Chemistry: A Molecular Approach Selected Solutions Manual, Books a la Carte Edition
4th Edition
ISBN: 9780134554259
Author: Nivaldo J. Tro
Publisher: PEARSON
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Chapter 22, Problem 56E
Interpretation Introduction
Interpretation: The reaction by which valance and asparagine from a peptide bond.
Concept Introduction:
Amino acids link together through the reaction of the
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Draw the product of the E2 reaction shown below. Include the correct
stereochemistry. Ignore any inorganic byproducts.
+
Br
CH3
Q
Strong Base
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and Rings
Charges
Undo
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H
"Br
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Br.
Remove
Done
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Drag To Pan
Curved arrows are used to illustrate the flow of electrons. Use the reaction conditions
provided and follow the curved arrows to draw the product of this elementary step in an
elimination mechanism.
Include all lone pairs and charges as appropriate. Ignore stereochemistry. Ignore
byproducts.
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Br:
..
8
0.01 M NaOH
heat
Drawing
Q
Atoms, Bonds
and Rings
Charges and
Lone Pairs
Draw or tap a new bond to see suggestions.
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Done
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Draw the product of the E2 reaction shown below. Include the correct
stereochemistry. Ignore any inorganic byproducts.
Ph
CH2CH3
H
H3C
H
Br
DBN
[૪]
Drawing
Atoms, Bonds
and Rings
H
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OH
Charges
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Br
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Done
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+
Chapter 22 Solutions
Chemistry: A Molecular Approach Selected Solutions Manual, Books a la Carte Edition
Ch. 22 - Prob. 1SAQCh. 22 - Prob. 2SAQCh. 22 - Prob. 3SAQCh. 22 - Prob. 4SAQCh. 22 - Prob. 5SAQCh. 22 - Prob. 6SAQCh. 22 - Prob. 7SAQCh. 22 - Prob. 8SAQCh. 22 - Q9. Peptide bonds occur in which type of...Ch. 22 - Q10. How many nucleotides are required to code for...
Ch. 22 - 1. What is biochemistry? What significant advances...Ch. 22 - Prob. 2ECh. 22 - Prob. 3ECh. 22 - 4. What effect do double bonds have within the...Ch. 22 - Prob. 5ECh. 22 - Prob. 6ECh. 22 - 7. Describe the basic structure of phospholipids...Ch. 22 - 8. What is a steroid? List some functions of...Ch. 22 - Prob. 9ECh. 22 - Prob. 10ECh. 22 - Prob. 11ECh. 22 - Prob. 12ECh. 22 - Prob. 13ECh. 22 - Prob. 14ECh. 22 - Prob. 15ECh. 22 - Prob. 16ECh. 22 - Prob. 17ECh. 22 - Prob. 18ECh. 22 - Prob. 19ECh. 22 - Prob. 20ECh. 22 - Prob. 21ECh. 22 - Prob. 22ECh. 22 - Prob. 23ECh. 22 - Prob. 24ECh. 22 - Prob. 25ECh. 22 - Prob. 26ECh. 22 - 27. What is a codon? A gene? A chromosome?
Ch. 22 - Prob. 28ECh. 22 - Prob. 29ECh. 22 - Prob. 30ECh. 22 - Prob. 31ECh. 22 - Prob. 32ECh. 22 - Prob. 33ECh. 22 - Prob. 34ECh. 22 - 35. Draw structures showing the reaction of...Ch. 22 - Prob. 36ECh. 22 - Prob. 37ECh. 22 - Prob. 38ECh. 22 - Prob. 39ECh. 22 - Prob. 40ECh. 22 - Prob. 41ECh. 22 - Prob. 42ECh. 22 - Prob. 43ECh. 22 - Prob. 44ECh. 22 - Prob. 45ECh. 22 - Prob. 46ECh. 22 - Prob. 47ECh. 22 - Prob. 48ECh. 22 - 49. Draw each amino acid in its dipolar ion...Ch. 22 - 50. Draw each amino acid in its dipolar ion...Ch. 22 - Prob. 51ECh. 22 - Prob. 52ECh. 22 - Prob. 53ECh. 22 - Prob. 54ECh. 22 - Prob. 55ECh. 22 - Prob. 56ECh. 22 - Prob. 57ECh. 22 - Prob. 58ECh. 22 - 59. A phenylalanine amino acid on a protein strand...Ch. 22 - 60. An amino acid on a protein strand forms a...Ch. 22 -
61. The amino acid sequence in one section of a...Ch. 22 - Prob. 62ECh. 22 - Prob. 63ECh. 22 - Prob. 64ECh. 22 - Prob. 65ECh. 22 - Prob. 66ECh. 22 - Prob. 67ECh. 22 - Prob. 68ECh. 22 - Prob. 69ECh. 22 - Prob. 70ECh. 22 - 71. Determine the class of biochemical compound...Ch. 22 - Prob. 72ECh. 22 - 73. What is the difference between a codon and a...Ch. 22 - 74. What is the difference between a fatty acid...Ch. 22 - Prob. 75ECh. 22 - Prob. 76ECh. 22 - Prob. 77ECh. 22 - Prob. 78ECh. 22 - 79. Determining the amino acid sequence in a...Ch. 22 - Prob. 80ECh. 22 - Prob. 81ECh. 22 - 82. Calculate the mass percent of phosphorus in a...Ch. 22 - 83. The double helical structure of DNA disrupts...Ch. 22 - Prob. 84ECh. 22 - Prob. 85ECh. 22 - Prob. 86ECh. 22 - Prob. 87ECh. 22 - Prob. 88ECh. 22 - 89. Write the major equilibrium that is...Ch. 22 - Prob. 90ECh. 22 - Prob. 91ECh. 22 - 92. The genetic code is random, which means that a...Ch. 22 - Prob. 93QGWCh. 22 - Prob. 94QGWCh. 22 - Prob. 95QGWCh. 22 - Prob. 96QGWCh. 22 - Prob. 97QGWCh. 22 - Prob. 98DIA
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- Reaction A Now the production A ΠIn the product of reaction i 12 Dear the product of actionarrow_forwardMacmillan Learnin When an unknown amine reacts with an unknown acid chloride, an amide with a molecular mass of 163 g/mol (M* = 163 m/z) is formed. In the infrared spectrum, important absorptions appear at 1661, 750 and 690 cm-1. The 13C NMR and DEPT spectra are provided. Draw the structure of the product as the resonance contributor lacking any formal charges. 13C NMR DEPT 90 200 160 120 80 40 0 200 160 120 80 DEPT 135 200 160 120 80 40 0 Draw the unknown amide. 40 40 0arrow_forwardDraw the major product karmed when I reach with the epoxide. Use walge dah bonds, including hydrogen al alcach genic center, to show the chemistry of the product Beeldraw any hydrogen akams on coxygen where applicablearrow_forward
- Curved arrows are used to illustrate the flow of electrons. Using the provided starting and product structures, draw the curved electron-pushing arrows for the following reaction or mechanistic step(s). Be sure to account for all bond-breaking and bond-making steps. H I Select to Add Arrows + H H 'H Q H2O H2O CI:O .H H H H I Select to Add Arrows I : C H2O H H H Select to Add Arrows 'Harrow_forward+ Draw an alkyl halide that produces ONLY the following alkene in an E2 elimination. Ignore any inorganic byproducts. Drawing Strong Base Q Atoms, Bonds and Rings Charges HO Br H2N Undo Reset Remove Done Drag To Panarrow_forwardFor the dehydrohalogenation (E2) reaction shown, draw the major organic product. Хок Br tert-butanol heat Select Drew Templates More Erase CH QQQarrow_forward
- Macmillan Learning Draw the major, neutral organic product for each substitution reaction. For this question, assume that each substitution reaction goes to completion. Disregard elimination. Reaction A. CI H₂O Select Draw Templates More Erase C Harrow_forwardMacmillan Learning Reaction B: CI HO_ 곳으 / Select Draw Templates More с € H D Erasearrow_forwardWhen 2-bromo-93-dimethylbutane is heated with sodium methoxide, one majors.. në la formed. 4th attempt Part 1 (0.5 point) t Ji See Periodic Table See Hint Draw the major alkene product and all other byproducts. Be sure to include lone-pair electrons and charges. Part 2 (0.5 point) What type of mechanism is occuring? Choose one: AS1 3rd attempt X H 41 See Hint Part 1 (0.5 point) Feedback See Periodic Table See Hintarrow_forward
- Complete the mechanism for the E1 reaction below by following the directions written above each of the five boxes. Be sure to include lone pair electrons and nonzero formal charges. 2nd attempt 1 Provide the missing curved arrow notation. E+ RUDDA 1st attempt Feedback See Periodic Table See Hint Iir See Periodic Table See Hintarrow_forwardHeating an alcohol in the presence of sulfuric or phosphoric acid will cause a dehydration to occur: the removal of the elements of water from a molecule, forming an alkene. The reaction usually follows an E1 mechanism. The SN1 pathway is suppressed by using a strong acid whose conjugate base is a poor nucleophile. Further, heating the reaction mixture causes a greater increase in the rate of E1 compared to the rate of Sy1. 3rd attempt h Draw curved arrow(s) to show how the alcohol reacts with phosphoric acid. TH © 1 0 0 +1% # 2nd attempt Feedback H Ju See Periodic Table See Hint H Jud See Periodic Table See Hintarrow_forwardPart 2 (0.5 point) 0- Draw the major organic product with the correct geometry. 10 1: 70000 х く 1st attempt Part 1 (0.5 point) Feedback Please draw all four bonds at chiral centers. P See Periodic Table See Hintarrow_forward
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