ORGANIC CHEMISTRY
ORGANIC CHEMISTRY
6th Edition
ISBN: 9781266633973
Author: SMITH
Publisher: MCG
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Chapter 22, Problem 38P
Interpretation Introduction

Interpretation: The reason corresponding to the given statement that the ketone K undergoes aldol reactions but the ketone J does not is to be stated.

Concept Introduction: Aldol reaction is the condensation reaction of the organic chemistry. In this reaction an enolate ion or an enol reacts with the carbonyl compound that leads to the formation of β-hydroxyaldehyde or β-hydroxyketone which on further dehydration gives the conjugated enone.

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Explain why ketone K undergoes aldol reactions but ketone J does not.
Show how to prepare   a,b-unsaturated ketone by an aldol reaction followed by dehydration of the aldol product.
Why is it not advisable to use aqueous hydrochloric acid in a Grignard reaction of a ketone? A) The Grignard reagent will react with the acid and cannot react with the ketone. B) The ketone will be protonated and will become unreactive. C) The ketone will form an unreactive enol. D) The Grignard reagent won't dissolve in aqueous solutions

Chapter 22 Solutions

ORGANIC CHEMISTRY

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