Chemistry: A Molecular Approach, Books a la Carte Edition (4th Edition)
Chemistry: A Molecular Approach, Books a la Carte Edition (4th Edition)
4th Edition
ISBN: 9780134113593
Author: Nivaldo J. Tro
Publisher: PEARSON
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Chapter 23, Problem 105E
Interpretation Introduction

To explain: The reason for SO2 to be a reducing agent, but not SO3.

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Relative Intensity Part VI. consider the multi-step reaction below for compounds A, B, and C. These compounds were subjected to mass spectrometric analysis and the following spectra for A, B, and C was obtained. Draw the structure of B and C and match all three compounds to the correct spectra. Relative Intensity Relative Intensity 100 HS-NJ-0547 80 60 31 20 S1 84 M+ absent 10 30 40 50 60 70 80 90 100 100- MS2016-05353CM 80- 60 40 20 135 137 S2 164 166 0-m 25 50 75 100 125 150 m/z 60 100 MS-NJ-09-43 40 20 20 80 45 S3 25 50 75 100 125 150 175 m/z
Part II. Given two isomers: 2-methylpentane (A) and 2,2-dimethyl butane (B) answer the following: (a) match structures of isomers given their mass spectra below (spectra A and spectra B) (b) Draw the fragments given the following prominent peaks from each spectrum: Spectra A m/2 =43 and 1/2-57 spectra B m/2 = 43 (c) why is 1/2=57 peak in spectrum A more intense compared to the same peak in spectrum B. Relative abundance Relative abundance 100 A 50 29 29 0 10 -0 -0 100 B 50 720 30 41 43 57 71 4-0 40 50 60 70 m/z 43 57 8-0 m/z = 86 M 90 100 71 m/z = 86 M -O 0 10 20 30 40 50 60 70 80 -88 m/z 90 100
Part IV. C6H5 CH2CH2OH is an aromatic compound which was subjected to Electron Ionization - mass spectrometry (El-MS) analysis. Prominent m/2 values: m/2 = 104 and m/2 = 9) was obtained. Draw the structures of these fragments.

Chapter 23 Solutions

Chemistry: A Molecular Approach, Books a la Carte Edition (4th Edition)

Ch. 23 - Prob. 1ECh. 23 - 2. What is the main characteristic that determines...Ch. 23 - 3. Does the metallic characteristic of a...Ch. 23 - Prob. 4ECh. 23 - Prob. 5ECh. 23 - Prob. 6ECh. 23 - Prob. 7ECh. 23 - Prob. 8ECh. 23 - Prob. 9ECh. 23 - Prob. 10ECh. 23 - 11. What is the typical concentration of oxygen in...Ch. 23 - Prob. 12ECh. 23 - Prob. 13ECh. 23 - Prob. 14ECh. 23 - Prob. 15ECh. 23 - Prob. 16ECh. 23 - Prob. 17ECh. 23 - Prob. 18ECh. 23 - Prob. 19ECh. 23 - Prob. 20ECh. 23 - Prob. 21ECh. 23 - Prob. 22ECh. 23 - Prob. 23ECh. 23 - Prob. 24ECh. 23 - Prob. 25ECh. 23 - Prob. 26ECh. 23 - Prob. 27ECh. 23 - Prob. 28ECh. 23 - Prob. 29ECh. 23 - Prob. 30ECh. 23 - Prob. 31ECh. 23 - Prob. 32ECh. 23 - Prob. 33ECh. 23 - Prob. 34ECh. 23 - Prob. 35ECh. 23 - 36. Silicon carbide is produced by heating...Ch. 23 - Prob. 37ECh. 23 - Prob. 38ECh. 23 - Prob. 39ECh. 23 - Prob. 40ECh. 23 - Prob. 41ECh. 23 - 42. Write a balanced reaction for the gas release...Ch. 23 - Prob. 43ECh. 23 - 44. Explain why the diatomic nitrogen atom is...Ch. 23 - Prob. 45ECh. 23 - Prob. 46ECh. 23 - Prob. 47ECh. 23 - Prob. 48ECh. 23 - Prob. 49ECh. 23 - Prob. 50ECh. 23 - Prob. 51ECh. 23 - Prob. 52ECh. 23 - Prob. 53ECh. 23 - Prob. 54ECh. 23 - Prob. 55ECh. 23 - Prob. 56ECh. 23 - Prob. 57ECh. 23 - Prob. 58ECh. 23 - Prob. 59ECh. 23 - Prob. 60ECh. 23 - Prob. 61ECh. 23 - Prob. 62ECh. 23 - Prob. 63ECh. 23 - Prob. 64ECh. 23 - Prob. 65ECh. 23 - Prob. 66ECh. 23 - 67. Calculate the maximum mass (in grams) of each...Ch. 23 - 68. A coal source contains 1.1% sulfur by mass. If...Ch. 23 - Prob. 69ECh. 23 - Prob. 70ECh. 23 - Prob. 71ECh. 23 - Prob. 72ECh. 23 - Prob. 73ECh. 23 - Prob. 74ECh. 23 - Prob. 75ECh. 23 - Prob. 76ECh. 23 - Prob. 77ECh. 23 - Prob. 78ECh. 23 - Prob. 79ECh. 23 - Prob. 80ECh. 23 - Prob. 81ECh. 23 - Prob. 82ECh. 23 - Prob. 83ECh. 23 - Prob. 84ECh. 23 - Prob. 85ECh. 23 - Prob. 86ECh. 23 - Prob. 87ECh. 23 - Prob. 88ECh. 23 - Prob. 89ECh. 23 - 90. Use the data in Appendix II, Table B to...Ch. 23 - Prob. 91ECh. 23 - Prob. 92ECh. 23 - Prob. 93ECh. 23 - Prob. 94ECh. 23 - Prob. 95ECh. 23 - Prob. 96ECh. 23 - Prob. 97ECh. 23 - Prob. 98ECh. 23 - Prob. 99ECh. 23 - Prob. 100ECh. 23 - Prob. 101ECh. 23 - 102. Explain why H2S has a different bond angle...Ch. 23 - Prob. 103ECh. 23 - Prob. 104ECh. 23 - Prob. 105ECh. 23 - Prob. 106ECh. 23 - Prob. 107QGWCh. 23 - Prob. 108QGWCh. 23 - Prob. 109QGWCh. 23 - Prob. 110QGWCh. 23 - Prob. 111QGWCh. 23 - Prob. 112DIA
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