Based on valence bond theory , which set of orbitals is used by a period 4 metal ion in forming a square planar complex has to be explained. Concept introduction: According to valence bond theory, complex ions have coordinate covalent bonds between Ligands (Lewis bases) and metal ions (Lewis acids). A coordinate covalent bond is a bond formed when both electrons came from one atom. Valence bond theory, which helps explain bonding and structure in main-group compounds (can also be used to describe bonding in complex ions. In the formation of a complex ion, the filled ligand orbital overlaps an empty metal-ion orbital: the ligand (Lewis base) donates an electron pair, and the metal ion (Lewis acid) accepts it to form a covalent bond in the complex ion (Lewis adduct). A bond in which one atom contributes both electrons is a coordinate covalent bond; once formed, it is identical to any covalent single bond. The VB concept of hybridization proposes mixing particular combinations of s , p , a n d d orbitals to obtain sets of hybrid orbitals, which have specific geometries. Let’s discuss orbital combinations that lead to octahedral, square planar, and tetrahedral geometries.

Question

Want to see the full answer?

Answer 1

Question

Chapter 23, Problem 23.71P

(a)

Interpretation Introduction

Interpretation:

Based on valence bond theory, which set of orbitals is used by a period 4 metal ion in forming a square planar complex has to be explained.

Concept introduction:

According to valence bond theory, complex ions have coordinate covalent bonds between

Ligands (Lewis bases) and metal ions (Lewis acids).

A coordinate covalent bond is a bond formed when both electrons came from one atom.

Valence bond theory, which helps explain bonding and structure in main-group compounds (can also be used to describe bonding in complex ions.

In the formation of a complex ion, the filled ligand orbital overlaps an empty metal-ion

orbital: the ligand (Lewis base) donates an electron pair, and the metal ion (Lewis acid)

accepts it to form a covalent bond in the complex ion (Lewis adduct).

A bond in which one atom contributes both electrons is a coordinate covalent bond; once

formed, it is identical to any covalent single bond.

The VB concept of hybridization proposes mixing particular combinations of s,p, and d orbitals to obtain sets of hybrid orbitals, which have specific geometries.

Let’s discuss orbital combinations that lead to octahedral, square planar, and tetrahedral geometries.

(b)

Interpretation Introduction

Interpretation:

Based on valence bond theory, which set of orbitals is used by a period 4 metal ion in forming a tetrahedral complex has to be explained.

Concept introduction:

According to valence bond theory, complex ions have coordinate covalent bonds between

Ligands (Lewis bases) and metal ions (Lewis acids).

A coordinate covalent bond is a bond formed when both electrons came from one atom.

Valence bond theory, which helps explain bonding and structure in main-group compounds (can also be used to describe bonding in complex ions.

In the formation of a complex ion, the filled ligand orbital overlaps an empty metal-ion

orbital: the ligand (Lewis base) donates an electron pair, and the metal ion (Lewis acid)

accepts it to form a covalent bond in the complex ion (Lewis adduct).

A bond in which one atom contributes both electrons is a coordinate covalent bond; once

formed, it is identical to any covalent single bond.

The VB concept of hybridization proposes mixing particular combinations of s,p, and d orbitals to obtain sets of hybrid orbitals, which have specific geometries.

Let’s discuss orbital combinations that lead to octahedral, square planar, and tetrahedral geometries.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Students have asked these similar questions

5. Propose a Synthesis for the molecule below. You may use any starting materials containing 6 carbons or less (reagents that aren't incorporated into the final molecule such as PhзP do not count towards this total, and the starting material can have whatever non-carbon functional groups you want), and any of the reactions you have learned so far in organic chemistry I, II, and III. Your final answer should show each step separately, with intermediates and conditions clearly drawn. H3C CH3

State the name and condensed formula of isooxazole obtained by reacting acetylacetone and hydroxylamine.

State the name and condensed formula of the isothiazole obtained by reacting acetylacetone and thiosemicarbazide.

Answer 2

Question

Chapter 23, Problem 23.71P

(a)

Interpretation Introduction

Interpretation:

Based on valence bond theory, which set of orbitals is used by a period 4 metal ion in forming a square planar complex has to be explained.

Concept introduction:

According to valence bond theory, complex ions have coordinate covalent bonds between

Ligands (Lewis bases) and metal ions (Lewis acids).

A coordinate covalent bond is a bond formed when both electrons came from one atom.

Valence bond theory, which helps explain bonding and structure in main-group compounds (can also be used to describe bonding in complex ions.

In the formation of a complex ion, the filled ligand orbital overlaps an empty metal-ion

orbital: the ligand (Lewis base) donates an electron pair, and the metal ion (Lewis acid)

accepts it to form a covalent bond in the complex ion (Lewis adduct).

A bond in which one atom contributes both electrons is a coordinate covalent bond; once

formed, it is identical to any covalent single bond.

The VB concept of hybridization proposes mixing particular combinations of s,p, and d orbitals to obtain sets of hybrid orbitals, which have specific geometries.

Let’s discuss orbital combinations that lead to octahedral, square planar, and tetrahedral geometries.

(b)

Interpretation Introduction

Interpretation:

Based on valence bond theory, which set of orbitals is used by a period 4 metal ion in forming a tetrahedral complex has to be explained.

Concept introduction:

According to valence bond theory, complex ions have coordinate covalent bonds between

Ligands (Lewis bases) and metal ions (Lewis acids).

A coordinate covalent bond is a bond formed when both electrons came from one atom.

Valence bond theory, which helps explain bonding and structure in main-group compounds (can also be used to describe bonding in complex ions.

In the formation of a complex ion, the filled ligand orbital overlaps an empty metal-ion

orbital: the ligand (Lewis base) donates an electron pair, and the metal ion (Lewis acid)

accepts it to form a covalent bond in the complex ion (Lewis adduct).

A bond in which one atom contributes both electrons is a coordinate covalent bond; once

formed, it is identical to any covalent single bond.

The VB concept of hybridization proposes mixing particular combinations of s,p, and d orbitals to obtain sets of hybrid orbitals, which have specific geometries.

Let’s discuss orbital combinations that lead to octahedral, square planar, and tetrahedral geometries.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 3

Question

Chapter 23, Problem 23.71P

(a)

Interpretation Introduction

Interpretation:

Based on valence bond theory, which set of orbitals is used by a period 4 metal ion in forming a square planar complex has to be explained.

Concept introduction:

According to valence bond theory, complex ions have coordinate covalent bonds between

Ligands (Lewis bases) and metal ions (Lewis acids).

A coordinate covalent bond is a bond formed when both electrons came from one atom.

Valence bond theory, which helps explain bonding and structure in main-group compounds (can also be used to describe bonding in complex ions.

In the formation of a complex ion, the filled ligand orbital overlaps an empty metal-ion

orbital: the ligand (Lewis base) donates an electron pair, and the metal ion (Lewis acid)

accepts it to form a covalent bond in the complex ion (Lewis adduct).

A bond in which one atom contributes both electrons is a coordinate covalent bond; once

formed, it is identical to any covalent single bond.

The VB concept of hybridization proposes mixing particular combinations of s,p, and d orbitals to obtain sets of hybrid orbitals, which have specific geometries.

Let’s discuss orbital combinations that lead to octahedral, square planar, and tetrahedral geometries.

(b)

Interpretation Introduction

Interpretation:

Based on valence bond theory, which set of orbitals is used by a period 4 metal ion in forming a tetrahedral complex has to be explained.

Concept introduction:

According to valence bond theory, complex ions have coordinate covalent bonds between

Ligands (Lewis bases) and metal ions (Lewis acids).

A coordinate covalent bond is a bond formed when both electrons came from one atom.

Valence bond theory, which helps explain bonding and structure in main-group compounds (can also be used to describe bonding in complex ions.

In the formation of a complex ion, the filled ligand orbital overlaps an empty metal-ion

orbital: the ligand (Lewis base) donates an electron pair, and the metal ion (Lewis acid)

accepts it to form a covalent bond in the complex ion (Lewis adduct).

A bond in which one atom contributes both electrons is a coordinate covalent bond; once

formed, it is identical to any covalent single bond.

The VB concept of hybridization proposes mixing particular combinations of s,p, and d orbitals to obtain sets of hybrid orbitals, which have specific geometries.

Let’s discuss orbital combinations that lead to octahedral, square planar, and tetrahedral geometries.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 4

Question

Chapter 23, Problem 23.71P

(a)

Interpretation Introduction

Interpretation:

Based on valence bond theory, which set of orbitals is used by a period 4 metal ion in forming a square planar complex has to be explained.

Concept introduction:

According to valence bond theory, complex ions have coordinate covalent bonds between

Ligands (Lewis bases) and metal ions (Lewis acids).

A coordinate covalent bond is a bond formed when both electrons came from one atom.

Valence bond theory, which helps explain bonding and structure in main-group compounds (can also be used to describe bonding in complex ions.

In the formation of a complex ion, the filled ligand orbital overlaps an empty metal-ion

orbital: the ligand (Lewis base) donates an electron pair, and the metal ion (Lewis acid)

accepts it to form a covalent bond in the complex ion (Lewis adduct).

A bond in which one atom contributes both electrons is a coordinate covalent bond; once

formed, it is identical to any covalent single bond.

The VB concept of hybridization proposes mixing particular combinations of s,p, and d orbitals to obtain sets of hybrid orbitals, which have specific geometries.

Let’s discuss orbital combinations that lead to octahedral, square planar, and tetrahedral geometries.

(b)

Interpretation Introduction

Interpretation:

Based on valence bond theory, which set of orbitals is used by a period 4 metal ion in forming a tetrahedral complex has to be explained.

Concept introduction:

According to valence bond theory, complex ions have coordinate covalent bonds between

Ligands (Lewis bases) and metal ions (Lewis acids).

A coordinate covalent bond is a bond formed when both electrons came from one atom.

Valence bond theory, which helps explain bonding and structure in main-group compounds (can also be used to describe bonding in complex ions.

In the formation of a complex ion, the filled ligand orbital overlaps an empty metal-ion

orbital: the ligand (Lewis base) donates an electron pair, and the metal ion (Lewis acid)

accepts it to form a covalent bond in the complex ion (Lewis adduct).

A bond in which one atom contributes both electrons is a coordinate covalent bond; once

formed, it is identical to any covalent single bond.

The VB concept of hybridization proposes mixing particular combinations of s,p, and d orbitals to obtain sets of hybrid orbitals, which have specific geometries.

Let’s discuss orbital combinations that lead to octahedral, square planar, and tetrahedral geometries.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 5

Chapter 23, Problem 23.71P

(a)

Interpretation Introduction

Interpretation:

Based on valence bond theory, which set of orbitals is used by a period 4 metal ion in forming a square planar complex has to be explained.

Concept introduction:

According to valence bond theory, complex ions have coordinate covalent bonds between

Ligands (Lewis bases) and metal ions (Lewis acids).

A coordinate covalent bond is a bond formed when both electrons came from one atom.

Valence bond theory, which helps explain bonding and structure in main-group compounds (can also be used to describe bonding in complex ions.

In the formation of a complex ion, the filled ligand orbital overlaps an empty metal-ion

orbital: the ligand (Lewis base) donates an electron pair, and the metal ion (Lewis acid)

accepts it to form a covalent bond in the complex ion (Lewis adduct).

A bond in which one atom contributes both electrons is a coordinate covalent bond; once

formed, it is identical to any covalent single bond.

The VB concept of hybridization proposes mixing particular combinations of s,p, and d orbitals to obtain sets of hybrid orbitals, which have specific geometries.

Let’s discuss orbital combinations that lead to octahedral, square planar, and tetrahedral geometries.

(b)

Interpretation Introduction

Interpretation:

Based on valence bond theory, which set of orbitals is used by a period 4 metal ion in forming a tetrahedral complex has to be explained.

Concept introduction:

According to valence bond theory, complex ions have coordinate covalent bonds between

Ligands (Lewis bases) and metal ions (Lewis acids).

A coordinate covalent bond is a bond formed when both electrons came from one atom.

Valence bond theory, which helps explain bonding and structure in main-group compounds (can also be used to describe bonding in complex ions.

In the formation of a complex ion, the filled ligand orbital overlaps an empty metal-ion

orbital: the ligand (Lewis base) donates an electron pair, and the metal ion (Lewis acid)

accepts it to form a covalent bond in the complex ion (Lewis adduct).

A bond in which one atom contributes both electrons is a coordinate covalent bond; once

formed, it is identical to any covalent single bond.

The VB concept of hybridization proposes mixing particular combinations of s,p, and d orbitals to obtain sets of hybrid orbitals, which have specific geometries.

Let’s discuss orbital combinations that lead to octahedral, square planar, and tetrahedral geometries.

Answer 6

Chapter 23, Problem 23.71P

(a)

Interpretation Introduction

Interpretation:

Based on valence bond theory, which set of orbitals is used by a period 4 metal ion in forming a square planar complex has to be explained.

Concept introduction:

According to valence bond theory, complex ions have coordinate covalent bonds between

Ligands (Lewis bases) and metal ions (Lewis acids).

A coordinate covalent bond is a bond formed when both electrons came from one atom.

Valence bond theory, which helps explain bonding and structure in main-group compounds (can also be used to describe bonding in complex ions.

In the formation of a complex ion, the filled ligand orbital overlaps an empty metal-ion

orbital: the ligand (Lewis base) donates an electron pair, and the metal ion (Lewis acid)

accepts it to form a covalent bond in the complex ion (Lewis adduct).

A bond in which one atom contributes both electrons is a coordinate covalent bond; once

formed, it is identical to any covalent single bond.

The VB concept of hybridization proposes mixing particular combinations of s,p, and d orbitals to obtain sets of hybrid orbitals, which have specific geometries.

Let’s discuss orbital combinations that lead to octahedral, square planar, and tetrahedral geometries.

Answer 7

Chapter 23, Problem 23.71P

(a)

Interpretation Introduction

Interpretation:

Based on valence bond theory, which set of orbitals is used by a period 4 metal ion in forming a square planar complex has to be explained.

Concept introduction:

According to valence bond theory, complex ions have coordinate covalent bonds between

Ligands (Lewis bases) and metal ions (Lewis acids).

A coordinate covalent bond is a bond formed when both electrons came from one atom.

Valence bond theory, which helps explain bonding and structure in main-group compounds (can also be used to describe bonding in complex ions.

In the formation of a complex ion, the filled ligand orbital overlaps an empty metal-ion

orbital: the ligand (Lewis base) donates an electron pair, and the metal ion (Lewis acid)

accepts it to form a covalent bond in the complex ion (Lewis adduct).

A bond in which one atom contributes both electrons is a coordinate covalent bond; once

formed, it is identical to any covalent single bond.

The VB concept of hybridization proposes mixing particular combinations of s,p, and d orbitals to obtain sets of hybrid orbitals, which have specific geometries.

Let’s discuss orbital combinations that lead to octahedral, square planar, and tetrahedral geometries.

Answer 8

(b)

Interpretation Introduction

Interpretation:

Based on valence bond theory, which set of orbitals is used by a period 4 metal ion in forming a tetrahedral complex has to be explained.

Concept introduction:

According to valence bond theory, complex ions have coordinate covalent bonds between

Ligands (Lewis bases) and metal ions (Lewis acids).

A coordinate covalent bond is a bond formed when both electrons came from one atom.

Valence bond theory, which helps explain bonding and structure in main-group compounds (can also be used to describe bonding in complex ions.

In the formation of a complex ion, the filled ligand orbital overlaps an empty metal-ion

orbital: the ligand (Lewis base) donates an electron pair, and the metal ion (Lewis acid)

accepts it to form a covalent bond in the complex ion (Lewis adduct).

A bond in which one atom contributes both electrons is a coordinate covalent bond; once

formed, it is identical to any covalent single bond.

The VB concept of hybridization proposes mixing particular combinations of s,p, and d orbitals to obtain sets of hybrid orbitals, which have specific geometries.

Let’s discuss orbital combinations that lead to octahedral, square planar, and tetrahedral geometries.

Answer 9

(b)

Interpretation Introduction

Interpretation:

Based on valence bond theory, which set of orbitals is used by a period 4 metal ion in forming a tetrahedral complex has to be explained.

Concept introduction:

According to valence bond theory, complex ions have coordinate covalent bonds between

Ligands (Lewis bases) and metal ions (Lewis acids).

A coordinate covalent bond is a bond formed when both electrons came from one atom.

Valence bond theory, which helps explain bonding and structure in main-group compounds (can also be used to describe bonding in complex ions.

In the formation of a complex ion, the filled ligand orbital overlaps an empty metal-ion

orbital: the ligand (Lewis base) donates an electron pair, and the metal ion (Lewis acid)

accepts it to form a covalent bond in the complex ion (Lewis adduct).

A bond in which one atom contributes both electrons is a coordinate covalent bond; once

formed, it is identical to any covalent single bond.

The VB concept of hybridization proposes mixing particular combinations of s,p, and d orbitals to obtain sets of hybrid orbitals, which have specific geometries.

Let’s discuss orbital combinations that lead to octahedral, square planar, and tetrahedral geometries.

Answer 10

Expert Solution & Answer

Answer 11

Expert Solution & Answer

Answer 12

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 13

Ch. 23.1 - Write partial electron configurations (no noble...Ch. 23.1 - Find the charge of each of the following ions,...Ch. 23.2 - Prob. 23.2AFP Ch. 23.2 - Prob. 23.2BFP Ch. 23.3 - Give the coordination number and the charge of the...Ch. 23.3 - Write the formula of the coordination compound...Ch. 23.3 - Prob. 23.4AFP Ch. 23.3 - Prob. 23.4BFP Ch. 23.3 - Prob. 23.5AFP Ch. 23.3 - Prob. 23.5BFP

Concept explainers

Want to see the full answer?

Chapter 23 Solutions