(a)
Interpretation:
The formulas for the given complex
Concept introduction: -
Geometry of coordination compounds: The study of geometry of the coordination compound helps in understanding the physical and chemical property of the compound.
Stereoisomer: The same molecular formula but different with the arrangements of atoms around the metal ion. The Ligands are arranged differently in coordination compounds.
Geometric isomers: stereoisomers that cannot be interconverted without breaking the
Optical isomers: Optical isomers are non-superimposable mirror images.
Plane-polarized light: Light that oscillates in a single plane.
(b)
Interpretation:
The formulas for the given complex
Concept introduction:
Linkage isomers occur when the composition of the complex ion is the same but the ligand donor atom is different. Some ligands can bind to the metal ion through either of two donor atoms.
Geometry of coordination compounds: The study of geometry of the coordination compound helps in understanding the physical and chemical property of the compound.
Stereoisomer: The same molecular formula but different with the arrangements of atoms around the metal ion. The Ligands are arranged differently in coordination compounds.
Geometric isomers: stereoisomers that cannot be interconverted without breaking the chemical bonds.
Optical isomers: Optical isomers are non-superimposable mirror images.
Plane-polarized light: Light that oscillates in a single plane.
(c)
Interpretation:
The formulas for the given complex
Concept introduction:
Geometry of coordination compounds: The study of geometry of the coordination compound helps in understanding the physical and chemical property of the compound.
Stereoisomer: The same molecular formula but different with the arrangements of atoms around the metal ion. The Ligands are arranged differently in coordination compounds.
Geometric isomers: stereoisomers that cannot be interconverted without breaking the chemical bonds.
Optical isomers: Optical isomers are non-superimposable mirror images.
Plane-polarized light: Light that oscillates in a single plane.
(d)
Interpretation:
The formulas for the given complex
Concept introduction:
Geometry of coordination compounds: The study of geometry of the coordination compound helps in understanding the physical and chemical property of the compound.
Stereoisomer: The same molecular formula but different with the arrangements of atoms around the metal ion. The Ligands are arranged differently in coordination compounds.
Geometric isomers: stereoisomers that cannot be interconverted without breaking the chemical bonds.
Optical isomers: Optical isomers are non-superimposable mirror images.
Plane-polarized light: Light that oscillates in a single plane.
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Chapter 23 Solutions
CHEMISTRY THE MOLECULAR NATURE OF MATTER
- Acetic acid is added to DI water at an initial concentration of 10 -6 M (Ka=1.8x10-5) A. Using the "ICE" Method, what would the pH be at equilibrium? State assumptions and show your work. B. Using the simultaneous equations method, what would the pH be at equilibrium? Show your workarrow_forward1. Show that the change in entropy for a fixed amount of ideal gas held at a constant temperature undergoing a volume change is given by the simple equation AS = NkB In Hint: Start with the equation M dS = du + (Œ) dv - Ž (#) an, dU du+av-dN; j=1 Why doesn't the equation for the entropy of an ideal gas depend on the strength of the intermolecular forces for the gas?arrow_forward2. Make an ice cube at 1 bar pressure by freezing an amount of liquid water that is 2 cm x 2 cm x 2 cm in volume. The density of liquid water at 0 °C is 1.000 g cm³ and the density of ice at 0 °C is 0.915 g cm³. Note that this difference in density is the reason your water pipes burst if they freeze and why you shouldn't forget to take your bottle of pop out of the freezer if you put it in there to try and cool it down faster. A. What is the work of expansion upon freezing? B. Is work done on the system or by the system?arrow_forward
- I have a excitation/emission spectra of a quinine standard solution here, and I'm having trouble interpreting it. the red line is emission the blue line is excitation. i'm having trouble interpreting properly. just want to know if there is any evidence of raman or rayleigh peaks in the spectra.arrow_forwardGive the major product of the following reaction. excess 1. OH, H₂O 1.OH H CH3CH2CH21 H 2. A.-H₂O Draw the molecule on the canvas by choosing buttons from the Tools (for bonds), Atoms, and Advanced Template toolbars. The single bond is active by default.arrow_forward2. Use Hess's law to calculate the AH (in kJ) for: rxn CIF(g) + F2(g) → CIF 3 (1) using the following information: 2CIF(g) + O2(g) → Cl₂O(g) + OF 2(g) AH = 167.5 kJ ΔΗ 2F2 (g) + O2(g) → 2 OF 2(g) 2C1F3 (1) + 202(g) → Cl₂O(g) + 3 OF 2(g) о = = -43.5 kJ AH = 394.1kJarrow_forward
- The combustion of 28.8 g of NH3 consumes exactly _____ g of O2. 4 NH3 + 7 O2 ----> 4 NO2 + 6 H2Oarrow_forwardWhat is the molecular formula of the bond-line structure shown below OH HO ○ C14H12O2 ○ C16H14O2 ○ C16H12O2 O C14H14O2arrow_forwardCheck all molecules that are acids on the list below. H2CO3 HC2H3O2 C6H5NH2 HNO3 NH3arrow_forward
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