General Chemistry: Principles and Modern Applications (11th Edition)
General Chemistry: Principles and Modern Applications (11th Edition)
11th Edition
ISBN: 9780132931281
Author: Ralph H. Petrucci, F. Geoffrey Herring, Jeffry D. Madura, Carey Bissonnette
Publisher: PEARSON
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Chapter 22, Problem 22E
Interpretation Introduction

Interpretation:

To identify the species which has a linear structure ClF2+, IBr,OCl2,and SF4 and the species has same structure.

Concept introduction:

In linear shapes molecules, electron pair force bonds to be 180° from each other and in the bent shape two pairs of unshared electrons push the two bonds down.

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(a 4 shows scanning electron microscope (SEM) images of extruded actions of packing bed for two capillary columns of different diameters, al 750 (bottom image) and b) 30-μm-i.d. Both columns are packed with the same stationary phase, spherical particles with 1-um diameter. A) When the columns were prepared, the figure shows that the column with the larger diameter has more packing irregularities. Explain this observation. B) Predict what affect this should have on band broadening and discuss your prediction using the van Deemter terms. C) Does this figure support your explanations in application question 33? Explain why or why not and make any changes in your answers in light of this figure. Figure 4 SEM images of sections of packed columns for a) 750 and b) 30-um-i.d. capillary columns.³
fcrip = ↓ bandwidth Il temp 32. What impact (increase, decrease, or no change) does each of the following conditions have on the individual components of the van Deemter equation and consequently, band broadening? Increase temperature Longer column Using a gas mobile phase instead of liquid Smaller particle stationary phase Multiple Paths Diffusion Mass Transfer
34. Figure 3 shows Van Deemter plots for a solute molecule using different column inner diameters (i.d.). A) Predict whether decreasing the column inner diameters increase or decrease bandwidth. B) Predict which van Deemter equation coefficient (A, B, or C) has the greatest effect on increasing or decreasing bandwidth as a function of i.d. and justify your answer. Figure 3 Van Deemter plots for hydroquinone using different column inner diameters (i.d. in μm). The data was obtained from liquid chromatography experiments using fused-silica capillary columns packed with 1.0-μm particles. 35 20 H(um) 큰 20 15 90 0+ 1500 100 75 550 01 02 594 05 μ(cm/sec) 30 15 10

Chapter 22 Solutions

General Chemistry: Principles and Modern Applications (11th Edition)

Ch. 22 - Prob. 11ECh. 22 - Prob. 12ECh. 22 - Prob. 13ECh. 22 - Prob. 14ECh. 22 - Make a general prediction about which of the...Ch. 22 - The following properties of astatine have been...Ch. 22 - Prob. 17ECh. 22 - Prob. 18ECh. 22 - Prob. 19ECh. 22 - Prob. 20ECh. 22 - Prob. 21ECh. 22 - Prob. 22ECh. 22 - Prob. 23ECh. 22 - Prob. 24ECh. 22 - Each of the following compounds decomposes to...Ch. 22 - Ozone is a power oxidizing agent. Using ozone as...Ch. 22 - Prob. 27ECh. 22 - Prob. 28ECh. 22 - Prob. 29ECh. 22 - Prob. 30ECh. 22 - Prob. 31ECh. 22 - Prob. 32ECh. 22 - Prob. 33ECh. 22 - In water, O2(aq) is a strong base. If 100.0 mg of...Ch. 22 - The conversion of O2(g) to O2(g) can be...Ch. 22 - Prob. 36ECh. 22 - Prob. 37ECh. 22 - Prob. 38ECh. 22 - Prob. 39ECh. 22 - Prob. 40ECh. 22 - Prob. 41ECh. 22 - Joseph Priestley, e British chemist, was credited...Ch. 22 - Give an appropriate name to each of theb following...Ch. 22 - Prob. 44ECh. 22 - Give a specific example of a chemical equation...Ch. 22 - Prob. 46ECh. 22 - Prob. 47ECh. 22 - Prob. 48ECh. 22 - Prob. 49ECh. 22 - Prob. 50ECh. 22 - Prob. 51ECh. 22 - Prob. 52ECh. 22 - Prob. 53ECh. 22 - Prob. 54ECh. 22 - Prob. 55ECh. 22 - Prob. 56ECh. 22 - Prob. 57ECh. 22 - Prob. 58ECh. 22 - Prob. 59ECh. 22 - One reaction that competes with reaction (22.41),...Ch. 22 - Prob. 61ECh. 22 - Prob. 62ECh. 22 - Draw plausible Lewis structures for a....Ch. 22 - Both nitramide and hyponitrous acid have the...Ch. 22 - Prob. 65ECh. 22 - Prob. 66ECh. 22 - Prob. 67ECh. 22 - Prob. 68ECh. 22 - Prob. 69ECh. 22 - Prob. 70ECh. 22 - Use data from Table 7.2 (page 273) to calculate...Ch. 22 - Prob. 72ECh. 22 - Prob. 73ECh. 22 - Prob. 74ECh. 22 - Prob. 75ECh. 22 - What volume of H2(g) at 25C and 752 mmHg is...Ch. 22 - Prob. 77ECh. 22 - How many grams of CaH2(s) are required to generate...Ch. 22 - Prob. 79ECh. 22 - On the basis of molecular orbital theory, would...Ch. 22 - Prob. 81IAECh. 22 - Prob. 82IAECh. 22 - Prob. 83IAECh. 22 - The photograph was taken after a few drops of a...Ch. 22 - Prob. 85IAECh. 22 - Prob. 86IAECh. 22 - Prob. 87IAECh. 22 - Despite the fact that it has the higher molecular...Ch. 22 - The text mentions that ammonium perchlorate is an...Ch. 22 - Prob. 90IAECh. 22 - Prob. 91IAECh. 22 - Prob. 92IAECh. 22 - Refer to Figure 11-25 to arrange the following...Ch. 22 - Prob. 94IAECh. 22 - Prob. 95IAECh. 22 - Estimate the percent dissociation of CI2(g) into...Ch. 22 - Prob. 97IAECh. 22 - The structure of N(SiH2)2 involves a planar...Ch. 22 - Prob. 99IAECh. 22 - Refer to the Integrative Example on page 1082....Ch. 22 - The bond energies of CIz and 159kJmol1 are 243 and...Ch. 22 - Prob. 102IAECh. 22 - Prob. 103IAECh. 22 - Prob. 104IAECh. 22 - Prob. 105IAECh. 22 - The heavier halogens (CI, Br, and I) form...Ch. 22 - Prob. 107IAECh. 22 - Chemists have successfully synthesized the ionic...Ch. 22 - Prob. 109IAECh. 22 - Various thermochemical cycles are being explored...Ch. 22 - The decomposition of aqueous hydrogen peroxide is...Ch. 22 - Both in this chapter and in Chapter 19, we have...Ch. 22 - Prob. 113FPCh. 22 - The so-called pyroanions, X2O7n+ , form a series...Ch. 22 - A description of bonding in XeF2 based on the...Ch. 22 - Prob. 116FPCh. 22 - Prob. 117SAECh. 22 - Prob. 118SAECh. 22 - Prob. 119SAECh. 22 - Which of the following can oxidize Br to Br2 in...Ch. 22 - Prob. 121SAECh. 22 - Prob. 122SAECh. 22 - Prob. 123SAECh. 22 - Prob. 124SAECh. 22 - Prob. 125SAECh. 22 - Prob. 126SAECh. 22 - Prob. 127SAECh. 22 - Give a practical laboratory method that you might...Ch. 22 - Prob. 129SAECh. 22 - Prob. 130SAECh. 22 - Prob. 131SAECh. 22 - Prob. 132SAECh. 22 - Prob. 133SAECh. 22 - Prob. 134SAECh. 22 - Prob. 135SAE
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