PCh. 24 - Prob. 24.104PCh. 24 - Prob. 24.105PCh. 24 - Prob. 24.106PCh. 24 - Prob. 24.107PCh. 24 - Prob. 24.108PCh. 24 - Prob. 24.109PCh. 24 - Prob. 24.110PCh. 24 - Prob. 24.111PCh. 24 - Prob. 24.112PCh. 24 - Prob. 24.113PCh. 24 - Prob. 24.114PCh. 24 - Prob. 24.115PCh. 24 - Prob. 24.116PCh. 24 - Prob. 24.117PCh. 24 - Prob. 24.118PCh. 24 - Prob. 24.119PCh. 24 - Prob. 24.120PCh. 24 - Prob. 24.121PCh. 24 - Prob. 24.122PCh. 24 - Prob. 24.123PCh. 24 - Prob. 24.124PCh. 24 - Prob. 24.125PCh. 24 - Prob. 24.126PCh. 24 - Prob. 24.127PCh. 24 - Prob. 24.128PCh. 24 - Prob. 24.129PCh. 24 - Prob. 24.130PCh. 24 - Prob. 24.131PCh. 24 - Prob. 24.132PCh. 24 - Prob. 24.133PCh. 24 - Prob. 24.134PCh. 24 - Prob. 24.135PCh. 24 - Prob. 24.136PCh. 24 - Prob. 24.137PCh. 24 - Prob. 24.138PCh. 24 - Prob. 24.139PCh. 24 - Prob. 24.140PCh. 24 - Prob. 24.141PCh. 24 - Prob. 24.142PCh. 24 - Prob. 24.143PCh. 24 - Prob. 24.144P
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Similar questions
- Part I. a) Elucidate the structure of compound A using the following information. • mass spectrum: m+ = 102, m/2=57 312=29 • IR spectrum: 1002.5 % TRANSMITTANCE Ngg 50 40 30 20 90 80 70 60 MICRONS 5 8 9 10 12 13 14 15 16 19 1740 cm M 10 0 4000 3600 3200 2800 2400 2000 1800 1600 13 • CNMR 'H -NMR Peak 8 ppm (H) Integration multiplicity a 1.5 (3H) triplet b 1.3 1.5 (3H) triplet C 2.3 1 (2H) quartet d 4.1 1 (2H) quartet & ppm (c) 10 15 28 60 177 (C=0) b) Elucidate the structure of compound B using the following information 13C/DEPT NMR 150.9 MHz IIL 1400 WAVENUMBERS (CM-1) DEPT-90 DEPT-135 85 80 75 70 65 60 55 50 45 40 35 30 25 20 ppm 1200 1000 800 600 400arrow_forward• Part II. a) Elucidate The structure of compound c w/ molecular formula C10 11202 and the following data below: • IR spectra % TRANSMITTANCE 1002.5 90 80 70 60 50 40 30 20 10 0 4000 3600 3200 2800 2400 2000 1800 1600 • Information from 'HAMR MICRONS 8 9 10 11 14 15 16 19 25 1400 WAVENUMBERS (CM-1) 1200 1000 800 600 400 peak 8 ppm Integration multiplicity a 2.1 1.5 (3H) Singlet b 3.6 1 (2H) singlet с 3.8 1.5 (3H) Singlet d 6.8 1(2H) doublet 7.1 1(2H) doublet Information from 13C-nmR Normal carbon 29ppm Dept 135 Dept -90 + NO peak NO peak 50 ppm 55 ppm + NO peak 114 ppm t 126 ppm No peak NO peak 130 ppm t + 159 ppm No peak NO peak 207 ppm по реак NO peakarrow_forwardCould you redraw these and also explain how to solve them for me pleasarrow_forward
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