Mastering Chemistry with Pearson eText -- Standalone Access Card -- for Chemistry: A Molecular Approach (4th Edition)
4th Edition
ISBN: 9780134162485
Author: Nivaldo J. Tro
Publisher: PEARSON
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Chapter 22, Problem 46E
Interpretation Introduction
Interpretation: The hydrolysis of the following carbohydrate. By drawing the following products.
Concept Introduction:
Three monosaccharaides can link together via a glycosidic linkage to form a trisaccharide—a carbohydrate that can be decomposed into three simple sugars. Water is a participant in the process, adding –H and –OH groups to either side of the glycosidic bond.
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(a
4 shows scanning electron microscope (SEM) images of extruded
actions of packing bed for two capillary columns of different diameters,
al 750 (bottom image) and b) 30-μm-i.d. Both columns are packed with the
same stationary phase, spherical particles with 1-um diameter.
A) When the columns were prepared, the figure shows that the column with
the larger diameter has more packing irregularities. Explain this observation.
B) Predict what affect this should have on band broadening and discuss your
prediction using the van Deemter terms.
C) Does this figure support your explanations in application question 33?
Explain why or why not and make any changes in your answers in light of
this figure.
Figure 4 SEM images of
sections of packed columns
for a) 750 and b) 30-um-i.d.
capillary columns.³
fcrip
= ↓ bandwidth Il temp
32. What impact (increase, decrease, or no change) does each of the following conditions have on the individual
components of the van Deemter equation and consequently, band broadening?
Increase temperature
Longer column
Using a gas mobile phase
instead of liquid
Smaller particle stationary phase
Multiple Paths
Diffusion
Mass Transfer
34. Figure 3 shows Van Deemter plots for a solute molecule using different column inner diameters (i.d.).
A) Predict whether decreasing the column inner diameters increase or decrease bandwidth.
B) Predict which van Deemter equation coefficient (A, B, or C) has the greatest effect on increasing or
decreasing bandwidth as a function of i.d. and justify your answer.
Figure 3 Van Deemter plots for hydroquinone using different column inner diameters (i.d. in μm). The data was
obtained from liquid chromatography experiments using fused-silica capillary columns packed with 1.0-μm particles.
35
20
H(um)
큰 20
15
90
0+
1500
100
75
550
01
02
594
05
μ(cm/sec)
30
15
10
Chapter 22 Solutions
Mastering Chemistry with Pearson eText -- Standalone Access Card -- for Chemistry: A Molecular Approach (4th Edition)
Ch. 22 - Prob. 1SAQCh. 22 - Prob. 2SAQCh. 22 - Prob. 3SAQCh. 22 - Prob. 4SAQCh. 22 - Prob. 5SAQCh. 22 - Prob. 6SAQCh. 22 - Prob. 7SAQCh. 22 - Prob. 8SAQCh. 22 - Q9. Peptide bonds occur in which type of...Ch. 22 - Q10. How many nucleotides are required to code for...
Ch. 22 - 1. What is biochemistry? What significant advances...Ch. 22 - Prob. 2ECh. 22 - Prob. 3ECh. 22 - 4. What effect do double bonds have within the...Ch. 22 - Prob. 5ECh. 22 - Prob. 6ECh. 22 - 7. Describe the basic structure of phospholipids...Ch. 22 - 8. What is a steroid? List some functions of...Ch. 22 - Prob. 9ECh. 22 - Prob. 10ECh. 22 - Prob. 11ECh. 22 - Prob. 12ECh. 22 - Prob. 13ECh. 22 - Prob. 14ECh. 22 - Prob. 15ECh. 22 - Prob. 16ECh. 22 - Prob. 17ECh. 22 - Prob. 18ECh. 22 - Prob. 19ECh. 22 - Prob. 20ECh. 22 - Prob. 21ECh. 22 - Prob. 22ECh. 22 - Prob. 23ECh. 22 - Prob. 24ECh. 22 - Prob. 25ECh. 22 - Prob. 26ECh. 22 - 27. What is a codon? A gene? A chromosome?
Ch. 22 - Prob. 28ECh. 22 - Prob. 29ECh. 22 - Prob. 30ECh. 22 - Prob. 31ECh. 22 - Prob. 32ECh. 22 - Prob. 33ECh. 22 - Prob. 34ECh. 22 - 35. Draw structures showing the reaction of...Ch. 22 - Prob. 36ECh. 22 - Prob. 37ECh. 22 - Prob. 38ECh. 22 - Prob. 39ECh. 22 - Prob. 40ECh. 22 - Prob. 41ECh. 22 - Prob. 42ECh. 22 - Prob. 43ECh. 22 - Prob. 44ECh. 22 - Prob. 45ECh. 22 - Prob. 46ECh. 22 - Prob. 47ECh. 22 - Prob. 48ECh. 22 - 49. Draw each amino acid in its dipolar ion...Ch. 22 - 50. Draw each amino acid in its dipolar ion...Ch. 22 - Prob. 51ECh. 22 - Prob. 52ECh. 22 - Prob. 53ECh. 22 - Prob. 54ECh. 22 - Prob. 55ECh. 22 - Prob. 56ECh. 22 - Prob. 57ECh. 22 - Prob. 58ECh. 22 - 59. A phenylalanine amino acid on a protein strand...Ch. 22 - 60. An amino acid on a protein strand forms a...Ch. 22 -
61. The amino acid sequence in one section of a...Ch. 22 - Prob. 62ECh. 22 - Prob. 63ECh. 22 - Prob. 64ECh. 22 - Prob. 65ECh. 22 - Prob. 66ECh. 22 - Prob. 67ECh. 22 - Prob. 68ECh. 22 - Prob. 69ECh. 22 - Prob. 70ECh. 22 - 71. Determine the class of biochemical compound...Ch. 22 - Prob. 72ECh. 22 - 73. What is the difference between a codon and a...Ch. 22 - 74. What is the difference between a fatty acid...Ch. 22 - Prob. 75ECh. 22 - Prob. 76ECh. 22 - Prob. 77ECh. 22 - Prob. 78ECh. 22 - 79. Determining the amino acid sequence in a...Ch. 22 - Prob. 80ECh. 22 - Prob. 81ECh. 22 - 82. Calculate the mass percent of phosphorus in a...Ch. 22 - 83. The double helical structure of DNA disrupts...Ch. 22 - Prob. 84ECh. 22 - Prob. 85ECh. 22 - Prob. 86ECh. 22 - Prob. 87ECh. 22 - Prob. 88ECh. 22 - 89. Write the major equilibrium that is...Ch. 22 - Prob. 90ECh. 22 - Prob. 91ECh. 22 - 92. The genetic code is random, which means that a...Ch. 22 - Prob. 93QGWCh. 22 - Prob. 94QGWCh. 22 - Prob. 95QGWCh. 22 - Prob. 96QGWCh. 22 - Prob. 97QGWCh. 22 - Prob. 98DIA
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