Organic Chemistry
Organic Chemistry
3rd Edition
ISBN: 9781119316152
Author: Klein, David R.
Publisher: WILEY
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Chapter 23.9, Problem 32ATS

(a)

Interpretation Introduction

Interpretation:

The coupling product obtained by treating the given compound with Grubbs catalyst should be identified.

Concept Introduction:

Grubbs catalyst: This catalyst is used to achieve alkene metathesis.  It contain transition metal namely Ru which is doubly bonded with carbon atom.

  Organic Chemistry, Chapter 23.9, Problem 32ATS , additional homework tip  1

Alkene metathesis: It involves two stages first; the starting material in presence of catalyst forms two possible intermediates.  Next the intermediates react with the starting material and results to form product.

(b)

Interpretation Introduction

Interpretation:

The coupling product obtained by treating the given compound with Grubbs catalyst should be identified.

Concept Introduction:

Grubbs catalyst: This catalyst is used to achieve alkene metathesis.  It contain transition metal namely Ru which is doubly bonded with carbon atom.

  Organic Chemistry, Chapter 23.9, Problem 32ATS , additional homework tip  2

Alkene metathesis: It involves two stages first; the starting material in presence of catalyst forms two possible intermediates.  Next the intermediates react with the starting material and results to form product.

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%Reflectance 95 90- 85 22 00 89 60 55 50 70 65 75 80 50- 45 40 WA 35 30- 25 20- 4000 3500 Date: Thu Feb 06 17:21:21 2025 (GMT-05:0(UnknownD Scans: 8 Resolution: 2.000 3000 2500 Wavenumbers (cm-1) 100- 2981.77 1734.25 2000 1500 1000 1372.09 1108.01 2359.09 1469.82 1181.94 1145.20 1017.01 958.45 886.97 820.49 668.25 630.05 611.37
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CH3 CH H3C CH3 H OH H3C- -OCH2CH3 H3C H -OCH3 For each of the above compounds, do the following: 1. List the wave numbers of all the IR bands in the 1350-4000 cm-1 region. For each one, state what bond or group it represents. 2. Label equivalent sets of protons with lower-case letters. Then, for each 1H NMR signal, give the 8 value, the type of splitting (singlet, doublet etc.), and the number protons it represents. of letter δ value splitting # of protons 3. Redraw the compound and label equivalent sets of carbons with lower-case letters. Then for each set of carbons give the 5 value and # of carbons it represents. letter δ value # of carbons

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