Chemistry: A Molecular Approach, Books a la Carte Edition; Modified MasteringChemistry with Pearson eText -- ValuePack Access Card -- for Chemistry: A Molecular Approach, 4/e
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Chapter 23, Problem 107QGW
Interpretation Introduction
To explain: The trend of periodic properties across 2nd period and 6A group.
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Draw the anti-Markovnikov product of the hydration of this alkene.
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AG/F-2° V
3. Before proceeding with this problem you may want to glance at p. 466 of your textbook
where various oxo-phosphorus derivatives and their oxidation states are summarized.
Shown below are Latimer diagrams for phosphorus at pH values at 0 and 14:
-0.93
+0.38
-0.50
-0.51 -0.06
H3PO4 →H4P206 →H3PO3 →→H3PO₂ → P → PH3
Acidic solution
Basic solution
-0.28
-0.50
3--1.12
-1.57
-2.05 -0.89
PO HPO H₂PO₂ →P → PH3
-1.73
a) Under acidic conditions, H3PO4 can be reduced into H3PO3 directly (-0.28V), or via the
formation and reduction of H4P206 (-0.93/+0.38V). Calculate the values of AG's for both
processes; comment.
(3 points)
0.5
PH
P
0.0
-0.5
-1.0-
-1.5-
-2.0
H.PO,
-2.3+
-3 -2
-1
1
2
3
2
H,PO,
b) Frost diagram for phosphorus under acidic
conditions is shown. Identify possible
disproportionation and comproportionation processes;
write out chemical equations describing them. (2 points)
H,PO
4
S
Oxidation stale, N
Chapter 23 Solutions
Chemistry: A Molecular Approach, Books a la Carte Edition; Modified MasteringChemistry with Pearson eText -- ValuePack Access Card -- for Chemistry: A Molecular Approach, 4/e
Ch. 23 - Prob. 1SAQCh. 23 - Prob. 2SAQCh. 23 - Prob. 3SAQCh. 23 - Prob. 4SAQCh. 23 - Prob. 5SAQCh. 23 - Q6. What is the molecular geometry of ICl–?
a)...Ch. 23 - Prob. 7SAQCh. 23 - Prob. 8SAQCh. 23 - Prob. 9SAQCh. 23 - Prob. 10SAQ
Ch. 23 - Prob. 1ECh. 23 - 2. What is the main characteristic that determines...Ch. 23 - 3. Does the metallic characteristic of a...Ch. 23 - Prob. 4ECh. 23 - Prob. 5ECh. 23 - Prob. 6ECh. 23 - Prob. 7ECh. 23 - Prob. 8ECh. 23 - Prob. 9ECh. 23 - Prob. 10ECh. 23 - 11. What is the typical concentration of oxygen in...Ch. 23 - Prob. 12ECh. 23 - Prob. 13ECh. 23 - Prob. 14ECh. 23 - Prob. 15ECh. 23 - Prob. 16ECh. 23 - Prob. 17ECh. 23 - Prob. 18ECh. 23 - Prob. 19ECh. 23 - Prob. 20ECh. 23 - Prob. 21ECh. 23 - Prob. 22ECh. 23 - Prob. 23ECh. 23 - Prob. 24ECh. 23 - Prob. 25ECh. 23 - Prob. 26ECh. 23 - Prob. 27ECh. 23 - Prob. 28ECh. 23 - Prob. 29ECh. 23 - Prob. 30ECh. 23 - Prob. 31ECh. 23 - Prob. 32ECh. 23 - Prob. 33ECh. 23 - Prob. 34ECh. 23 - Prob. 35ECh. 23 - 36. Silicon carbide is produced by heating...Ch. 23 - Prob. 37ECh. 23 - Prob. 38ECh. 23 - Prob. 39ECh. 23 - Prob. 40ECh. 23 - Prob. 41ECh. 23 - 42. Write a balanced reaction for the gas release...Ch. 23 - Prob. 43ECh. 23 - 44. Explain why the diatomic nitrogen atom is...Ch. 23 - Prob. 45ECh. 23 - Prob. 46ECh. 23 - Prob. 47ECh. 23 - Prob. 48ECh. 23 - Prob. 49ECh. 23 - Prob. 50ECh. 23 - Prob. 51ECh. 23 - Prob. 52ECh. 23 - Prob. 53ECh. 23 - Prob. 54ECh. 23 - Prob. 55ECh. 23 - Prob. 56ECh. 23 - Prob. 57ECh. 23 - Prob. 58ECh. 23 - Prob. 59ECh. 23 - Prob. 60ECh. 23 - Prob. 61ECh. 23 - Prob. 62ECh. 23 - Prob. 63ECh. 23 - Prob. 64ECh. 23 - Prob. 65ECh. 23 - Prob. 66ECh. 23 - 67. Calculate the maximum mass (in grams) of each...Ch. 23 - 68. A coal source contains 1.1% sulfur by mass. If...Ch. 23 - Prob. 69ECh. 23 - Prob. 70ECh. 23 - Prob. 71ECh. 23 - Prob. 72ECh. 23 - Prob. 73ECh. 23 - Prob. 74ECh. 23 - Prob. 75ECh. 23 - Prob. 76ECh. 23 - Prob. 77ECh. 23 - Prob. 78ECh. 23 - Prob. 79ECh. 23 - Prob. 80ECh. 23 - Prob. 81ECh. 23 - Prob. 82ECh. 23 - Prob. 83ECh. 23 - Prob. 84ECh. 23 - Prob. 85ECh. 23 - Prob. 86ECh. 23 - Prob. 87ECh. 23 - Prob. 88ECh. 23 - Prob. 89ECh. 23 - 90. Use the data in Appendix II, Table B to...Ch. 23 - Prob. 91ECh. 23 - Prob. 92ECh. 23 - Prob. 93ECh. 23 - Prob. 94ECh. 23 - Prob. 95ECh. 23 - Prob. 96ECh. 23 - Prob. 97ECh. 23 - Prob. 98ECh. 23 - Prob. 99ECh. 23 - Prob. 100ECh. 23 - Prob. 101ECh. 23 - 102. Explain why H2S has a different bond angle...Ch. 23 - Prob. 103ECh. 23 - Prob. 104ECh. 23 - Prob. 105ECh. 23 - Prob. 106ECh. 23 - Prob. 107QGWCh. 23 - Prob. 108QGWCh. 23 - Prob. 109QGWCh. 23 - Prob. 110QGWCh. 23 - Prob. 111QGWCh. 23 - Prob. 112DIA
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