MODIFIED MAST ASTRONOMY:COSMIC PERSPECTI
MODIFIED MAST ASTRONOMY:COSMIC PERSPECTI
9th Edition
ISBN: 9780136904496
Author: Bennett
Publisher: PEARSON
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Chapter 22, Problem 45EAP
To determine

To Discuss:The reasonable scientific understanding of what the universe was like when it was 1 minute old

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Pure membranes of dipalmitoyl lecithin phospholipids are models of biological membranes. They melt = 41°C. Reversible melting experiments indicate that at Tm AHm=37.7 kJ mol-1. Calculate: A. The entropy of melting, ASm- B. The Gibbs free energy of melting, AGm- C. Does the membrane become more or less ordered upon melting? D. There are 32 rotatable CH2 CH2 bonds in each molecule that can rotate more freely if the membrane melts. What is the increase in multiplicity on melting a mole of bonds?
5. Heat capacity often has a temperature dependence for real molecules, particularly if you go over a large temperature range. The heat capacity for liquid n-butane can be fit to the equation Cp(T) = a + bT where a = 100 J K₁₁ mol¹ and b = 0.1067 J K² mol¹ from its freezing point (T = 140 K) to its boiling point (T₁ = 270 K). A. Compute AH for heating butane from 170 K to 270 K. B. Compute AS for the same temperature range.
4. How much energy must be transferred as heat to cause the quasi-static isothermal expansion of one mole of an ideal gas at 300 K from PA = 1 bar to PB = 0.5 bar? A. What is VA? B. What is VB? C. What is AU for the process? D. What is AH for the process? E. What is AS for the process?

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MODIFIED MAST ASTRONOMY:COSMIC PERSPECTI

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