
Concept explainers
(a)
Interpretation:
The
Concept introduction:
Organic compounds are named systematically by using IUPAC rules.
Name of the organic compounds are given according to the number of carbon present in the molecule for example
A molecule having one carbon atom, the molecule name will start with meth etc.…
If any halogens are present in the molecule, the name of the halogens as follows.
Naming the substituted
- (1) Name the parent alkane (long alkyl chain)
- (2) Number the carbon
- (3) Name and number the substituent
If the molecules have the multiple substituents, the compound named as di, tri, tetra, Penta, etc.
If the molecules having functional group, the name of the compound is given below. Numbering should be starts from the functional group of the given molecule.
The given compound is an alcohol
Example is given below
The given compound is an acid (
The amides are derivatives of acids and it is named as the ending of alkane with amide.
For example
If the molecule is ester,
Esters end with “ate”
Example
The given compound is an
The given compound is
The given compound is an
(b)
Interpretation:
The functional group should be identified for the given molecule.
Concept introduction:
Organic compounds are named systematically by using IUPAC rules.
Name of the organic compounds are given according to the number of carbon present in the molecule for example
A molecule having one carbon atom, the molecule name will start with meth etc.…
If any halogens are present in the molecule, the name of the halogens as follows.
Naming the substituted alkane:
- (4) Name the parent alkane (long alkyl chain)
- (5) Number the carbon
- (6) Name and number the substituent
If the molecules have the multiple substituents, the compound named as di, tri, tetra, Penta, etc.
If the molecules having functional group, the name of the compound is given below. Numbering should be starts from the functional group of the given molecule.
The given compound is an alcohol
Example is given below
The given compound is an acid (
The amides are derivatives of acids and it is named as the ending of alkane with amide.
For example
If the molecule is ester,
Esters end with “ate”
Example
The given compound is an aldehyde (
The given compound is ketone (
The given compound is an amine (
(c)
Interpretation:
The functional group should be identified for the given molecule.
Concept introduction:
Organic compounds are named systematically by using IUPAC rules.
Name of the organic compounds are given according to the number of carbon present in the molecule for example
A molecule having one carbon atom, the molecule name will start with meth etc.…
If any halogens are present in the molecule, the name of the halogens as follows.
Naming the substituted alkane:
- (7) Name the parent alkane (long alkyl chain)
- (8) Number the carbon
- (9) Name and number the substituent
If the molecules have the multiple substituents, the compound named as di, tri, tetra, Penta, etc.
If the molecules having functional group, the name of the compound is given below. Numbering should be starts from the functional group of the given molecule.
The given compound is an alcohol
Example is given below
The given compound is an acid (
The amides are derivatives of acids and it is named as the ending of alkane with amide.
For example
If the molecule is ester,
Esters end with “ate”
Example
The given compound is an aldehyde (
The given compound is ketone (
The given compound is an amine (

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Chapter 23 Solutions
GEN COMBO CHEMISTRY: ATOMS FIRST; ALEKS 360 2S ACCESS CARD CHEMISTRY:ATOMS FIRST
- Determine if the following salt is neutral, acidic or basic. If acidic or basic, write the appropriate equilibrium equation for the acid or base that exists when the salt is dissolved in aqueous solution. If neutral, simply write only NR. Be sure to include the proper phases for all species within the reaction LiNO3arrow_forwardAn unknown weak acid with a concentration of 0.410 M has a pH of 5.600. What is the Ka of the weak acid?arrow_forward(racemic) 19.84 Using your reaction roadmaps as a guide, show how to convert 2-oxepanone and ethanol into 1-cyclopentenecarbaldehyde. You must use 2-oxepanone as the source of all carbon atoms in the target molecule. Show all reagents and all molecules synthesized along the way. & + EtOH H 2-Oxepanone 1-Cyclopentenecarbaldehydearrow_forward
- R₂ R₁ R₁ a R Rg Nu R₂ Rg R₁ R R₁₂ R3 R R Nu enolate forming R₁ R B-Alkylated carbonyl species or amines Cyclic B-Ketoester R₁₁ HOB R R₁B R R₁₂ B-Hydroxy carbonyl R diester R2 R3 R₁ RB OR R₂ 0 aB-Unsaturated carbonyl NaOR Aldol HOR reaction 1) LDA 2) R-X 3) H₂O/H₂O ketone, aldehyde 1) 2°-amine 2) acid chloride 3) H₂O'/H₂O 0 O R₁ R₁ R R₁ R₁₂ Alkylated a-carbon R₁ H.C R₁ H.C Alkylated methyl ketone acetoacetic ester B-Ketoester ester R₁ HO R₂ R B-Dicarbonyl HO Alkylated carboxylic acid malonic ester Write the reagents required to bring about each reaction next to the arrows shown. Next, record any regiochemistry or stereochemistry considerations relevant to the reaction. You should also record any key aspects of the mechanism, such as forma- tion of an important intermediate, as a helpful reminder. You may want to keep track of all reactions that make carbon-carbon bonds, because these help you build large molecules from smaller fragments. This especially applies to the reactions in…arrow_forwardProvide the reasonable steps to achieve the following synthesis.arrow_forwardIdentify which compound is more acidic. Justify your choice.arrow_forward
- Provide the reasonable steps to achieve the following synthesis.arrow_forwardWhen anisole is treated with excess bromine, the reaction gives a product which shows two singlets in 1H NMR. Draw the product.arrow_forward(ii) Draw a reasonable mechanism for the following reaction: CI NaOH heat OH (hint: SNAr Reaction) :arrow_forward
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