The orbital occupancy of the cobalt ion in [ Co ( CN ) 6 ] 3– has to be discussed. Concept introduction: Oxidation number: (Oxidation state) A number equal to the magnitude of the charge an atom would have if its shared electrons were transferred to the atom that attracts them more strongly. If the metal complex have unpaired electrons that metal has paramagnetic nature. If the metal complex have no paired electrons that metal has diamagnetic nature.

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Answer 1

Question

Chapter 23, Problem 23.122P

(a)

Interpretation Introduction

Interpretation:

The orbital occupancy of the cobalt ion in [Co(CN)6]3– has to be discussed.

Concept introduction:

Oxidation number: (Oxidation state) A number equal to the magnitude of the charge an atom would have if its shared electrons were transferred to the atom that attracts them more strongly.

If the metal complex have unpaired electrons that metal has paramagnetic nature.

If the metal complex have no paired electrons that metal has diamagnetic nature.

(b)

Interpretation Introduction

Interpretation:

The orbital occupancy of the cobalt ion in [Co(CN)6]3– has to be discussed.

Concept introduction:

Oxidation number: (Oxidation state) A number equal to the magnitude of the charge an atom would have if its shared electrons were transferred to the atom that attracts them more strongly.

If the metal complex have unpaired electrons that metal has paramagnetic nature.

If the metal complex have no paired electrons that metal has diamagnetic nature.

(c)

Interpretation Introduction

Interpretation:

The orbital occupancy of the cobalt ion in [Co(CN)6]3– has to be discussed.

Concept introduction:

Oxidation number: (Oxidation state) A number equal to the magnitude of the charge an atom would have if its shared electrons were transferred to the atom that attracts them more strongly.

If the metal complex have unpaired electrons that metal has paramagnetic nature.

If the metal complex have no paired electrons that metal has diamagnetic nature.

(d)

Interpretation Introduction

Interpretation:

The orbital occupancy of the cobalt ion in [Co(CN)6]3– has to be discussed.

Concept introduction:

Oxidation number: (Oxidation state) A number equal to the magnitude of the charge an atom would have if its shared electrons were transferred to the atom that attracts them more strongly.

If the metal complex have unpaired electrons that metal has paramagnetic nature.

If the metal complex have no paired electrons that metal has diamagnetic nature.

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Answer 2

Question

Chapter 23, Problem 23.122P

(a)

Interpretation Introduction

Interpretation:

The orbital occupancy of the cobalt ion in [Co(CN)6]3– has to be discussed.

Concept introduction:

Oxidation number: (Oxidation state) A number equal to the magnitude of the charge an atom would have if its shared electrons were transferred to the atom that attracts them more strongly.

If the metal complex have unpaired electrons that metal has paramagnetic nature.

If the metal complex have no paired electrons that metal has diamagnetic nature.

(b)

Interpretation Introduction

Interpretation:

The orbital occupancy of the cobalt ion in [Co(CN)6]3– has to be discussed.

Concept introduction:

Oxidation number: (Oxidation state) A number equal to the magnitude of the charge an atom would have if its shared electrons were transferred to the atom that attracts them more strongly.

If the metal complex have unpaired electrons that metal has paramagnetic nature.

If the metal complex have no paired electrons that metal has diamagnetic nature.

(c)

Interpretation Introduction

Interpretation:

The orbital occupancy of the cobalt ion in [Co(CN)6]3– has to be discussed.

Concept introduction:

Oxidation number: (Oxidation state) A number equal to the magnitude of the charge an atom would have if its shared electrons were transferred to the atom that attracts them more strongly.

If the metal complex have unpaired electrons that metal has paramagnetic nature.

If the metal complex have no paired electrons that metal has diamagnetic nature.

(d)

Interpretation Introduction

Interpretation:

The orbital occupancy of the cobalt ion in [Co(CN)6]3– has to be discussed.

Concept introduction:

Oxidation number: (Oxidation state) A number equal to the magnitude of the charge an atom would have if its shared electrons were transferred to the atom that attracts them more strongly.

If the metal complex have unpaired electrons that metal has paramagnetic nature.

If the metal complex have no paired electrons that metal has diamagnetic nature.

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Answer 3

Question

Chapter 23, Problem 23.122P

(a)

Interpretation Introduction

Interpretation:

The orbital occupancy of the cobalt ion in [Co(CN)6]3– has to be discussed.

Concept introduction:

Oxidation number: (Oxidation state) A number equal to the magnitude of the charge an atom would have if its shared electrons were transferred to the atom that attracts them more strongly.

If the metal complex have unpaired electrons that metal has paramagnetic nature.

If the metal complex have no paired electrons that metal has diamagnetic nature.

(b)

Interpretation Introduction

Interpretation:

The orbital occupancy of the cobalt ion in [Co(CN)6]3– has to be discussed.

Concept introduction:

Oxidation number: (Oxidation state) A number equal to the magnitude of the charge an atom would have if its shared electrons were transferred to the atom that attracts them more strongly.

If the metal complex have unpaired electrons that metal has paramagnetic nature.

If the metal complex have no paired electrons that metal has diamagnetic nature.

(c)

Interpretation Introduction

Interpretation:

The orbital occupancy of the cobalt ion in [Co(CN)6]3– has to be discussed.

Concept introduction:

Oxidation number: (Oxidation state) A number equal to the magnitude of the charge an atom would have if its shared electrons were transferred to the atom that attracts them more strongly.

If the metal complex have unpaired electrons that metal has paramagnetic nature.

If the metal complex have no paired electrons that metal has diamagnetic nature.

(d)

Interpretation Introduction

Interpretation:

The orbital occupancy of the cobalt ion in [Co(CN)6]3– has to be discussed.

Concept introduction:

Oxidation number: (Oxidation state) A number equal to the magnitude of the charge an atom would have if its shared electrons were transferred to the atom that attracts them more strongly.

If the metal complex have unpaired electrons that metal has paramagnetic nature.

If the metal complex have no paired electrons that metal has diamagnetic nature.

Expert Solution & Answer

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Answer 4

Question

Chapter 23, Problem 23.122P

(a)

Interpretation Introduction

Interpretation:

The orbital occupancy of the cobalt ion in [Co(CN)6]3– has to be discussed.

Concept introduction:

Oxidation number: (Oxidation state) A number equal to the magnitude of the charge an atom would have if its shared electrons were transferred to the atom that attracts them more strongly.

If the metal complex have unpaired electrons that metal has paramagnetic nature.

If the metal complex have no paired electrons that metal has diamagnetic nature.

(b)

Interpretation Introduction

Interpretation:

The orbital occupancy of the cobalt ion in [Co(CN)6]3– has to be discussed.

Concept introduction:

Oxidation number: (Oxidation state) A number equal to the magnitude of the charge an atom would have if its shared electrons were transferred to the atom that attracts them more strongly.

If the metal complex have unpaired electrons that metal has paramagnetic nature.

If the metal complex have no paired electrons that metal has diamagnetic nature.

(c)

Interpretation Introduction

Interpretation:

The orbital occupancy of the cobalt ion in [Co(CN)6]3– has to be discussed.

Concept introduction:

Oxidation number: (Oxidation state) A number equal to the magnitude of the charge an atom would have if its shared electrons were transferred to the atom that attracts them more strongly.

If the metal complex have unpaired electrons that metal has paramagnetic nature.

If the metal complex have no paired electrons that metal has diamagnetic nature.

(d)

Interpretation Introduction

Interpretation:

The orbital occupancy of the cobalt ion in [Co(CN)6]3– has to be discussed.

Concept introduction:

Oxidation number: (Oxidation state) A number equal to the magnitude of the charge an atom would have if its shared electrons were transferred to the atom that attracts them more strongly.

If the metal complex have unpaired electrons that metal has paramagnetic nature.

If the metal complex have no paired electrons that metal has diamagnetic nature.

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Answer 5

Chapter 23, Problem 23.122P

(a)

Interpretation Introduction

Interpretation:

The orbital occupancy of the cobalt ion in [Co(CN)6]3– has to be discussed.

Concept introduction:

Oxidation number: (Oxidation state) A number equal to the magnitude of the charge an atom would have if its shared electrons were transferred to the atom that attracts them more strongly.

If the metal complex have unpaired electrons that metal has paramagnetic nature.

If the metal complex have no paired electrons that metal has diamagnetic nature.

(b)

Interpretation Introduction

Interpretation:

The orbital occupancy of the cobalt ion in [Co(CN)6]3– has to be discussed.

Concept introduction:

Oxidation number: (Oxidation state) A number equal to the magnitude of the charge an atom would have if its shared electrons were transferred to the atom that attracts them more strongly.

If the metal complex have unpaired electrons that metal has paramagnetic nature.

If the metal complex have no paired electrons that metal has diamagnetic nature.

(c)

Interpretation Introduction

Interpretation:

The orbital occupancy of the cobalt ion in [Co(CN)6]3– has to be discussed.

Concept introduction:

Oxidation number: (Oxidation state) A number equal to the magnitude of the charge an atom would have if its shared electrons were transferred to the atom that attracts them more strongly.

If the metal complex have unpaired electrons that metal has paramagnetic nature.

If the metal complex have no paired electrons that metal has diamagnetic nature.

(d)

Interpretation Introduction

Interpretation:

The orbital occupancy of the cobalt ion in [Co(CN)6]3– has to be discussed.

Concept introduction:

Oxidation number: (Oxidation state) A number equal to the magnitude of the charge an atom would have if its shared electrons were transferred to the atom that attracts them more strongly.

If the metal complex have unpaired electrons that metal has paramagnetic nature.

If the metal complex have no paired electrons that metal has diamagnetic nature.

Answer 6

Chapter 23, Problem 23.122P

(a)

Interpretation Introduction

Interpretation:

The orbital occupancy of the cobalt ion in [Co(CN)6]3– has to be discussed.

Concept introduction:

Oxidation number: (Oxidation state) A number equal to the magnitude of the charge an atom would have if its shared electrons were transferred to the atom that attracts them more strongly.

If the metal complex have unpaired electrons that metal has paramagnetic nature.

If the metal complex have no paired electrons that metal has diamagnetic nature.

Answer 7

Chapter 23, Problem 23.122P

(a)

Interpretation Introduction

Interpretation:

The orbital occupancy of the cobalt ion in [Co(CN)6]3– has to be discussed.

Concept introduction:

Oxidation number: (Oxidation state) A number equal to the magnitude of the charge an atom would have if its shared electrons were transferred to the atom that attracts them more strongly.

If the metal complex have unpaired electrons that metal has paramagnetic nature.

If the metal complex have no paired electrons that metal has diamagnetic nature.

Answer 8

(b)

Interpretation Introduction

Interpretation:

The orbital occupancy of the cobalt ion in [Co(CN)6]3– has to be discussed.

Concept introduction:

Oxidation number: (Oxidation state) A number equal to the magnitude of the charge an atom would have if its shared electrons were transferred to the atom that attracts them more strongly.

If the metal complex have unpaired electrons that metal has paramagnetic nature.

If the metal complex have no paired electrons that metal has diamagnetic nature.

Answer 9

(b)

Interpretation Introduction

Interpretation:

The orbital occupancy of the cobalt ion in [Co(CN)6]3– has to be discussed.

Concept introduction:

Oxidation number: (Oxidation state) A number equal to the magnitude of the charge an atom would have if its shared electrons were transferred to the atom that attracts them more strongly.

If the metal complex have unpaired electrons that metal has paramagnetic nature.

If the metal complex have no paired electrons that metal has diamagnetic nature.

Answer 10

(c)

Interpretation Introduction

Interpretation:

The orbital occupancy of the cobalt ion in [Co(CN)6]3– has to be discussed.

Concept introduction:

Oxidation number: (Oxidation state) A number equal to the magnitude of the charge an atom would have if its shared electrons were transferred to the atom that attracts them more strongly.

If the metal complex have unpaired electrons that metal has paramagnetic nature.

If the metal complex have no paired electrons that metal has diamagnetic nature.

Answer 11

(c)

Interpretation Introduction

Interpretation:

The orbital occupancy of the cobalt ion in [Co(CN)6]3– has to be discussed.

Concept introduction:

Oxidation number: (Oxidation state) A number equal to the magnitude of the charge an atom would have if its shared electrons were transferred to the atom that attracts them more strongly.

If the metal complex have unpaired electrons that metal has paramagnetic nature.

If the metal complex have no paired electrons that metal has diamagnetic nature.

Answer 12

(d)

Interpretation Introduction

Interpretation:

The orbital occupancy of the cobalt ion in [Co(CN)6]3– has to be discussed.

Concept introduction:

Oxidation number: (Oxidation state) A number equal to the magnitude of the charge an atom would have if its shared electrons were transferred to the atom that attracts them more strongly.

If the metal complex have unpaired electrons that metal has paramagnetic nature.

If the metal complex have no paired electrons that metal has diamagnetic nature.

Answer 13

(d)

Interpretation Introduction

Interpretation:

The orbital occupancy of the cobalt ion in [Co(CN)6]3– has to be discussed.

Concept introduction:

Oxidation number: (Oxidation state) A number equal to the magnitude of the charge an atom would have if its shared electrons were transferred to the atom that attracts them more strongly.

If the metal complex have unpaired electrons that metal has paramagnetic nature.

If the metal complex have no paired electrons that metal has diamagnetic nature.

Answer 14

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Answer 15

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Answer 16

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Answer 17

Ch. 23.1 - Write partial electron configurations (no noble...Ch. 23.1 - Find the charge of each of the following ions,...Ch. 23.2 - Prob. 23.2AFP Ch. 23.2 - Prob. 23.2BFP Ch. 23.3 - Give the coordination number and the charge of the...Ch. 23.3 - Write the formula of the coordination compound...Ch. 23.3 - Prob. 23.4AFP Ch. 23.3 - Prob. 23.4BFP Ch. 23.3 - Prob. 23.5AFP Ch. 23.3 - Prob. 23.5BFP

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Chapter 23 Solutions