Study Guide/solutions Manual For Organic Chemistry
Study Guide/solutions Manual For Organic Chemistry
6th Edition
ISBN: 9781260475678
Author: Janice Gorzynski Smith Dr.
Publisher: McGraw-Hill Education
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Chapter 22, Problem 56P
Interpretation Introduction

Interpretation: The stepwise mechanism for the given reaction is to be drawn.

Concept introduction: The Aldol condensation reaction that takes place within the same molecule in presence of strong base is known as intramolecular aldol reactions. This reaction takes place within the dicarbonyl compounds in which one carbonyl group forms the enolate that acts as a nucleophile and reacts with second carbonyl group which acts as electrophile.

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16. The proton NMR spectral information shown in this problem is for a compound with formula CioH,N. Expansions are shown for the region from 8.7 to 7.0 ppm. The normal carbon-13 spec- tral results, including DEPT-135 and DEPT-90 results, are tabulated: 7 J Normal Carbon DEPT-135 DEPT-90 19 ppm Positive No peak 122 Positive Positive cus и 124 Positive Positive 126 Positive Positive 128 No peak No peak 4° 129 Positive Positive 130 Positive Positive (144 No peak No peak 148 No peak No peak 150 Positive Positive してし
3. Propose a synthesis for the following transformation. Do not draw an arrow-pushing mechanism below, but make sure to draw the product of each proposed step (3 points). + En CN CN
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Chapter 22 Solutions

Study Guide/solutions Manual For Organic Chemistry

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