The wavelength of maximum absorption and the crystal field splitting energy have to be calculated. Concept introduction: Crystal field splitting: The energy gap between the splitting of d-orbitals of the metal ion in presence of ligands is known as the crystal field splitting (Δ) . The magnitude of (Δ) is depends on the nature of metal ions and the ligands. The fact that colour depends on the ligand allows us to create a spectrochemical series, which ranks the ability of a ligand to split d-orbital energies. The relative magnitude of Δ for a series of octahedral complexes of a given metal ion. As Δ increases, higher energies (shorter wavelengths) of light must be absorbed to excite electrons. The spectrochemical series is I − < C l − < F − < O H − < H 2 O < S C N − < e n < N O 2 − < C N − < C O

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Answer 1

Question

Chapter 23, Problem 23.120P

(a)

Interpretation Introduction

Interpretation:

The wavelength of maximum absorption and the crystal field splitting energy have to be calculated.

Concept introduction:

Crystal field splitting: The energy gap between the splitting of d-orbitals of the metal ion in presence of ligands is known as the crystal field splitting (Δ). The magnitude of (Δ) is depends on the nature of metal ions and the ligands.

The fact that colour depends on the ligand allows us to create a spectrochemical series, which ranks the ability of a ligand to split d-orbital energies.

The relative magnitude of Δ for a series of octahedral complexes of a given metal ion. As Δ increases, higher energies (shorter wavelengths) of light must be absorbed to excite electrons.

The spectrochemical series is

I−<Cl−<F−<OH−<H2O<SCN−<en<NO2−<CN−<CO

(b)

Interpretation Introduction

Interpretation:

The spectrochemical series for the ligand in the Chromium complex has to be written.

Concept introduction:

The fact that colour depends on the ligand allows us to create a spectrochemical series, which ranks the ability of a ligand to split d-orbital energies.

The relative magnitude of Δ for a series of octahedral complexes of a given metal ion. As Δ increases, higher energies (shorter wavelengths) of light must be absorbed to excite electrons.

The spectrochemical series is

I−<Cl−<F−<OH−<H2O<SCN−<en<NO2−<CN−<CO

(c)

Interpretation Introduction

Interpretation:

The Iron data is affect the oxidation state has to be explained.

Concept introduction:

Oxidation number: (Oxidation state) A number equal to the magnitude of the charge an atom would have if its shared electrons were transferred to the atom that attracts them more strongly.

The spectrochemical series is

I−<Cl−<F−<OH−<H2O<SCN−<en<NO2−<CN−<CO

(d)

Interpretation Introduction

Interpretation:

The Cobalt, Rhodium and Iron atom affect the periodic number has to be discussed.

Concept introduction:

The fact that colour depends on the ligand allows us to create a spectrochemical series, which ranks the ability of a ligand to split d-orbital energies.

The relative magnitude of Δ for a series of octahedral complexes of a given metal ion. As Δ increases, higher energies (shorter wavelengths) of light must be absorbed to excite electrons.

The spectrochemical series is

I−<Cl−<F−<OH−<H2O<SCN−<en<NO2−<CN−<CO

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Answer 2

Question

Chapter 23, Problem 23.120P

(a)

Interpretation Introduction

Interpretation:

The wavelength of maximum absorption and the crystal field splitting energy have to be calculated.

Concept introduction:

Crystal field splitting: The energy gap between the splitting of d-orbitals of the metal ion in presence of ligands is known as the crystal field splitting (Δ). The magnitude of (Δ) is depends on the nature of metal ions and the ligands.

The fact that colour depends on the ligand allows us to create a spectrochemical series, which ranks the ability of a ligand to split d-orbital energies.

The relative magnitude of Δ for a series of octahedral complexes of a given metal ion. As Δ increases, higher energies (shorter wavelengths) of light must be absorbed to excite electrons.

The spectrochemical series is

I−<Cl−<F−<OH−<H2O<SCN−<en<NO2−<CN−<CO

(b)

Interpretation Introduction

Interpretation:

The spectrochemical series for the ligand in the Chromium complex has to be written.

Concept introduction:

The fact that colour depends on the ligand allows us to create a spectrochemical series, which ranks the ability of a ligand to split d-orbital energies.

The relative magnitude of Δ for a series of octahedral complexes of a given metal ion. As Δ increases, higher energies (shorter wavelengths) of light must be absorbed to excite electrons.

The spectrochemical series is

I−<Cl−<F−<OH−<H2O<SCN−<en<NO2−<CN−<CO

(c)

Interpretation Introduction

Interpretation:

The Iron data is affect the oxidation state has to be explained.

Concept introduction:

Oxidation number: (Oxidation state) A number equal to the magnitude of the charge an atom would have if its shared electrons were transferred to the atom that attracts them more strongly.

The spectrochemical series is

I−<Cl−<F−<OH−<H2O<SCN−<en<NO2−<CN−<CO

(d)

Interpretation Introduction

Interpretation:

The Cobalt, Rhodium and Iron atom affect the periodic number has to be discussed.

Concept introduction:

The fact that colour depends on the ligand allows us to create a spectrochemical series, which ranks the ability of a ligand to split d-orbital energies.

The relative magnitude of Δ for a series of octahedral complexes of a given metal ion. As Δ increases, higher energies (shorter wavelengths) of light must be absorbed to excite electrons.

The spectrochemical series is

I−<Cl−<F−<OH−<H2O<SCN−<en<NO2−<CN−<CO

Expert Solution & Answer

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Answer 3

Question

Chapter 23, Problem 23.120P

(a)

Interpretation Introduction

Interpretation:

The wavelength of maximum absorption and the crystal field splitting energy have to be calculated.

Concept introduction:

Crystal field splitting: The energy gap between the splitting of d-orbitals of the metal ion in presence of ligands is known as the crystal field splitting (Δ). The magnitude of (Δ) is depends on the nature of metal ions and the ligands.

The fact that colour depends on the ligand allows us to create a spectrochemical series, which ranks the ability of a ligand to split d-orbital energies.

The relative magnitude of Δ for a series of octahedral complexes of a given metal ion. As Δ increases, higher energies (shorter wavelengths) of light must be absorbed to excite electrons.

The spectrochemical series is

I−<Cl−<F−<OH−<H2O<SCN−<en<NO2−<CN−<CO

(b)

Interpretation Introduction

Interpretation:

The spectrochemical series for the ligand in the Chromium complex has to be written.

Concept introduction:

The fact that colour depends on the ligand allows us to create a spectrochemical series, which ranks the ability of a ligand to split d-orbital energies.

The relative magnitude of Δ for a series of octahedral complexes of a given metal ion. As Δ increases, higher energies (shorter wavelengths) of light must be absorbed to excite electrons.

The spectrochemical series is

I−<Cl−<F−<OH−<H2O<SCN−<en<NO2−<CN−<CO

(c)

Interpretation Introduction

Interpretation:

The Iron data is affect the oxidation state has to be explained.

Concept introduction:

Oxidation number: (Oxidation state) A number equal to the magnitude of the charge an atom would have if its shared electrons were transferred to the atom that attracts them more strongly.

The spectrochemical series is

I−<Cl−<F−<OH−<H2O<SCN−<en<NO2−<CN−<CO

(d)

Interpretation Introduction

Interpretation:

The Cobalt, Rhodium and Iron atom affect the periodic number has to be discussed.

Concept introduction:

The fact that colour depends on the ligand allows us to create a spectrochemical series, which ranks the ability of a ligand to split d-orbital energies.

The relative magnitude of Δ for a series of octahedral complexes of a given metal ion. As Δ increases, higher energies (shorter wavelengths) of light must be absorbed to excite electrons.

The spectrochemical series is

I−<Cl−<F−<OH−<H2O<SCN−<en<NO2−<CN−<CO

Expert Solution & Answer

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Check out a sample textbook solution

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Answer 4

Question

Chapter 23, Problem 23.120P

(a)

Interpretation Introduction

Interpretation:

The wavelength of maximum absorption and the crystal field splitting energy have to be calculated.

Concept introduction:

Crystal field splitting: The energy gap between the splitting of d-orbitals of the metal ion in presence of ligands is known as the crystal field splitting (Δ). The magnitude of (Δ) is depends on the nature of metal ions and the ligands.

The fact that colour depends on the ligand allows us to create a spectrochemical series, which ranks the ability of a ligand to split d-orbital energies.

The relative magnitude of Δ for a series of octahedral complexes of a given metal ion. As Δ increases, higher energies (shorter wavelengths) of light must be absorbed to excite electrons.

The spectrochemical series is

I−<Cl−<F−<OH−<H2O<SCN−<en<NO2−<CN−<CO

(b)

Interpretation Introduction

Interpretation:

The spectrochemical series for the ligand in the Chromium complex has to be written.

Concept introduction:

The fact that colour depends on the ligand allows us to create a spectrochemical series, which ranks the ability of a ligand to split d-orbital energies.

The relative magnitude of Δ for a series of octahedral complexes of a given metal ion. As Δ increases, higher energies (shorter wavelengths) of light must be absorbed to excite electrons.

The spectrochemical series is

I−<Cl−<F−<OH−<H2O<SCN−<en<NO2−<CN−<CO

(c)

Interpretation Introduction

Interpretation:

The Iron data is affect the oxidation state has to be explained.

Concept introduction:

Oxidation number: (Oxidation state) A number equal to the magnitude of the charge an atom would have if its shared electrons were transferred to the atom that attracts them more strongly.

The spectrochemical series is

I−<Cl−<F−<OH−<H2O<SCN−<en<NO2−<CN−<CO

(d)

Interpretation Introduction

Interpretation:

The Cobalt, Rhodium and Iron atom affect the periodic number has to be discussed.

Concept introduction:

The fact that colour depends on the ligand allows us to create a spectrochemical series, which ranks the ability of a ligand to split d-orbital energies.

The relative magnitude of Δ for a series of octahedral complexes of a given metal ion. As Δ increases, higher energies (shorter wavelengths) of light must be absorbed to excite electrons.

The spectrochemical series is

I−<Cl−<F−<OH−<H2O<SCN−<en<NO2−<CN−<CO

Expert Solution & Answer

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Check out a sample textbook solution

See solution

Answer 5

Chapter 23, Problem 23.120P

(a)

Interpretation Introduction

Interpretation:

The wavelength of maximum absorption and the crystal field splitting energy have to be calculated.

Concept introduction:

Crystal field splitting: The energy gap between the splitting of d-orbitals of the metal ion in presence of ligands is known as the crystal field splitting (Δ). The magnitude of (Δ) is depends on the nature of metal ions and the ligands.

The fact that colour depends on the ligand allows us to create a spectrochemical series, which ranks the ability of a ligand to split d-orbital energies.

The relative magnitude of Δ for a series of octahedral complexes of a given metal ion. As Δ increases, higher energies (shorter wavelengths) of light must be absorbed to excite electrons.

The spectrochemical series is

I−<Cl−<F−<OH−<H2O<SCN−<en<NO2−<CN−<CO

(b)

Interpretation Introduction

Interpretation:

The spectrochemical series for the ligand in the Chromium complex has to be written.

Concept introduction:

The fact that colour depends on the ligand allows us to create a spectrochemical series, which ranks the ability of a ligand to split d-orbital energies.

The relative magnitude of Δ for a series of octahedral complexes of a given metal ion. As Δ increases, higher energies (shorter wavelengths) of light must be absorbed to excite electrons.

The spectrochemical series is

I−<Cl−<F−<OH−<H2O<SCN−<en<NO2−<CN−<CO

(c)

Interpretation Introduction

Interpretation:

The Iron data is affect the oxidation state has to be explained.

Concept introduction:

Oxidation number: (Oxidation state) A number equal to the magnitude of the charge an atom would have if its shared electrons were transferred to the atom that attracts them more strongly.

The spectrochemical series is

I−<Cl−<F−<OH−<H2O<SCN−<en<NO2−<CN−<CO

(d)

Interpretation Introduction

Interpretation:

The Cobalt, Rhodium and Iron atom affect the periodic number has to be discussed.

Concept introduction:

The fact that colour depends on the ligand allows us to create a spectrochemical series, which ranks the ability of a ligand to split d-orbital energies.

The relative magnitude of Δ for a series of octahedral complexes of a given metal ion. As Δ increases, higher energies (shorter wavelengths) of light must be absorbed to excite electrons.

The spectrochemical series is

I−<Cl−<F−<OH−<H2O<SCN−<en<NO2−<CN−<CO

Answer 6

Chapter 23, Problem 23.120P

(a)

Interpretation Introduction

Interpretation:

The wavelength of maximum absorption and the crystal field splitting energy have to be calculated.

Concept introduction:

Crystal field splitting: The energy gap between the splitting of d-orbitals of the metal ion in presence of ligands is known as the crystal field splitting (Δ). The magnitude of (Δ) is depends on the nature of metal ions and the ligands.

The fact that colour depends on the ligand allows us to create a spectrochemical series, which ranks the ability of a ligand to split d-orbital energies.

The relative magnitude of Δ for a series of octahedral complexes of a given metal ion. As Δ increases, higher energies (shorter wavelengths) of light must be absorbed to excite electrons.

The spectrochemical series is

I−<Cl−<F−<OH−<H2O<SCN−<en<NO2−<CN−<CO

Answer 7

Chapter 23, Problem 23.120P

(a)

Interpretation Introduction

Interpretation:

The wavelength of maximum absorption and the crystal field splitting energy have to be calculated.

Concept introduction:

Crystal field splitting: The energy gap between the splitting of d-orbitals of the metal ion in presence of ligands is known as the crystal field splitting (Δ). The magnitude of (Δ) is depends on the nature of metal ions and the ligands.

The fact that colour depends on the ligand allows us to create a spectrochemical series, which ranks the ability of a ligand to split d-orbital energies.

The relative magnitude of Δ for a series of octahedral complexes of a given metal ion. As Δ increases, higher energies (shorter wavelengths) of light must be absorbed to excite electrons.

The spectrochemical series is

I−<Cl−<F−<OH−<H2O<SCN−<en<NO2−<CN−<CO

Answer 8

(b)

Interpretation Introduction

Interpretation:

The spectrochemical series for the ligand in the Chromium complex has to be written.

Concept introduction:

The fact that colour depends on the ligand allows us to create a spectrochemical series, which ranks the ability of a ligand to split d-orbital energies.

The relative magnitude of Δ for a series of octahedral complexes of a given metal ion. As Δ increases, higher energies (shorter wavelengths) of light must be absorbed to excite electrons.

The spectrochemical series is

I−<Cl−<F−<OH−<H2O<SCN−<en<NO2−<CN−<CO

Answer 9

(b)

Interpretation Introduction

Interpretation:

The spectrochemical series for the ligand in the Chromium complex has to be written.

Concept introduction:

The fact that colour depends on the ligand allows us to create a spectrochemical series, which ranks the ability of a ligand to split d-orbital energies.

The relative magnitude of Δ for a series of octahedral complexes of a given metal ion. As Δ increases, higher energies (shorter wavelengths) of light must be absorbed to excite electrons.

The spectrochemical series is

I−<Cl−<F−<OH−<H2O<SCN−<en<NO2−<CN−<CO

Answer 10

(c)

Interpretation Introduction

Interpretation:

The Iron data is affect the oxidation state has to be explained.

Concept introduction:

Oxidation number: (Oxidation state) A number equal to the magnitude of the charge an atom would have if its shared electrons were transferred to the atom that attracts them more strongly.

The spectrochemical series is

I−<Cl−<F−<OH−<H2O<SCN−<en<NO2−<CN−<CO

Answer 11

(c)

Interpretation Introduction

Interpretation:

The Iron data is affect the oxidation state has to be explained.

Concept introduction:

Oxidation number: (Oxidation state) A number equal to the magnitude of the charge an atom would have if its shared electrons were transferred to the atom that attracts them more strongly.

The spectrochemical series is

I−<Cl−<F−<OH−<H2O<SCN−<en<NO2−<CN−<CO

Answer 12

(d)

Interpretation Introduction

Interpretation:

The Cobalt, Rhodium and Iron atom affect the periodic number has to be discussed.

Concept introduction:

The fact that colour depends on the ligand allows us to create a spectrochemical series, which ranks the ability of a ligand to split d-orbital energies.

The relative magnitude of Δ for a series of octahedral complexes of a given metal ion. As Δ increases, higher energies (shorter wavelengths) of light must be absorbed to excite electrons.

The spectrochemical series is

I−<Cl−<F−<OH−<H2O<SCN−<en<NO2−<CN−<CO

Answer 13

(d)

Interpretation Introduction

Interpretation:

The Cobalt, Rhodium and Iron atom affect the periodic number has to be discussed.

Concept introduction:

The fact that colour depends on the ligand allows us to create a spectrochemical series, which ranks the ability of a ligand to split d-orbital energies.

The relative magnitude of Δ for a series of octahedral complexes of a given metal ion. As Δ increases, higher energies (shorter wavelengths) of light must be absorbed to excite electrons.

The spectrochemical series is

I−<Cl−<F−<OH−<H2O<SCN−<en<NO2−<CN−<CO

Answer 14

Expert Solution & Answer

Answer 15

Expert Solution & Answer

Answer 16

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Answer 17

Ch. 23.1 - Write partial electron configurations (no noble...Ch. 23.1 - Find the charge of each of the following ions,...Ch. 23.2 - Prob. 23.2AFP Ch. 23.2 - Prob. 23.2BFP Ch. 23.3 - Give the coordination number and the charge of the...Ch. 23.3 - Write the formula of the coordination compound...Ch. 23.3 - Prob. 23.4AFP Ch. 23.3 - Prob. 23.4BFP Ch. 23.3 - Prob. 23.5AFP Ch. 23.3 - Prob. 23.5BFP

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