
Concept explainers
(a)
Interpretation:
For the given complex the orbital splitting diagram has to be drawn using spectrochemial series.
Concept introduction:
The element in the periodic table and count its position in the respective transition series. These elements are in Periods 5 and 6, so the general configuration is
The spectrochemical series is
(a)

Explanation of Solution
Electron configuration of
Charge on
Electron configuration of
Six ligands indicate an octahedral arrangement. Using Hund’s rule, fill the lower energy
(b)
Interpretation:
For the given complex the orbital splitting diagram has to be drawn using spectrochemial series.
Concept introduction:
The element in the periodic table and count its position in the respective transition series. These elements are in Periods 5 and 6, so the general configuration is
The spectrochemical series is
(b)

Explanation of Solution
Electron configuration of
Charge on
Electron configuration of
Four ligands and a
(c)
Interpretation:
For the given complex the orbital splitting diagram has to be drawn using spectrochemial series.
Concept introduction:
The element in the periodic table and count its position in the respective transition series. These elements are in Periods 5 and 6, so the general configuration is
The spectrochemical series is
(c)

Explanation of Solution
Electron configuration of
Charge on
Electron configuration of
Six ligands indicate an octahedral arrangement. Use Hund’s rule to fill the orbitals.
F– is a weak-field ligand, so the splitting energy, Δ, is not large enough to overcome the resistance to electron pairing. The electrons remain unpaired, and the complex is called high-spin.
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Chapter 23 Solutions
Chemistry: The Molecular Nature of Matter and Change - Standalone book
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