![Organic Chemistry, Third Edition Binder Ready Version](https://www.bartleby.com/isbn_cover_images/9781119110453/9781119110453_largeCoverImage.gif)
(a)
Interpretation:
For a given set of nitrogen containing compounds, the structures have to be drawn using their general or IUPAC names.
Concept Introduction: If,
and
groups are attached to the parent carbon, they are called primary, secondary and tertiary
There are two ways followed to name the compound. First one is the method of giving general name in which name of the alkyl group followed by amine name is given. Second one is the method giving IUPAC name in which name of the alkane group followed by amine name is given.
The length of the chain which is having more number of carbon atoms is selected as the parent or main chain. Other chains are considered as substituents to the main chain. Position of the substituents should be included in the name. If one, two, three, four, five, six, etc carbons are activating as the main chain in IUPAC system, then the name of the compound comes as methane, ethane, propane, butane, pentane, hexane, etc. which are the name of
If any configuration is present in the compound, that should be assigned to it while writing the name. If the compound contains heavier groups on the same side, it gets (Z)-configuration. If they are on the opposite directions, (E)-configurations result.
If a carbon has four different groups attached to it, that carbon shows a chirality nature. If that chiral carbon rotates the plane polarized light into a clockwise direction, it gets (R)-isomer. If that carbon rotates the plane polarized light into a counter-clockwise direction, it gets (S)-isomer.
(b)
Interpretation: For a given set of nitrogen containing compounds, the structures have to be drawn using their general or IUPAC names.
Concept Introduction: If,
and
groups are attached to the parent carbon, they are called primary, secondary and tertiary amines respectively.
There are two ways followed to name the compound. First one is the method of giving general name in which name of the alkyl group followed by amine name is given. Second one is the method giving IUPAC name in which name of the alkane group followed by amine name is given.
The length of the chain which is having more number of carbon atoms is selected as the parent or main chain. Other chains are considered as substituents to the main chain. Position of the substituents should be included in the name. If one, two, three, four, five, six, etc carbons are activating as the main chain in IUPAC system, then the name of the compound comes as methane, ethane, propane, butane, pentane, hexane, etc. which are the name of alkanes. If one, two, three, four, five, six, etc carbons are activating as the main chain in general name method, then the name of the compound comes as methyl, ethyl, propyl, butyl, pentyl, hexyl, etc. which are the name of alkyl groups. If substituent groups are attached to nitrogen atom as in the case of tertiary or secondary amines, the name is given as N-alkyl name of the substituent.
If any configuration is present in the compound, that should be assigned to it while writing the name. If the compound contains heavier groups on the same side, it gets (Z)-configuration. If they are on the opposite directions, (E)-configurations result.
If a carbon has four different groups attached to it, that carbon shows a chirality nature. If that chiral carbon rotates the plane polarized light into a clockwise direction, it gets (R)-isomer. If that carbon rotates the plane polarized light into a counter-clockwise direction, it gets (S)-isomer.
(c)
Interpretation: For a given set of nitrogen containing compounds, the structures have to be drawn using their general or IUPAC names.
Concept Introduction: If,
and
groups are attached to the parent carbon, they are called primary, secondary and tertiary amines respectively.
There are two ways followed to name the compound. First one is the method of giving general name in which name of the alkyl group followed by amine name is given. Second one is the method giving IUPAC name in which name of the alkane group followed by amine name is given.
The length of the chain which is having more number of carbon atoms is selected as the parent or main chain. Other chains are considered as substituents to the main chain. Position of the substituents should be included in the name. If one, two, three, four, five, six, etc carbons are activating as the main chain in IUPAC system, then the name of the compound comes as methane, ethane, propane, butane, pentane, hexane, etc. which are the name of alkanes. If one, two, three, four, five, six, etc carbons are activating as the main chain in general name method, then the name of the compound comes as methyl, ethyl, propyl, butyl, pentyl, hexyl, etc. which are the name of alkyl groups. If substituent groups are attached to nitrogen atom as in the case of tertiary or secondary amines, the name is given as N-alkyl name of the substituent.
If any configuration is present in the compound, that should be assigned to it while writing the name. If the compound contains heavier groups on the same side, it gets (Z)-configuration. If they are on the opposite directions, (E)-configurations result.
If a carbon has four different groups attached to it, that carbon shows a chirality nature. If that chiral carbon rotates the plane polarized light into a clockwise direction, it gets (R)-isomer. If that carbon rotates the plane polarized light into a counter-clockwise direction, it gets (S)-isomer.
(d)
Interpretation: For a given set of nitrogen containing compounds, the structures have to be drawn using their general or IUPAC names.
Concept Introduction: If,
and
groups are attached to the parent carbon, they are called primary, secondary and tertiary amines respectively.
There are two ways followed to name the compound. First one is the method of giving general name in which name of the alkyl group followed by amine name is given. Second one is the method giving IUPAC name in which name of the alkane group followed by amine name is given.
The length of the chain which is having more number of carbon atoms is selected as the parent or main chain. Other chains are considered as substituents to the main chain. Position of the substituents should be included in the name. If one, two, three, four, five, six, etc carbons are activating as the main chain in IUPAC system, then the name of the compound comes as methane, ethane, propane, butane, pentane, hexane, etc. which are the name of alkanes. If one, two, three, four, five, six, etc carbons are activating as the main chain in general name method, then the name of the compound comes as methyl, ethyl, propyl, butyl, pentyl, hexyl, etc. which are the name of alkyl groups. If substituent groups are attached to nitrogen atom as in the case of tertiary or secondary amines, the name is given as N-alkyl name of the substituent.
If any configuration is present in the compound, that should be assigned to it while writing the name. If the compound contains heavier groups on the same side, it gets (Z)-configuration. If they are on the opposite directions, (E)-configurations result.
If a carbon has four different groups attached to it, that carbon shows a chirality nature. If that chiral carbon rotates the plane polarized light into a clockwise direction, it gets (R)-isomer. If that carbon rotates the plane polarized light into a counter-clockwise direction, it gets (S)-isomer.
(e)
Interpretation: For a given set of nitrogen containing compounds, the structures have to be drawn using their general or IUPAC names.
Concept Introduction: If,
and
groups are attached to the parent carbon, they are called primary, secondary and tertiary amines respectively.
There are two ways followed to name the compound. First one is the method of giving general name in which name of the alkyl group followed by amine name is given. Second one is the method giving IUPAC name in which name of the alkane group followed by amine name is given.
The length of the chain which is having more number of carbon atoms is selected as the parent or main chain. Other chains are considered as substituents to the main chain. Position of the substituents should be included in the name. If one, two, three, four, five, six, etc carbons are activating as the main chain in IUPAC system, then the name of the compound comes as methane, ethane, propane, butane, pentane, hexane, etc. which are the name of alkanes. If one, two, three, four, five, six, etc carbons are activating as the main chain in general name method, then the name of the compound comes as methyl, ethyl, propyl, butyl, pentyl, hexyl, etc. which are the name of alkyl groups. If substituent groups are attached to nitrogen atom as in the case of tertiary or secondary amines, the name is given as N-alkyl name of the substituent.
If any configuration is present in the compound, that should be assigned to it while writing the name. If the compound contains heavier groups on the same side, it gets (Z)-configuration. If they are on the opposite directions, (E)-configurations result.
If a carbon has four different groups attached to it, that carbon shows a chirality nature. If that chiral carbon rotates the plane polarized light into a clockwise direction, it gets (R)-isomer. If that carbon rotates the plane polarized light into a counter-clockwise direction, it gets (S)-isomer.
![Check Mark](/static/check-mark.png)
Want to see the full answer?
Check out a sample textbook solution![Blurred answer](/static/blurred-answer.jpg)
Chapter 22 Solutions
Organic Chemistry, Third Edition Binder Ready Version
- REPORT FOR EXPERIMENT 9 (continued) NAME F. Solubility vs. Temperature; Saturated and Unsaturated Solutions Data Table: Circle the choices which best describe your observations. NaCl 1.0 g +5 mL water 1.0 g +5 mL water +1.4 g dissolved completely? yes/no saturated or unsaturated? dissolved completely? yes/no saturated or unsaturated? 2.4 g +5 mL water +heat dissolved completely? yes/no saturated or unsaturated? 2.4 g +5 mL water after cooling dissolved completely? yes/no saturated or unsaturated? NHC dissolved completely? yes/no saturated or unsaturated? dissolved completely? yes/no saturated or unsaturated? dissolved completely? yes/no saturated or unsaturated? dissolved completely? yes/no saturated or unsaturated? G. Ionic Reactions in Solution 1. Write the word and formula equations representing the chemical reaction that occurred between the barium chloride solution, BaCl,(aq), and the sodium sulfate solution, Na SO (aq). Word Equation: Formula Equation: 2. (a) Which of the…arrow_forwardIn the drawing areas below, draw the two most expected stable conformations of the following molecule: ייון Be sure your drawings make it possible to distinguish between the conformations. After you've drawn the conformations, answer the question below the drawing areas. Х S : ☐ ☑ 5arrow_forwardDraw the structure of the organic reactant, and write the chemical formula of the reagent used to form the given product. Click and drag to start drawing a structure. + T ☑ OH NO₂ NO2arrow_forward
- Please correct answer and don't use hand ratingarrow_forwardSafari File Edit View History Bookmarks Window Help く < mylabmastering.pearson.com Wed Feb 12 8:44 PM ✩ + Apple Q Bing Google SignOutOptions M Question 36 - Lab HW BI... P Pearson MyLab and Mast... P Course Home Error | bartleby b Answered: If the biosynth... Draw a free-radical mechanism for the following reaction, forming the major monobromination product: ScreenPal - 2022 CHEM2... Access Pearson 2 CH3 Br-Br CH H3 Draw all missing reactants and/or products in the appropriate boxes by placing atoms on the canvas and connecting them with bonds. Add charges where needed. Electron- flow arrows should start on the electron(s) of an atom or a bond and should end on an atom, bond, or location where a new bond should be created. Include all free radicals by right-clicking on an atom on the canvas and then using the Atom properties to select the monovalent radical. ▸ View Available Hint(s) 0 2 DE [1] H EXP. CONT. H. Br-Br H FEB 12arrow_forwardPlease correct answer and don't use hand ratingarrow_forwardNonearrow_forwardQ1: For each molecule, assign each stereocenter as R or S. Circle the meso compounds. Label each compound as chiral or achiral. + CI Br : Н OH H wo་ཡིག་ཐrow HO 3 D ။။ဂ CI Br H, CI Br Br H₂N OMe R IN I I N S H Br ជ័យ CI CI D OHarrow_forwardPlease correct answer and don't use hand ratingarrow_forwardarrow_back_iosSEE MORE QUESTIONSarrow_forward_ios
- ChemistryChemistryISBN:9781305957404Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCostePublisher:Cengage LearningChemistryChemistryISBN:9781259911156Author:Raymond Chang Dr., Jason Overby ProfessorPublisher:McGraw-Hill EducationPrinciples of Instrumental AnalysisChemistryISBN:9781305577213Author:Douglas A. Skoog, F. James Holler, Stanley R. CrouchPublisher:Cengage Learning
- Organic ChemistryChemistryISBN:9780078021558Author:Janice Gorzynski Smith Dr.Publisher:McGraw-Hill EducationChemistry: Principles and ReactionsChemistryISBN:9781305079373Author:William L. Masterton, Cecile N. HurleyPublisher:Cengage LearningElementary Principles of Chemical Processes, Bind...ChemistryISBN:9781118431221Author:Richard M. Felder, Ronald W. Rousseau, Lisa G. BullardPublisher:WILEY
![Text book image](https://www.bartleby.com/isbn_cover_images/9781305957404/9781305957404_smallCoverImage.gif)
![Text book image](https://www.bartleby.com/isbn_cover_images/9781259911156/9781259911156_smallCoverImage.gif)
![Text book image](https://www.bartleby.com/isbn_cover_images/9781305577213/9781305577213_smallCoverImage.gif)
![Text book image](https://www.bartleby.com/isbn_cover_images/9780078021558/9780078021558_smallCoverImage.gif)
![Text book image](https://www.bartleby.com/isbn_cover_images/9781305079373/9781305079373_smallCoverImage.gif)
![Text book image](https://www.bartleby.com/isbn_cover_images/9781118431221/9781118431221_smallCoverImage.gif)