The complex [ P t ( N H 3 ) 3 C l 3 ] + gives two geometric isomers. The number of geometric isomers expected for this complex ion if it has regular planar hexagonal geometry has to be determined and the isomers have to be drawn. The possibility of planar hexagonal geometry of the complex has to be verified. Concept Introduction: A compound that has same molecular formula but different structural formula is said to exhibit isomerism. Co-ordination compounds exhibit cis-trans isomerism which is a type of geometric isomerism. A cis isomer has two same ligands lying adjacent to each other whereas a trans isomer has two same ligands lying opposite to each other.

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Answer 1

Question

Chapter 22, Problem 22.70QP

Interpretation Introduction

Interpretation:

The complex [Pt(NH3)3Cl3]+ gives two geometric isomers. The number of geometric isomers expected for this complex ion if it has regular planar hexagonal geometry has to be determined and the isomers have to be drawn. The possibility of planar hexagonal geometry of the complex has to be verified.

Concept Introduction:

A compound that has same molecular formula but different structural formula is said to exhibit isomerism. Co-ordination compounds exhibit cis-trans isomerism which is a type of geometric isomerism.

A cis isomer has two same ligands lying adjacent to each other whereas a trans isomer has two same ligands lying opposite to each other.

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Answer 2

Question

Chapter 22, Problem 22.70QP

Interpretation Introduction

Interpretation:

The complex [Pt(NH3)3Cl3]+ gives two geometric isomers. The number of geometric isomers expected for this complex ion if it has regular planar hexagonal geometry has to be determined and the isomers have to be drawn. The possibility of planar hexagonal geometry of the complex has to be verified.

Concept Introduction:

A compound that has same molecular formula but different structural formula is said to exhibit isomerism. Co-ordination compounds exhibit cis-trans isomerism which is a type of geometric isomerism.

A cis isomer has two same ligands lying adjacent to each other whereas a trans isomer has two same ligands lying opposite to each other.

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Answer 3

Question

Chapter 22, Problem 22.70QP

Interpretation Introduction

Interpretation:

The complex [Pt(NH3)3Cl3]+ gives two geometric isomers. The number of geometric isomers expected for this complex ion if it has regular planar hexagonal geometry has to be determined and the isomers have to be drawn. The possibility of planar hexagonal geometry of the complex has to be verified.

Concept Introduction:

A compound that has same molecular formula but different structural formula is said to exhibit isomerism. Co-ordination compounds exhibit cis-trans isomerism which is a type of geometric isomerism.

A cis isomer has two same ligands lying adjacent to each other whereas a trans isomer has two same ligands lying opposite to each other.

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Answer 4

Question

Chapter 22, Problem 22.70QP

Interpretation Introduction

Interpretation:

The complex [Pt(NH3)3Cl3]+ gives two geometric isomers. The number of geometric isomers expected for this complex ion if it has regular planar hexagonal geometry has to be determined and the isomers have to be drawn. The possibility of planar hexagonal geometry of the complex has to be verified.

Concept Introduction:

A compound that has same molecular formula but different structural formula is said to exhibit isomerism. Co-ordination compounds exhibit cis-trans isomerism which is a type of geometric isomerism.

A cis isomer has two same ligands lying adjacent to each other whereas a trans isomer has two same ligands lying opposite to each other.

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Answer 5

Chapter 22, Problem 22.70QP

Interpretation Introduction

Interpretation:

The complex [Pt(NH3)3Cl3]+ gives two geometric isomers. The number of geometric isomers expected for this complex ion if it has regular planar hexagonal geometry has to be determined and the isomers have to be drawn. The possibility of planar hexagonal geometry of the complex has to be verified.

Concept Introduction:

A compound that has same molecular formula but different structural formula is said to exhibit isomerism. Co-ordination compounds exhibit cis-trans isomerism which is a type of geometric isomerism.

A cis isomer has two same ligands lying adjacent to each other whereas a trans isomer has two same ligands lying opposite to each other.

Answer 6

Chapter 22, Problem 22.70QP

Interpretation Introduction

Interpretation:

The complex [Pt(NH3)3Cl3]+ gives two geometric isomers. The number of geometric isomers expected for this complex ion if it has regular planar hexagonal geometry has to be determined and the isomers have to be drawn. The possibility of planar hexagonal geometry of the complex has to be verified.

Concept Introduction:

A compound that has same molecular formula but different structural formula is said to exhibit isomerism. Co-ordination compounds exhibit cis-trans isomerism which is a type of geometric isomerism.

A cis isomer has two same ligands lying adjacent to each other whereas a trans isomer has two same ligands lying opposite to each other.

Answer 7

Chapter 22, Problem 22.70QP

Interpretation Introduction

Interpretation:

The complex [Pt(NH3)3Cl3]+ gives two geometric isomers. The number of geometric isomers expected for this complex ion if it has regular planar hexagonal geometry has to be determined and the isomers have to be drawn. The possibility of planar hexagonal geometry of the complex has to be verified.

Concept Introduction:

A compound that has same molecular formula but different structural formula is said to exhibit isomerism. Co-ordination compounds exhibit cis-trans isomerism which is a type of geometric isomerism.

A cis isomer has two same ligands lying adjacent to each other whereas a trans isomer has two same ligands lying opposite to each other.

Answer 8

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Answer 9

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Answer 10

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Answer 11

Ch. 22.3 - Another complex studied by Werner had a...Ch. 22.4 - Prob. 22.1E Ch. 22.4 - Prob. 22.2E Ch. 22.5 - Prob. 22.2CC Ch. 22.5 - Prob. 22.3E Ch. 22.5 - Prob. 22.4E Ch. 22.5 - Prob. 22.3CC Ch. 22.7 - Prob. 22.5E Ch. 22.7 - Prob. 22.6E Ch. 22.7 - Prob. 22.7E

Solution Summary: The author explains that the complex left has two geometric isomers, and the possibility of planar hexagonal geometry is ruled out.

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Chapter 22 Solutions