The formulas of the given compound has to be written using its names has to be given. Hexaaquachromium (III) sulfate Concept introduction: The set of rules for naming a coordination compound is: 1. When naming a complex ion, the ligands are named before the metal ion. 2. Write the names of the ligands in the following order: neutral, negative, positive. If there are multiple ligands of the same charge type, they are named in alphabetical order. 3. Multiple occurring monodentate ligands receive a prefix according to the number of occurrences: di-, tri-, tetra-, penta-, or hexa . Polydentate ligands (e.g., ethylene diamine, oxalate) receive bis-, tris-, tetrakis-, etc . Anions end in -ido. This replaces the final “e” when the anion ends with “-ate” (e.g, sulfate becomes sulfato) and replaces “-ide” (cyanide becomes cyanido). 4. Neutral ligands are given their usual name, with some exceptions: NH 3 becomes ammine; H 2 O becomes aqua or aquo; C O becomes carbonyl; NO becomes nitrosyl. 5. Write the name of the central atom/ion. If the complex is an anion, the central atom’s name will end in -ate, and its Latin name will be used if available 6. If the central atom’s oxidation state needs to be specified (when it is one of several possible, or zero), write it as a Roman numeral (or 0) in parentheses. 7. End with “cation” or “anion” as separate words.

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Answer 1

Question

Chapter 23, Problem 23.57P

(a)

Interpretation Introduction

Interpretation:

The formulas of the given compound has to be written using its names has to be given.

Hexaaquachromium (III) sulfate

Concept introduction:

The set of rules for naming a coordination compound is:

1. When naming a complex ion, the ligands are named before the metal ion.

2. Write the names of the ligands in the following order: neutral, negative, positive. If there are multiple ligands of the same charge type, they are named in alphabetical order.

3. Multiple occurring monodentate ligands receive a prefix according to the number of occurrences: di-, tri-, tetra-, penta-, or hexa. Polydentate ligands (e.g., ethylene diamine, oxalate) receive bis-, tris-, tetrakis-, etc. Anions end in -ido. This replaces the final “e” when the anion ends with “-ate” (e.g, sulfate becomes sulfato) and replaces “-ide” (cyanide becomes cyanido).

4. Neutral ligands are given their usual name, with some exceptions: NH₃ becomes ammine; H2O becomes aqua or aquo;CO becomes carbonyl; NO becomes nitrosyl.

5. Write the name of the central atom/ion. If the complex is an anion, the central atom’s name will end in -ate, and its Latin name will be used if available

6. If the central atom’s oxidation state needs to be specified (when it is one of several possible, or zero), write it as a Roman numeral (or 0) in parentheses.

7. End with “cation” or “anion” as separate words.

(b)

Interpretation Introduction

Interpretation:

The formulas of the given compound has to be written using its names has to be given.

Barium tetrabromoferrate (III)

Concept introduction;

The set of rules for naming a coordination compound is:

1. When naming a complex ion, the ligands are named before the metal ion.

2. Write the names of the ligands in the following order: neutral, negative, positive. If there are multiple ligands of the same charge type, they are named in alphabetical order.

3. Multiple occurring monodentate ligands receive a prefix according to the number of occurrences: di-, tri-, tetra-, penta-, or hexa. Polydentate ligands (e.g., ethylene diamine, oxalate) receive bis-, tris-, tetrakis-, etc. Anions end in -ido. This replaces the final “e” when the anion ends with “-ate” (e.g, sulfate becomes sulfato) and replaces “-ide” (cyanide becomes cyanido).

4. Neutral ligands are given their usual name, with some exceptions: NH₃ becomes ammine; H2O becomes aqua or aquo;CO becomes carbonyl; NO becomes nitrosyl.

5. Write the name of the central atom/ion. If the complex is an anion, the central atom’s name will end in -ate, and its Latin name will be used if available

6. If the central atom’s oxidation state needs to be specified (when it is one of several possible, or zero), write it as a Roman numeral (or 0) in parentheses.

7. End with “cation” or “anion” as separate words.

(c)

Interpretation Introduction

Interpretation:

The formulas of the given compound has to be written using its names has to be given.

Bis (ethylene diamine) platinum (II) carbonate

Concept introduction;

The set of rules for naming a coordination compound is:

1. When naming a complex ion, the ligands are named before the metal ion.

2. Write the names of the ligands in the following order: neutral, negative, positive. If there are multiple ligands of the same charge type, they are named in alphabetical order.

3. Multiple occurring monodentate ligands receive a prefix according to the number of occurrences: di-, tri-, tetra-, penta-, or hexa. Polydentate ligands (e.g., ethylene diamine, oxalate) receive bis-, tris-, tetrakis-, etc. Anions end in -ido. This replaces the final “e” when the anion ends with “-ate” (e.g, sulfate becomes sulfato) and replaces “-ide” (cyanide becomes cyanido).

4. Neutral ligands are given their usual name, with some exceptions: NH₃ becomes ammine; H2O becomes aqua or aquo;CO becomes carbonyl; NO becomes nitrosyl.

5. Write the name of the central atom/ion. If the complex is an anion, the central atom’s name will end in -ate, and its Latin name will be used if available

6. If the central atom’s oxidation state needs to be specified (when it is one of several possible, or zero), write it as a Roman numeral (or 0) in parentheses.

7. End with “cation” or “anion” as separate words.

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Experiment: Each team will be provided with 5g of a mixture of acetanilide and salicylic acid. You will divide it into three 1.5 g portions in separate 125 mL Erlenmeyer flasks savıng some for melting point analysis. Dissolve the mixture in each flask in ~60mL of DI water by heating to boiling on a hotplate. Take the flasks off the hotplate once you have a clear solution and let them stand on the bench top for 5 mins and then allow them to cool as described below. Sample A-Let the first sample cool slowly to room temperature by letting it stand on your lab bench, with occasional stirring to promote crystallization. Sample B-Cool the second sample 1n a tap-water bath to 10-15 °C Sample C-Cool the third sample in an ice-bath to 0-2 °C Results: weight after recrystalization and melting point temp. A=0.624g,102-115° B=0.765g, 80-105° C=1.135g, 77-108 What is the percent yield of A,B, and C.

Answer 2

Question

Chapter 23, Problem 23.57P

(a)

Interpretation Introduction

Interpretation:

The formulas of the given compound has to be written using its names has to be given.

Hexaaquachromium (III) sulfate

Concept introduction:

The set of rules for naming a coordination compound is:

1. When naming a complex ion, the ligands are named before the metal ion.

2. Write the names of the ligands in the following order: neutral, negative, positive. If there are multiple ligands of the same charge type, they are named in alphabetical order.

3. Multiple occurring monodentate ligands receive a prefix according to the number of occurrences: di-, tri-, tetra-, penta-, or hexa. Polydentate ligands (e.g., ethylene diamine, oxalate) receive bis-, tris-, tetrakis-, etc. Anions end in -ido. This replaces the final “e” when the anion ends with “-ate” (e.g, sulfate becomes sulfato) and replaces “-ide” (cyanide becomes cyanido).

4. Neutral ligands are given their usual name, with some exceptions: NH₃ becomes ammine; H2O becomes aqua or aquo;CO becomes carbonyl; NO becomes nitrosyl.

5. Write the name of the central atom/ion. If the complex is an anion, the central atom’s name will end in -ate, and its Latin name will be used if available

6. If the central atom’s oxidation state needs to be specified (when it is one of several possible, or zero), write it as a Roman numeral (or 0) in parentheses.

7. End with “cation” or “anion” as separate words.

(b)

Interpretation Introduction

Interpretation:

The formulas of the given compound has to be written using its names has to be given.

Barium tetrabromoferrate (III)

Concept introduction;

The set of rules for naming a coordination compound is:

1. When naming a complex ion, the ligands are named before the metal ion.

2. Write the names of the ligands in the following order: neutral, negative, positive. If there are multiple ligands of the same charge type, they are named in alphabetical order.

3. Multiple occurring monodentate ligands receive a prefix according to the number of occurrences: di-, tri-, tetra-, penta-, or hexa. Polydentate ligands (e.g., ethylene diamine, oxalate) receive bis-, tris-, tetrakis-, etc. Anions end in -ido. This replaces the final “e” when the anion ends with “-ate” (e.g, sulfate becomes sulfato) and replaces “-ide” (cyanide becomes cyanido).

4. Neutral ligands are given their usual name, with some exceptions: NH₃ becomes ammine; H2O becomes aqua or aquo;CO becomes carbonyl; NO becomes nitrosyl.

5. Write the name of the central atom/ion. If the complex is an anion, the central atom’s name will end in -ate, and its Latin name will be used if available

6. If the central atom’s oxidation state needs to be specified (when it is one of several possible, or zero), write it as a Roman numeral (or 0) in parentheses.

7. End with “cation” or “anion” as separate words.

(c)

Interpretation Introduction

Interpretation:

The formulas of the given compound has to be written using its names has to be given.

Bis (ethylene diamine) platinum (II) carbonate

Concept introduction;

The set of rules for naming a coordination compound is:

1. When naming a complex ion, the ligands are named before the metal ion.

2. Write the names of the ligands in the following order: neutral, negative, positive. If there are multiple ligands of the same charge type, they are named in alphabetical order.

3. Multiple occurring monodentate ligands receive a prefix according to the number of occurrences: di-, tri-, tetra-, penta-, or hexa. Polydentate ligands (e.g., ethylene diamine, oxalate) receive bis-, tris-, tetrakis-, etc. Anions end in -ido. This replaces the final “e” when the anion ends with “-ate” (e.g, sulfate becomes sulfato) and replaces “-ide” (cyanide becomes cyanido).

4. Neutral ligands are given their usual name, with some exceptions: NH₃ becomes ammine; H2O becomes aqua or aquo;CO becomes carbonyl; NO becomes nitrosyl.

5. Write the name of the central atom/ion. If the complex is an anion, the central atom’s name will end in -ate, and its Latin name will be used if available

6. If the central atom’s oxidation state needs to be specified (when it is one of several possible, or zero), write it as a Roman numeral (or 0) in parentheses.

7. End with “cation” or “anion” as separate words.

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Answer 3

Question

Chapter 23, Problem 23.57P

(a)

Interpretation Introduction

Interpretation:

The formulas of the given compound has to be written using its names has to be given.

Hexaaquachromium (III) sulfate

Concept introduction:

The set of rules for naming a coordination compound is:

1. When naming a complex ion, the ligands are named before the metal ion.

2. Write the names of the ligands in the following order: neutral, negative, positive. If there are multiple ligands of the same charge type, they are named in alphabetical order.

3. Multiple occurring monodentate ligands receive a prefix according to the number of occurrences: di-, tri-, tetra-, penta-, or hexa. Polydentate ligands (e.g., ethylene diamine, oxalate) receive bis-, tris-, tetrakis-, etc. Anions end in -ido. This replaces the final “e” when the anion ends with “-ate” (e.g, sulfate becomes sulfato) and replaces “-ide” (cyanide becomes cyanido).

4. Neutral ligands are given their usual name, with some exceptions: NH₃ becomes ammine; H2O becomes aqua or aquo;CO becomes carbonyl; NO becomes nitrosyl.

5. Write the name of the central atom/ion. If the complex is an anion, the central atom’s name will end in -ate, and its Latin name will be used if available

6. If the central atom’s oxidation state needs to be specified (when it is one of several possible, or zero), write it as a Roman numeral (or 0) in parentheses.

7. End with “cation” or “anion” as separate words.

(b)

Interpretation Introduction

Interpretation:

The formulas of the given compound has to be written using its names has to be given.

Barium tetrabromoferrate (III)

Concept introduction;

The set of rules for naming a coordination compound is:

1. When naming a complex ion, the ligands are named before the metal ion.

2. Write the names of the ligands in the following order: neutral, negative, positive. If there are multiple ligands of the same charge type, they are named in alphabetical order.

3. Multiple occurring monodentate ligands receive a prefix according to the number of occurrences: di-, tri-, tetra-, penta-, or hexa. Polydentate ligands (e.g., ethylene diamine, oxalate) receive bis-, tris-, tetrakis-, etc. Anions end in -ido. This replaces the final “e” when the anion ends with “-ate” (e.g, sulfate becomes sulfato) and replaces “-ide” (cyanide becomes cyanido).

4. Neutral ligands are given their usual name, with some exceptions: NH₃ becomes ammine; H2O becomes aqua or aquo;CO becomes carbonyl; NO becomes nitrosyl.

5. Write the name of the central atom/ion. If the complex is an anion, the central atom’s name will end in -ate, and its Latin name will be used if available

6. If the central atom’s oxidation state needs to be specified (when it is one of several possible, or zero), write it as a Roman numeral (or 0) in parentheses.

7. End with “cation” or “anion” as separate words.

(c)

Interpretation Introduction

Interpretation:

The formulas of the given compound has to be written using its names has to be given.

Bis (ethylene diamine) platinum (II) carbonate

Concept introduction;

The set of rules for naming a coordination compound is:

1. When naming a complex ion, the ligands are named before the metal ion.

2. Write the names of the ligands in the following order: neutral, negative, positive. If there are multiple ligands of the same charge type, they are named in alphabetical order.

3. Multiple occurring monodentate ligands receive a prefix according to the number of occurrences: di-, tri-, tetra-, penta-, or hexa. Polydentate ligands (e.g., ethylene diamine, oxalate) receive bis-, tris-, tetrakis-, etc. Anions end in -ido. This replaces the final “e” when the anion ends with “-ate” (e.g, sulfate becomes sulfato) and replaces “-ide” (cyanide becomes cyanido).

4. Neutral ligands are given their usual name, with some exceptions: NH₃ becomes ammine; H2O becomes aqua or aquo;CO becomes carbonyl; NO becomes nitrosyl.

5. Write the name of the central atom/ion. If the complex is an anion, the central atom’s name will end in -ate, and its Latin name will be used if available

6. If the central atom’s oxidation state needs to be specified (when it is one of several possible, or zero), write it as a Roman numeral (or 0) in parentheses.

7. End with “cation” or “anion” as separate words.

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Answer 4

Question

Chapter 23, Problem 23.57P

(a)

Interpretation Introduction

Interpretation:

The formulas of the given compound has to be written using its names has to be given.

Hexaaquachromium (III) sulfate

Concept introduction:

The set of rules for naming a coordination compound is:

1. When naming a complex ion, the ligands are named before the metal ion.

2. Write the names of the ligands in the following order: neutral, negative, positive. If there are multiple ligands of the same charge type, they are named in alphabetical order.

3. Multiple occurring monodentate ligands receive a prefix according to the number of occurrences: di-, tri-, tetra-, penta-, or hexa. Polydentate ligands (e.g., ethylene diamine, oxalate) receive bis-, tris-, tetrakis-, etc. Anions end in -ido. This replaces the final “e” when the anion ends with “-ate” (e.g, sulfate becomes sulfato) and replaces “-ide” (cyanide becomes cyanido).

4. Neutral ligands are given their usual name, with some exceptions: NH₃ becomes ammine; H2O becomes aqua or aquo;CO becomes carbonyl; NO becomes nitrosyl.

5. Write the name of the central atom/ion. If the complex is an anion, the central atom’s name will end in -ate, and its Latin name will be used if available

6. If the central atom’s oxidation state needs to be specified (when it is one of several possible, or zero), write it as a Roman numeral (or 0) in parentheses.

7. End with “cation” or “anion” as separate words.

(b)

Interpretation Introduction

Interpretation:

The formulas of the given compound has to be written using its names has to be given.

Barium tetrabromoferrate (III)

Concept introduction;

The set of rules for naming a coordination compound is:

1. When naming a complex ion, the ligands are named before the metal ion.

2. Write the names of the ligands in the following order: neutral, negative, positive. If there are multiple ligands of the same charge type, they are named in alphabetical order.

3. Multiple occurring monodentate ligands receive a prefix according to the number of occurrences: di-, tri-, tetra-, penta-, or hexa. Polydentate ligands (e.g., ethylene diamine, oxalate) receive bis-, tris-, tetrakis-, etc. Anions end in -ido. This replaces the final “e” when the anion ends with “-ate” (e.g, sulfate becomes sulfato) and replaces “-ide” (cyanide becomes cyanido).

4. Neutral ligands are given their usual name, with some exceptions: NH₃ becomes ammine; H2O becomes aqua or aquo;CO becomes carbonyl; NO becomes nitrosyl.

5. Write the name of the central atom/ion. If the complex is an anion, the central atom’s name will end in -ate, and its Latin name will be used if available

6. If the central atom’s oxidation state needs to be specified (when it is one of several possible, or zero), write it as a Roman numeral (or 0) in parentheses.

7. End with “cation” or “anion” as separate words.

(c)

Interpretation Introduction

Interpretation:

The formulas of the given compound has to be written using its names has to be given.

Bis (ethylene diamine) platinum (II) carbonate

Concept introduction;

The set of rules for naming a coordination compound is:

1. When naming a complex ion, the ligands are named before the metal ion.

2. Write the names of the ligands in the following order: neutral, negative, positive. If there are multiple ligands of the same charge type, they are named in alphabetical order.

3. Multiple occurring monodentate ligands receive a prefix according to the number of occurrences: di-, tri-, tetra-, penta-, or hexa. Polydentate ligands (e.g., ethylene diamine, oxalate) receive bis-, tris-, tetrakis-, etc. Anions end in -ido. This replaces the final “e” when the anion ends with “-ate” (e.g, sulfate becomes sulfato) and replaces “-ide” (cyanide becomes cyanido).

4. Neutral ligands are given their usual name, with some exceptions: NH₃ becomes ammine; H2O becomes aqua or aquo;CO becomes carbonyl; NO becomes nitrosyl.

5. Write the name of the central atom/ion. If the complex is an anion, the central atom’s name will end in -ate, and its Latin name will be used if available

6. If the central atom’s oxidation state needs to be specified (when it is one of several possible, or zero), write it as a Roman numeral (or 0) in parentheses.

7. End with “cation” or “anion” as separate words.

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Answer 5

Chapter 23, Problem 23.57P

(a)

Interpretation Introduction

Interpretation:

The formulas of the given compound has to be written using its names has to be given.

Hexaaquachromium (III) sulfate

Concept introduction:

The set of rules for naming a coordination compound is:

1. When naming a complex ion, the ligands are named before the metal ion.

2. Write the names of the ligands in the following order: neutral, negative, positive. If there are multiple ligands of the same charge type, they are named in alphabetical order.

3. Multiple occurring monodentate ligands receive a prefix according to the number of occurrences: di-, tri-, tetra-, penta-, or hexa. Polydentate ligands (e.g., ethylene diamine, oxalate) receive bis-, tris-, tetrakis-, etc. Anions end in -ido. This replaces the final “e” when the anion ends with “-ate” (e.g, sulfate becomes sulfato) and replaces “-ide” (cyanide becomes cyanido).

4. Neutral ligands are given their usual name, with some exceptions: NH₃ becomes ammine; H2O becomes aqua or aquo;CO becomes carbonyl; NO becomes nitrosyl.

5. Write the name of the central atom/ion. If the complex is an anion, the central atom’s name will end in -ate, and its Latin name will be used if available

6. If the central atom’s oxidation state needs to be specified (when it is one of several possible, or zero), write it as a Roman numeral (or 0) in parentheses.

7. End with “cation” or “anion” as separate words.

(b)

Interpretation Introduction

Interpretation:

The formulas of the given compound has to be written using its names has to be given.

Barium tetrabromoferrate (III)

Concept introduction;

The set of rules for naming a coordination compound is:

1. When naming a complex ion, the ligands are named before the metal ion.

2. Write the names of the ligands in the following order: neutral, negative, positive. If there are multiple ligands of the same charge type, they are named in alphabetical order.

3. Multiple occurring monodentate ligands receive a prefix according to the number of occurrences: di-, tri-, tetra-, penta-, or hexa. Polydentate ligands (e.g., ethylene diamine, oxalate) receive bis-, tris-, tetrakis-, etc. Anions end in -ido. This replaces the final “e” when the anion ends with “-ate” (e.g, sulfate becomes sulfato) and replaces “-ide” (cyanide becomes cyanido).

4. Neutral ligands are given their usual name, with some exceptions: NH₃ becomes ammine; H2O becomes aqua or aquo;CO becomes carbonyl; NO becomes nitrosyl.

5. Write the name of the central atom/ion. If the complex is an anion, the central atom’s name will end in -ate, and its Latin name will be used if available

6. If the central atom’s oxidation state needs to be specified (when it is one of several possible, or zero), write it as a Roman numeral (or 0) in parentheses.

7. End with “cation” or “anion” as separate words.

(c)

Interpretation Introduction

Interpretation:

The formulas of the given compound has to be written using its names has to be given.

Bis (ethylene diamine) platinum (II) carbonate

Concept introduction;

The set of rules for naming a coordination compound is:

1. When naming a complex ion, the ligands are named before the metal ion.

2. Write the names of the ligands in the following order: neutral, negative, positive. If there are multiple ligands of the same charge type, they are named in alphabetical order.

3. Multiple occurring monodentate ligands receive a prefix according to the number of occurrences: di-, tri-, tetra-, penta-, or hexa. Polydentate ligands (e.g., ethylene diamine, oxalate) receive bis-, tris-, tetrakis-, etc. Anions end in -ido. This replaces the final “e” when the anion ends with “-ate” (e.g, sulfate becomes sulfato) and replaces “-ide” (cyanide becomes cyanido).

4. Neutral ligands are given their usual name, with some exceptions: NH₃ becomes ammine; H2O becomes aqua or aquo;CO becomes carbonyl; NO becomes nitrosyl.

5. Write the name of the central atom/ion. If the complex is an anion, the central atom’s name will end in -ate, and its Latin name will be used if available

6. If the central atom’s oxidation state needs to be specified (when it is one of several possible, or zero), write it as a Roman numeral (or 0) in parentheses.

7. End with “cation” or “anion” as separate words.

Answer 6

Chapter 23, Problem 23.57P

(a)

Interpretation Introduction

Interpretation:

The formulas of the given compound has to be written using its names has to be given.

Hexaaquachromium (III) sulfate

Concept introduction:

The set of rules for naming a coordination compound is:

1. When naming a complex ion, the ligands are named before the metal ion.

2. Write the names of the ligands in the following order: neutral, negative, positive. If there are multiple ligands of the same charge type, they are named in alphabetical order.

3. Multiple occurring monodentate ligands receive a prefix according to the number of occurrences: di-, tri-, tetra-, penta-, or hexa. Polydentate ligands (e.g., ethylene diamine, oxalate) receive bis-, tris-, tetrakis-, etc. Anions end in -ido. This replaces the final “e” when the anion ends with “-ate” (e.g, sulfate becomes sulfato) and replaces “-ide” (cyanide becomes cyanido).

4. Neutral ligands are given their usual name, with some exceptions: NH₃ becomes ammine; H2O becomes aqua or aquo;CO becomes carbonyl; NO becomes nitrosyl.

5. Write the name of the central atom/ion. If the complex is an anion, the central atom’s name will end in -ate, and its Latin name will be used if available

6. If the central atom’s oxidation state needs to be specified (when it is one of several possible, or zero), write it as a Roman numeral (or 0) in parentheses.

7. End with “cation” or “anion” as separate words.

Answer 7

Chapter 23, Problem 23.57P

(a)

Interpretation Introduction

Interpretation:

The formulas of the given compound has to be written using its names has to be given.

Hexaaquachromium (III) sulfate

Concept introduction:

The set of rules for naming a coordination compound is:

1. When naming a complex ion, the ligands are named before the metal ion.

2. Write the names of the ligands in the following order: neutral, negative, positive. If there are multiple ligands of the same charge type, they are named in alphabetical order.

3. Multiple occurring monodentate ligands receive a prefix according to the number of occurrences: di-, tri-, tetra-, penta-, or hexa. Polydentate ligands (e.g., ethylene diamine, oxalate) receive bis-, tris-, tetrakis-, etc. Anions end in -ido. This replaces the final “e” when the anion ends with “-ate” (e.g, sulfate becomes sulfato) and replaces “-ide” (cyanide becomes cyanido).

4. Neutral ligands are given their usual name, with some exceptions: NH₃ becomes ammine; H2O becomes aqua or aquo;CO becomes carbonyl; NO becomes nitrosyl.

5. Write the name of the central atom/ion. If the complex is an anion, the central atom’s name will end in -ate, and its Latin name will be used if available

6. If the central atom’s oxidation state needs to be specified (when it is one of several possible, or zero), write it as a Roman numeral (or 0) in parentheses.

7. End with “cation” or “anion” as separate words.

Answer 8

(b)

Interpretation Introduction

Interpretation:

The formulas of the given compound has to be written using its names has to be given.

Barium tetrabromoferrate (III)

Concept introduction;

The set of rules for naming a coordination compound is:

1. When naming a complex ion, the ligands are named before the metal ion.

2. Write the names of the ligands in the following order: neutral, negative, positive. If there are multiple ligands of the same charge type, they are named in alphabetical order.

3. Multiple occurring monodentate ligands receive a prefix according to the number of occurrences: di-, tri-, tetra-, penta-, or hexa. Polydentate ligands (e.g., ethylene diamine, oxalate) receive bis-, tris-, tetrakis-, etc. Anions end in -ido. This replaces the final “e” when the anion ends with “-ate” (e.g, sulfate becomes sulfato) and replaces “-ide” (cyanide becomes cyanido).

4. Neutral ligands are given their usual name, with some exceptions: NH₃ becomes ammine; H2O becomes aqua or aquo;CO becomes carbonyl; NO becomes nitrosyl.

5. Write the name of the central atom/ion. If the complex is an anion, the central atom’s name will end in -ate, and its Latin name will be used if available

6. If the central atom’s oxidation state needs to be specified (when it is one of several possible, or zero), write it as a Roman numeral (or 0) in parentheses.

7. End with “cation” or “anion” as separate words.

Answer 9

(b)

Interpretation Introduction

Interpretation:

The formulas of the given compound has to be written using its names has to be given.

Barium tetrabromoferrate (III)

Concept introduction;

The set of rules for naming a coordination compound is:

1. When naming a complex ion, the ligands are named before the metal ion.

2. Write the names of the ligands in the following order: neutral, negative, positive. If there are multiple ligands of the same charge type, they are named in alphabetical order.

3. Multiple occurring monodentate ligands receive a prefix according to the number of occurrences: di-, tri-, tetra-, penta-, or hexa. Polydentate ligands (e.g., ethylene diamine, oxalate) receive bis-, tris-, tetrakis-, etc. Anions end in -ido. This replaces the final “e” when the anion ends with “-ate” (e.g, sulfate becomes sulfato) and replaces “-ide” (cyanide becomes cyanido).

4. Neutral ligands are given their usual name, with some exceptions: NH₃ becomes ammine; H2O becomes aqua or aquo;CO becomes carbonyl; NO becomes nitrosyl.

5. Write the name of the central atom/ion. If the complex is an anion, the central atom’s name will end in -ate, and its Latin name will be used if available

6. If the central atom’s oxidation state needs to be specified (when it is one of several possible, or zero), write it as a Roman numeral (or 0) in parentheses.

7. End with “cation” or “anion” as separate words.

Answer 10

(c)

Interpretation Introduction

Interpretation:

The formulas of the given compound has to be written using its names has to be given.

Bis (ethylene diamine) platinum (II) carbonate

Concept introduction;

The set of rules for naming a coordination compound is:

1. When naming a complex ion, the ligands are named before the metal ion.

2. Write the names of the ligands in the following order: neutral, negative, positive. If there are multiple ligands of the same charge type, they are named in alphabetical order.

3. Multiple occurring monodentate ligands receive a prefix according to the number of occurrences: di-, tri-, tetra-, penta-, or hexa. Polydentate ligands (e.g., ethylene diamine, oxalate) receive bis-, tris-, tetrakis-, etc. Anions end in -ido. This replaces the final “e” when the anion ends with “-ate” (e.g, sulfate becomes sulfato) and replaces “-ide” (cyanide becomes cyanido).

4. Neutral ligands are given their usual name, with some exceptions: NH₃ becomes ammine; H2O becomes aqua or aquo;CO becomes carbonyl; NO becomes nitrosyl.

5. Write the name of the central atom/ion. If the complex is an anion, the central atom’s name will end in -ate, and its Latin name will be used if available

6. If the central atom’s oxidation state needs to be specified (when it is one of several possible, or zero), write it as a Roman numeral (or 0) in parentheses.

7. End with “cation” or “anion” as separate words.

Answer 11

(c)

Interpretation Introduction

Interpretation:

The formulas of the given compound has to be written using its names has to be given.

Bis (ethylene diamine) platinum (II) carbonate

Concept introduction;

The set of rules for naming a coordination compound is:

1. When naming a complex ion, the ligands are named before the metal ion.

2. Write the names of the ligands in the following order: neutral, negative, positive. If there are multiple ligands of the same charge type, they are named in alphabetical order.

3. Multiple occurring monodentate ligands receive a prefix according to the number of occurrences: di-, tri-, tetra-, penta-, or hexa. Polydentate ligands (e.g., ethylene diamine, oxalate) receive bis-, tris-, tetrakis-, etc. Anions end in -ido. This replaces the final “e” when the anion ends with “-ate” (e.g, sulfate becomes sulfato) and replaces “-ide” (cyanide becomes cyanido).

4. Neutral ligands are given their usual name, with some exceptions: NH₃ becomes ammine; H2O becomes aqua or aquo;CO becomes carbonyl; NO becomes nitrosyl.

5. Write the name of the central atom/ion. If the complex is an anion, the central atom’s name will end in -ate, and its Latin name will be used if available

6. If the central atom’s oxidation state needs to be specified (when it is one of several possible, or zero), write it as a Roman numeral (or 0) in parentheses.

7. End with “cation” or “anion” as separate words.

Answer 12

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Answer 13

Expert Solution & Answer

Answer 14

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Answer 15

Ch. 23.1 - Write partial electron configurations (no noble...Ch. 23.1 - Find the charge of each of the following ions,...Ch. 23.2 - Prob. 23.2AFP Ch. 23.2 - Prob. 23.2BFP Ch. 23.3 - Give the coordination number and the charge of the...Ch. 23.3 - Write the formula of the coordination compound...Ch. 23.3 - Prob. 23.4AFP Ch. 23.3 - Prob. 23.4BFP Ch. 23.3 - Prob. 23.5AFP Ch. 23.3 - Prob. 23.5BFP

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