Chemistry
12th Edition
ISBN: 9780078021510
Author: Raymond Chang Dr., Kenneth Goldsby Professor
Publisher: McGraw-Hill Education
expand_more
expand_more
format_list_bulleted
Videos
Textbook Question
Chapter 23.1, Problem 1RC
Identify the following
Table 7.3 The Ground-State Electron Configurations of the Elements*
Expert Solution & Answer
Trending nowThis is a popular solution!
Students have asked these similar questions
Write the condensed ground-state electron configurations of these transition metal ions, and indicate which are paramagnetic. (Type your answer using the format [Ar] 4s2 3d10 4p1 for [Ar] 4s23d104p1.)
(a) Mo3+
O paramagnetic
O diamagnetic
(b) Hf2+
O paramagnetic
O diamagnetic
(c) Mn2+
O paramagnetic
O diamagnetic
(d) v3+
O paramagnetic
O diamagnetic
The electron configuration of a Cr 3+ ion is
[Ar]4s23d4.
[Ar]4s13d2.
[Ar]3d5.
[Ar]3d3.
[Ar]4s13d5.
Mercury ions, Hg(1) and Hg(II), are poisonous due to their ability to displace other metal ions in
enzymes and disrupt the biological function.
a) Are these ions hard or soft?
b) Common ligands for metal ions in biological environments are amino acids (building
blocks of proteins). Of the amino acids depicted below (focus on the highlighted atoms),
which would be the best ligand for Hg(1) and Hg(II), and why?
H
H
H
O H3Nt
CH2
H
H
H3N* -c
CH2
H3Nt C-c
CH2
H3Nt
CH2
H3N+-C-c
CH
CH2
HO CH3
OH
SH
он
H2N
H2N
Serine (S)
Ser
Threonine (T)
Thr
Cysteine
Сys
Tyrosine (Y) Asparagine (N) Glutamine (Q)
Asn
Тyr
Gln
c) Other metal ions that are toxic at certain concentrations include cadmium, chromium,
iron, arsenic, and lead. For each of these metals, predict whether they would have
similar chemistry to mercury using HSAB concepts.
(Note that toxicity is dose-dependent; even water can be poisonous at too high a
concentration in the body)
Chapter 23 Solutions
Chemistry
Ch. 23.1 - Identify the following transition metal atoms and...Ch. 23.3 - What is the difference between these two...Ch. 23.3 - Write the oxidation numbers of the metals in the...Ch. 23.3 - Prob. 2PECh. 23.3 - Prob. 3PECh. 23.3 - Prob. 2RCCh. 23.4 - Prob. 1RCCh. 23.5 - Prob. 4PECh. 23.5 - Prob. 1RCCh. 23 - What distinguishes a transition metal from a...
Ch. 23 - Why is zinc not considered a transition metal?Ch. 23 - Explain why atomic radii decrease very gradually...Ch. 23 - Without referring to the text, write the...Ch. 23 - Write the electron configurations of the following...Ch. 23 - Why do transition metals have more oxidation...Ch. 23 - Prob. 23.7QPCh. 23 - Prob. 23.8QPCh. 23 - Define the following terms: coordination compound,...Ch. 23 - Describe the interaction between a donor atom and...Ch. 23 - Prob. 23.11QPCh. 23 - Prob. 23.12QPCh. 23 - Prob. 23.13QPCh. 23 - Prob. 23.14QPCh. 23 - Prob. 23.15QPCh. 23 - What are the systematic names for the following...Ch. 23 - Prob. 23.17QPCh. 23 - Prob. 23.18QPCh. 23 - Define the following terms: stereoisomers,...Ch. 23 - Prob. 23.20QPCh. 23 - Prob. 23.21QPCh. 23 - Prob. 23.22QPCh. 23 - Prob. 23.23QPCh. 23 - Prob. 23.24QPCh. 23 - Draw structures of all the geometric and optical...Ch. 23 - Prob. 23.26QPCh. 23 - Briefly describe crystal field theory.Ch. 23 - Prob. 23.28QPCh. 23 - What is the origin of color in a coordination...Ch. 23 - Prob. 23.30QPCh. 23 - Prob. 23.31QPCh. 23 - Prob. 23.32QPCh. 23 - Prob. 23.33QPCh. 23 - Prob. 23.34QPCh. 23 - Prob. 23.35QPCh. 23 - The absorption maximum for the complex ion...Ch. 23 - Prob. 23.37QPCh. 23 - A solution made by dissolving 0.875 g of...Ch. 23 - Prob. 23.39QPCh. 23 - Prob. 23.40QPCh. 23 - Prob. 23.41QPCh. 23 - The [Fe(CN)6]3 complex is more labile than the...Ch. 23 - Aqueous copper(II) sulfate solution is blue in...Ch. 23 - When aqueous potassium cyanide is added to a...Ch. 23 - A concentrated aqueous copper(II) chloride...Ch. 23 - Prob. 23.46QPCh. 23 - As we read across the first-row transition metals...Ch. 23 - Prob. 23.48QPCh. 23 - Prob. 23.49QPCh. 23 - Prob. 23.50QPCh. 23 - Prob. 23.51QPCh. 23 - Chemical analysis shows that hemoglobin contains...Ch. 23 - Explain the following facts: (a) Copper and iron...Ch. 23 - A student in 1895 prepared three coordination...Ch. 23 - Prob. 23.55QPCh. 23 - From the standard reduction potentials listed in...Ch. 23 - Using the standard reduction potentials listed in...Ch. 23 - The Co2+-porphyrin complex is more stable than the...Ch. 23 - Prob. 23.59QPCh. 23 - Prob. 23.60QPCh. 23 - Hydrated Mn2+ ions are practically colorless (see...Ch. 23 - Which of the following hydrated cations are...Ch. 23 - Prob. 23.63QPCh. 23 - Prob. 23.64QPCh. 23 - Prob. 23.65QPCh. 23 - Prob. 23.66QPCh. 23 - The compound 1,1,1-trifluoroacetylacetone (tfa) is...Ch. 23 - Prob. 23.68QPCh. 23 - Prob. 23.69QPCh. 23 - Prob. 23.70QPCh. 23 - Prob. 23.71QPCh. 23 - Commercial silver-plating operations frequently...Ch. 23 - Draw qualitative diagrams for the crystal field...Ch. 23 - (a) The free Cu(I) ion is unstable in solution and...Ch. 23 - Prob. 23.75QPCh. 23 - Prob. 23.76QP
Knowledge Booster
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.Similar questions
- What two first-row transition metals have unexpected electron configurations? A statement in the text says that first-row transition metal ions do not have 4s electrons. Why not? Why do transition metal ions often have several oxidation states, whereas representative metals generally have only one?arrow_forwardWhich Period 4 transition-metal ions are isoelectronic with (a) Zn2+ (b) Mn2+ (c) Cr3+ (d) Fe3+arrow_forwardIdentify a cation of a first series transition metal that is isoelectronic with each of the following. (a) Fe3+ (b) Zn2+ (c) Fe2+ (d) Cr3+arrow_forward
- Give the symbol of the main-group metals in period 4 with the following number of unpaired electrons per atom. (Transition metals are not included.) (a) 0(b) 1(c) 2(d) 3arrow_forward3. At 525 nm, the permanganate ions absorb which color of light?arrow_forwarda) How many core electrons does the Ni atom have? b) How many valence electrons are in the Ni3+ ion? Which transition-metal ion with a 3+ charge has the electron configuration [Kr]4d5 ?arrow_forward
- Define actinidesarrow_forward- [Fe(CN)6]ª- has how many unpaired electrons? A. 2 В. О C. 4 С. D. 3arrow_forwardWrite down the set of quantum numbers that describe the 4th and 11th electrons of Mg atom. 2. А. В. Write down the orbital diagram for each transition metal ion below, and predict whether the ion is paramagnetic or diamagnetic. (a) Cul* (Z=29) (b) Zn²* (Z=30) С. Are the following combinations allowed? If not, show two ways to correct them: (a) n = 2; 1 = 0; mị = -1; ms= +1/2 (b) n = 3; 1= 1; mị = 0, mş=-1/2 (c) n= 4; 1= 3; mị = -1; ms= -1/2 (d) n = 3; 1= 3; mị = +2; mş=+1/2 In which of the following ground state electron distribution, the Hund's rule is violated? Justify your answer. D. (A) (B) (C) (D) Е. Which of the following is a violation of Pauli's exclusion principle? Justify your answer. (A) 11 (B) tt (C) 14 (D) farrow_forward
- What is magnetic susceptibility and magnetic moment? Use electron configuration to describe the paramagnetic properties of Fe(III). (Inorganic Chemistry)arrow_forwardWhich atoms/ions fit the electron configuration? 1s22s22p63s23p64s23d4 Cr Fe2+ None Mn+ Co3+arrow_forwardWhich of the following transition metals is most likely to form an oxide? a gold b silver c platinum d palladium e copperarrow_forward
arrow_back_ios
SEE MORE QUESTIONS
arrow_forward_ios
Recommended textbooks for you
Chemistry: Principles and PracticeChemistryISBN:9780534420123Author:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward MercerPublisher:Cengage Learning
ChemistryChemistryISBN:9781305957404Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCostePublisher:Cengage Learning
Chemistry: An Atoms First ApproachChemistryISBN:9781305079243Author:Steven S. Zumdahl, Susan A. ZumdahlPublisher:Cengage Learning
Chemistry: Principles and ReactionsChemistryISBN:9781305079373Author:William L. Masterton, Cecile N. HurleyPublisher:Cengage Learning
Chemistry & Chemical ReactivityChemistryISBN:9781337399074Author:John C. Kotz, Paul M. Treichel, John Townsend, David TreichelPublisher:Cengage Learning
Chemistry: Principles and Practice
Chemistry
ISBN:9780534420123
Author:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer
Publisher:Cengage Learning
Chemistry
Chemistry
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Cengage Learning
Chemistry: An Atoms First Approach
Chemistry
ISBN:9781305079243
Author:Steven S. Zumdahl, Susan A. Zumdahl
Publisher:Cengage Learning
Chemistry: Principles and Reactions
Chemistry
ISBN:9781305079373
Author:William L. Masterton, Cecile N. Hurley
Publisher:Cengage Learning
Chemistry & Chemical Reactivity
Chemistry
ISBN:9781337399074
Author:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher:Cengage Learning
Introduction to Coordination ComplexesWave Function for Hydrogen atom # All Vital Topics # Quantum Mechanics part -21; Author: Priyanka Jain;https://www.youtube.com/watch?v=GKgNV9dmUHo;License: Standard YouTube License, CC-BY
CBSE Class 12 Chemistry || The d & f Block Elements Part 1 || Full Chapter || By Shiksha House; Author: Best for NEET;https://www.youtube.com/watch?v=LzZWHSdYaxw;License: Standard Youtube License