Organic Chemistry 3rd.ed. Klein Evaluation/desk Copy
3rd Edition
ISBN: 9781119320524
Author: Klein
Publisher: WILEY
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Chapter 23.5, Problem 2LTS
Interpretation Introduction
Interpretation:
The coupling product obtained when given aryl iodide treated with organostannane in presence of
Concept Introduction:
Stille coupling reaction: The reaction that involves coupling of an aryl, benzyl or vinyl halide or triflate with stannane in presence of
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1. Predict the organic product(s) of the following reactions. Assume excess of reagents unless
otherwise noted.
a)
&l
BH3 •THF
b)
1) NaOH
2) H3O+
solve
d)
ala
1) EtMgBr
2) H3O+
e)
H2N
سكر
CuLi
NH2
1) SOCI2
2) EtMgBr
3) H3O+
NC
H3O+
Δ
There are 48 pairs of students in the following table. Each pair has quantitatively determined the mass of taurine in a 250 mL can of the popular energy drink marketed as “Munster” using High Performance Liquid Chromatography (HPLC). The class results are presented below:
QUESTION: Summarise and report these results including an indication of measurement uncertainty.
In both calculation samples calculate if an outlier is present, max value, number of samples, mean, standard deviation, g (suspect), g (critical) and t (critical).
Mass of Taurine (mg)
Mass of Taurine (mg)
(Table continued)
152.01
152.23
151.87
151.45
154.11
152.64
152.98
153.24
152.88
151.45
153.49
152.48
150.68
152.33
151.52
153.63
152.48
151.68
153.17
153.40
153.77
153.67
152.34
153.16
152.57
153.02
152.86
151.50
151.23
152.57
152.72
151.54
146.47
152.38
152.44
152.54
152.53
152.54
151.32…
Indicate the rate expressions for reactions that have order 0, 1, and 2.
Chapter 23 Solutions
Organic Chemistry 3rd.ed. Klein Evaluation/desk Copy
Ch. 23.1 - Identify which of the following reagents is...Ch. 23.2 - Prob. 2CCCh. 23.2 - Prob. 3CCCh. 23.2 - Prob. 4CCCh. 23.2 - Prob. 5CCCh. 23.2 - Prob. 6CCCh. 23.3 - Show how you would prepare 1-butylcyclopentene...Ch. 23.3 - Prob. 7PTSCh. 23.3 -
Using any two organohalides of your choice...Ch. 23.3 - Prob. 9ATS
Ch. 23.4 - Prob. 10CCCh. 23.4 - Prob. 11CCCh. 23.5 - Prob. 2LTSCh. 23.6 - Prob. 3LTSCh. 23.6 - Prob. 16PTSCh. 23.6 - Prob. 17PTSCh. 23.6 - Prob. 18ATSCh. 23.6 - Prob. 19ATSCh. 23.7 - Prob. 4LTSCh. 23.7 - Prob. 20PTSCh. 23.7 - Prob. 21PTSCh. 23.7 - Prob. 22ATSCh. 23.7 - Prob. 23ATSCh. 23.8 - Prob. 5LTSCh. 23.8 - Prob. 24PTSCh. 23.8 - Prob. 25ATSCh. 23.8 - Prob. 26ATSCh. 23.9 - Prob. 27CCCh. 23.9 - Prob. 28CCCh. 23.9 - Prob. 29CCCh. 23.9 - Prob. 6LTSCh. 23.9 - Prob. 30PTSCh. 23.9 - Prob. 31PTSCh. 23.9 - Prob. 32ATSCh. 23 - Prob. 33PPCh. 23 - Prob. 34PPCh. 23 - Prob. 35PPCh. 23 - Prob. 36PPCh. 23 - Prob. 37PPCh. 23 - Prob. 38PPCh. 23 - Prob. 39PPCh. 23 - Prob. 40PPCh. 23 - Prob. 41PPCh. 23 - Prob. 42PPCh. 23 - Prob. 43PPCh. 23 - Prob. 44PPCh. 23 - Prob. 45PPCh. 23 - Prob. 46PPCh. 23 - Using 1-pentene as your only source of carbon...Ch. 23 - Prob. 48PPCh. 23 - Prob. 49PPCh. 23 - Prob. 50PPCh. 23 - Prob. 51PPCh. 23 - Prob. 52PPCh. 23 - Prob. 53PPCh. 23 - Prob. 54PPCh. 23 - Prob. 55PPCh. 23 - Prob. 56PPCh. 23 - Prob. 57PPCh. 23 - Prob. 58PPCh. 23 - Prob. 59IPCh. 23 - Prob. 60IPCh. 23 - Prob. 61IPCh. 23 - Prob. 62IPCh. 23 - Prob. 64IPCh. 23 - Prob. 66IPCh. 23 - Prob. 68IPCh. 23 - Prob. 69IPCh. 23 - Prob. 70IPCh. 23 - Prob. 71CPCh. 23 - Prob. 72CPCh. 23 - Prob. 73CPCh. 23 - Prob. 74CPCh. 23 - Prob. 75CPCh. 23 - Prob. 76CP
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- 1. Answer the questions about the following reaction: (a) Draw in the arrows that can be used make this reaction occur and draw in the product of substitution in this reaction. Be sure to include any relevant stereochemistry in the product structure. + SK F Br + (b) In which solvent would this reaction proceed the fastest (Circle one) Methanol Acetone (c) Imagine that you are working for a chemical company and it was your job to perform a similar reaction to the one above, with the exception of the S atom in this reaction being replaced by an O atom. During the reaction, you observe the formation of three separate molecules instead of the single molecule obtained above. What is the likeliest other products that are formed? Draw them in the box provided.arrow_forward3. For the reactions below, draw the arrows corresponding to the transformations and draw in the boxes the reactants or products as indicated. Note: Part A should have arrows drawn going from the reactants to the middle structure and the arrows on the middle structure that would yield the final structure. For part B, you will need to draw in the reactant before being able to draw the arrows corresponding to product formation. A. B. Rearrangement ΘΗarrow_forward2. Draw the arrows required to make the following reactions occur. Please ensure your arrows point from exactly where you want to exactly where you want. If it is unclear from where arrows start or where they end, only partial credit will be given. Note: You may need to draw in lone pairs before drawing the arrows. A. B. H-Br 人 C Θ CI H Cl Θ + Br Oarrow_forward
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