Structure of cis-trans isomer of the following complexes has to be drawn. (a) [ C o ( N O 2 ) 4 ( N H 3 ) 2 ] − (b) [ C o ( N H 3 ) 5 ( N O ) 2 ] 2 + (c) [ C o ( N H 3 ) 6 ] 3 + (d) [ C r ( N H 3 ) 5 C l ] 2 + Concept Introduction: A compound that has same molecular formula but different structural formula is said to exhibit isomerism. Co-ordination compounds exhibit cis-trans isomerism which is a type of geometric isomerism. A cis isomer has two same ligands lying adjacent to each other whereas a trans isomer has two same ligands lying opposite to each other.

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Answer 1

Question

Chapter 22, Problem 22.54QP

(a)

Interpretation Introduction

Interpretation:

Structure of cis-trans isomer of the following complexes has to be drawn.

(a) [Co(NO2)4(NH3)2]− (b) [Co(NH3)5(NO)2]2+ (c) [Co(NH3)6]3+ (d) [Cr(NH3)5Cl]2+

Concept Introduction:

A compound that has same molecular formula but different structural formula is said to exhibit isomerism. Co-ordination compounds exhibit cis-trans isomerism which is a type of geometric isomerism.

A cis isomer has two same ligands lying adjacent to each other whereas a trans isomer has two same ligands lying opposite to each other.

(b)

Interpretation Introduction

Interpretation:

Structure of cis-trans isomer of the following complexes has to be drawn.

(a) [Co(NO2)4(NH3)2]− (b) [Co(NH3)5(NO)2]2+ (c) [Co(NH3)6]3+ (d) [Cr(NH3)5Cl]2+

Concept Introduction:

A compound that has same molecular formula but different structural formula is said to exhibit isomerism. Co-ordination compounds exhibit cis-trans isomerism which is a type of geometric isomerism.

A cis isomer has two same ligands lying adjacent to each other whereas a trans isomer has two same ligands lying opposite to each other.

(c)

Interpretation Introduction

Interpretation:

Structure of cis-trans isomer of the following complexes has to be drawn.

(a) [Co(NO2)4(NH3)2]− (b) [Co(NH3)5(NO)2]2+ (c) [Co(NH3)6]3+ (d) [Cr(NH3)5Cl]2+

Concept Introduction:

A compound that has same molecular formula but different structural formula is said to exhibit isomerism. Co-ordination compounds exhibit cis-trans isomerism which is a type of geometric isomerism.

A cis isomer has two same ligands lying adjacent to each other whereas a trans isomer has two same ligands lying opposite to each other.

(d)

Interpretation Introduction

Interpretation:

Structure of cis-trans isomer of the following complexes has to be drawn.

(a) [Co(NO2)4(NH3)2]− (b) [Co(NH3)5(NO)2]2+ (c) [Co(NH3)6]3+ (d) [Cr(NH3)5Cl]2+

Concept Introduction:

A compound that has same molecular formula but different structural formula is said to exhibit isomerism. Co-ordination compounds exhibit cis-trans isomerism which is a type of geometric isomerism.

A cis isomer has two same ligands lying adjacent to each other whereas a trans isomer has two same ligands lying opposite to each other.

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For each reaction below, decide if the first stable organic product that forms in solution will create a new CC bond, and check the appropriate box. Next, for each reaction to which you answered "Yes" to in the table, draw this product in the drawing area below. Note for advanced students: for this problem, don't worry if you think this product will continue to react under the current conditions - just focus on the first stable product you expect to form in solution. ? NH2 MgBr Will the first product that forms in this reaction create a new CC bond? ○ Yes ○ No MgBr ? Will the first product that forms in this reaction create a new CC bond? O Yes O No Click and drag to start drawing a structure. :☐ G x c olo Ar HE

Predicting As the lead product manager at OrganometALEKS Industries, you are trying to decide if the following reaction will make a molecule with a new C - C bond as its major product: H₂N O H 1. ? 2. H3O+ If this reaction will work, draw the major organic product or products you would expect in the drawing area below. If there's more than one major product, you can draw them in any arrangement you like. Be sure you use wedge and dash bonds if necessary, for example to distinguish between major products with different stereochemistry. 0 If the major products of this reaction won't have a new CC bond, just check the box under the drawing area and leave it blank. فا Explanation Check Click and drag to start drawing a structure.

Highlight the chirality (or stereogenic) center(s) in the given compound. A compound may have one or more stereogenic centers. OH OH OH OH OH OH

Answer 2

Question

Chapter 22, Problem 22.54QP

(a)

Interpretation Introduction

Interpretation:

Structure of cis-trans isomer of the following complexes has to be drawn.

(a) [Co(NO2)4(NH3)2]− (b) [Co(NH3)5(NO)2]2+ (c) [Co(NH3)6]3+ (d) [Cr(NH3)5Cl]2+

Concept Introduction:

A compound that has same molecular formula but different structural formula is said to exhibit isomerism. Co-ordination compounds exhibit cis-trans isomerism which is a type of geometric isomerism.

A cis isomer has two same ligands lying adjacent to each other whereas a trans isomer has two same ligands lying opposite to each other.

(b)

Interpretation Introduction

Interpretation:

Structure of cis-trans isomer of the following complexes has to be drawn.

(a) [Co(NO2)4(NH3)2]− (b) [Co(NH3)5(NO)2]2+ (c) [Co(NH3)6]3+ (d) [Cr(NH3)5Cl]2+

Concept Introduction:

A compound that has same molecular formula but different structural formula is said to exhibit isomerism. Co-ordination compounds exhibit cis-trans isomerism which is a type of geometric isomerism.

A cis isomer has two same ligands lying adjacent to each other whereas a trans isomer has two same ligands lying opposite to each other.

(c)

Interpretation Introduction

Interpretation:

Structure of cis-trans isomer of the following complexes has to be drawn.

(a) [Co(NO2)4(NH3)2]− (b) [Co(NH3)5(NO)2]2+ (c) [Co(NH3)6]3+ (d) [Cr(NH3)5Cl]2+

Concept Introduction:

A compound that has same molecular formula but different structural formula is said to exhibit isomerism. Co-ordination compounds exhibit cis-trans isomerism which is a type of geometric isomerism.

A cis isomer has two same ligands lying adjacent to each other whereas a trans isomer has two same ligands lying opposite to each other.

(d)

Interpretation Introduction

Interpretation:

Structure of cis-trans isomer of the following complexes has to be drawn.

(a) [Co(NO2)4(NH3)2]− (b) [Co(NH3)5(NO)2]2+ (c) [Co(NH3)6]3+ (d) [Cr(NH3)5Cl]2+

Concept Introduction:

A compound that has same molecular formula but different structural formula is said to exhibit isomerism. Co-ordination compounds exhibit cis-trans isomerism which is a type of geometric isomerism.

A cis isomer has two same ligands lying adjacent to each other whereas a trans isomer has two same ligands lying opposite to each other.

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Answer 3

Question

Chapter 22, Problem 22.54QP

(a)

Interpretation Introduction

Interpretation:

Structure of cis-trans isomer of the following complexes has to be drawn.

(a) [Co(NO2)4(NH3)2]− (b) [Co(NH3)5(NO)2]2+ (c) [Co(NH3)6]3+ (d) [Cr(NH3)5Cl]2+

Concept Introduction:

A compound that has same molecular formula but different structural formula is said to exhibit isomerism. Co-ordination compounds exhibit cis-trans isomerism which is a type of geometric isomerism.

A cis isomer has two same ligands lying adjacent to each other whereas a trans isomer has two same ligands lying opposite to each other.

(b)

Interpretation Introduction

Interpretation:

Structure of cis-trans isomer of the following complexes has to be drawn.

(a) [Co(NO2)4(NH3)2]− (b) [Co(NH3)5(NO)2]2+ (c) [Co(NH3)6]3+ (d) [Cr(NH3)5Cl]2+

Concept Introduction:

A compound that has same molecular formula but different structural formula is said to exhibit isomerism. Co-ordination compounds exhibit cis-trans isomerism which is a type of geometric isomerism.

A cis isomer has two same ligands lying adjacent to each other whereas a trans isomer has two same ligands lying opposite to each other.

(c)

Interpretation Introduction

Interpretation:

Structure of cis-trans isomer of the following complexes has to be drawn.

(a) [Co(NO2)4(NH3)2]− (b) [Co(NH3)5(NO)2]2+ (c) [Co(NH3)6]3+ (d) [Cr(NH3)5Cl]2+

Concept Introduction:

A compound that has same molecular formula but different structural formula is said to exhibit isomerism. Co-ordination compounds exhibit cis-trans isomerism which is a type of geometric isomerism.

A cis isomer has two same ligands lying adjacent to each other whereas a trans isomer has two same ligands lying opposite to each other.

(d)

Interpretation Introduction

Interpretation:

Structure of cis-trans isomer of the following complexes has to be drawn.

(a) [Co(NO2)4(NH3)2]− (b) [Co(NH3)5(NO)2]2+ (c) [Co(NH3)6]3+ (d) [Cr(NH3)5Cl]2+

Concept Introduction:

A compound that has same molecular formula but different structural formula is said to exhibit isomerism. Co-ordination compounds exhibit cis-trans isomerism which is a type of geometric isomerism.

A cis isomer has two same ligands lying adjacent to each other whereas a trans isomer has two same ligands lying opposite to each other.

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Answer 4

Question

Chapter 22, Problem 22.54QP

(a)

Interpretation Introduction

Interpretation:

Structure of cis-trans isomer of the following complexes has to be drawn.

(a) [Co(NO2)4(NH3)2]− (b) [Co(NH3)5(NO)2]2+ (c) [Co(NH3)6]3+ (d) [Cr(NH3)5Cl]2+

Concept Introduction:

A compound that has same molecular formula but different structural formula is said to exhibit isomerism. Co-ordination compounds exhibit cis-trans isomerism which is a type of geometric isomerism.

A cis isomer has two same ligands lying adjacent to each other whereas a trans isomer has two same ligands lying opposite to each other.

(b)

Interpretation Introduction

Interpretation:

Structure of cis-trans isomer of the following complexes has to be drawn.

(a) [Co(NO2)4(NH3)2]− (b) [Co(NH3)5(NO)2]2+ (c) [Co(NH3)6]3+ (d) [Cr(NH3)5Cl]2+

Concept Introduction:

A compound that has same molecular formula but different structural formula is said to exhibit isomerism. Co-ordination compounds exhibit cis-trans isomerism which is a type of geometric isomerism.

A cis isomer has two same ligands lying adjacent to each other whereas a trans isomer has two same ligands lying opposite to each other.

(c)

Interpretation Introduction

Interpretation:

Structure of cis-trans isomer of the following complexes has to be drawn.

(a) [Co(NO2)4(NH3)2]− (b) [Co(NH3)5(NO)2]2+ (c) [Co(NH3)6]3+ (d) [Cr(NH3)5Cl]2+

Concept Introduction:

A compound that has same molecular formula but different structural formula is said to exhibit isomerism. Co-ordination compounds exhibit cis-trans isomerism which is a type of geometric isomerism.

A cis isomer has two same ligands lying adjacent to each other whereas a trans isomer has two same ligands lying opposite to each other.

(d)

Interpretation Introduction

Interpretation:

Structure of cis-trans isomer of the following complexes has to be drawn.

(a) [Co(NO2)4(NH3)2]− (b) [Co(NH3)5(NO)2]2+ (c) [Co(NH3)6]3+ (d) [Cr(NH3)5Cl]2+

Concept Introduction:

A compound that has same molecular formula but different structural formula is said to exhibit isomerism. Co-ordination compounds exhibit cis-trans isomerism which is a type of geometric isomerism.

A cis isomer has two same ligands lying adjacent to each other whereas a trans isomer has two same ligands lying opposite to each other.

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See solution

Answer 5

Chapter 22, Problem 22.54QP

(a)

Interpretation Introduction

Interpretation:

Structure of cis-trans isomer of the following complexes has to be drawn.

(a) [Co(NO2)4(NH3)2]− (b) [Co(NH3)5(NO)2]2+ (c) [Co(NH3)6]3+ (d) [Cr(NH3)5Cl]2+

Concept Introduction:

A compound that has same molecular formula but different structural formula is said to exhibit isomerism. Co-ordination compounds exhibit cis-trans isomerism which is a type of geometric isomerism.

A cis isomer has two same ligands lying adjacent to each other whereas a trans isomer has two same ligands lying opposite to each other.

(b)

Interpretation Introduction

Interpretation:

Structure of cis-trans isomer of the following complexes has to be drawn.

(a) [Co(NO2)4(NH3)2]− (b) [Co(NH3)5(NO)2]2+ (c) [Co(NH3)6]3+ (d) [Cr(NH3)5Cl]2+

Concept Introduction:

A compound that has same molecular formula but different structural formula is said to exhibit isomerism. Co-ordination compounds exhibit cis-trans isomerism which is a type of geometric isomerism.

A cis isomer has two same ligands lying adjacent to each other whereas a trans isomer has two same ligands lying opposite to each other.

(c)

Interpretation Introduction

Interpretation:

Structure of cis-trans isomer of the following complexes has to be drawn.

(a) [Co(NO2)4(NH3)2]− (b) [Co(NH3)5(NO)2]2+ (c) [Co(NH3)6]3+ (d) [Cr(NH3)5Cl]2+

Concept Introduction:

A compound that has same molecular formula but different structural formula is said to exhibit isomerism. Co-ordination compounds exhibit cis-trans isomerism which is a type of geometric isomerism.

A cis isomer has two same ligands lying adjacent to each other whereas a trans isomer has two same ligands lying opposite to each other.

(d)

Interpretation Introduction

Interpretation:

Structure of cis-trans isomer of the following complexes has to be drawn.

(a) [Co(NO2)4(NH3)2]− (b) [Co(NH3)5(NO)2]2+ (c) [Co(NH3)6]3+ (d) [Cr(NH3)5Cl]2+

Concept Introduction:

A compound that has same molecular formula but different structural formula is said to exhibit isomerism. Co-ordination compounds exhibit cis-trans isomerism which is a type of geometric isomerism.

A cis isomer has two same ligands lying adjacent to each other whereas a trans isomer has two same ligands lying opposite to each other.

Answer 6

Chapter 22, Problem 22.54QP

(a)

Interpretation Introduction

Interpretation:

Structure of cis-trans isomer of the following complexes has to be drawn.

(a) [Co(NO2)4(NH3)2]− (b) [Co(NH3)5(NO)2]2+ (c) [Co(NH3)6]3+ (d) [Cr(NH3)5Cl]2+

Concept Introduction:

A compound that has same molecular formula but different structural formula is said to exhibit isomerism. Co-ordination compounds exhibit cis-trans isomerism which is a type of geometric isomerism.

A cis isomer has two same ligands lying adjacent to each other whereas a trans isomer has two same ligands lying opposite to each other.

Answer 7

Chapter 22, Problem 22.54QP

(a)

Interpretation Introduction

Interpretation:

Structure of cis-trans isomer of the following complexes has to be drawn.

(a) [Co(NO2)4(NH3)2]− (b) [Co(NH3)5(NO)2]2+ (c) [Co(NH3)6]3+ (d) [Cr(NH3)5Cl]2+

Concept Introduction:

A compound that has same molecular formula but different structural formula is said to exhibit isomerism. Co-ordination compounds exhibit cis-trans isomerism which is a type of geometric isomerism.

A cis isomer has two same ligands lying adjacent to each other whereas a trans isomer has two same ligands lying opposite to each other.

Answer 8

(b)

Interpretation Introduction

Interpretation:

Structure of cis-trans isomer of the following complexes has to be drawn.

(a) [Co(NO2)4(NH3)2]− (b) [Co(NH3)5(NO)2]2+ (c) [Co(NH3)6]3+ (d) [Cr(NH3)5Cl]2+

Concept Introduction:

A compound that has same molecular formula but different structural formula is said to exhibit isomerism. Co-ordination compounds exhibit cis-trans isomerism which is a type of geometric isomerism.

A cis isomer has two same ligands lying adjacent to each other whereas a trans isomer has two same ligands lying opposite to each other.

Answer 9

(b)

Interpretation Introduction

Interpretation:

Structure of cis-trans isomer of the following complexes has to be drawn.

(a) [Co(NO2)4(NH3)2]− (b) [Co(NH3)5(NO)2]2+ (c) [Co(NH3)6]3+ (d) [Cr(NH3)5Cl]2+

Concept Introduction:

A compound that has same molecular formula but different structural formula is said to exhibit isomerism. Co-ordination compounds exhibit cis-trans isomerism which is a type of geometric isomerism.

A cis isomer has two same ligands lying adjacent to each other whereas a trans isomer has two same ligands lying opposite to each other.

Answer 10

(c)

Interpretation Introduction

Interpretation:

Structure of cis-trans isomer of the following complexes has to be drawn.

(a) [Co(NO2)4(NH3)2]− (b) [Co(NH3)5(NO)2]2+ (c) [Co(NH3)6]3+ (d) [Cr(NH3)5Cl]2+

Concept Introduction:

A compound that has same molecular formula but different structural formula is said to exhibit isomerism. Co-ordination compounds exhibit cis-trans isomerism which is a type of geometric isomerism.

A cis isomer has two same ligands lying adjacent to each other whereas a trans isomer has two same ligands lying opposite to each other.

Answer 11

(c)

Interpretation Introduction

Interpretation:

Structure of cis-trans isomer of the following complexes has to be drawn.

(a) [Co(NO2)4(NH3)2]− (b) [Co(NH3)5(NO)2]2+ (c) [Co(NH3)6]3+ (d) [Cr(NH3)5Cl]2+

Concept Introduction:

A compound that has same molecular formula but different structural formula is said to exhibit isomerism. Co-ordination compounds exhibit cis-trans isomerism which is a type of geometric isomerism.

A cis isomer has two same ligands lying adjacent to each other whereas a trans isomer has two same ligands lying opposite to each other.

Answer 12

(d)

Interpretation Introduction

Interpretation:

Structure of cis-trans isomer of the following complexes has to be drawn.

(a) [Co(NO2)4(NH3)2]− (b) [Co(NH3)5(NO)2]2+ (c) [Co(NH3)6]3+ (d) [Cr(NH3)5Cl]2+

Concept Introduction:

A compound that has same molecular formula but different structural formula is said to exhibit isomerism. Co-ordination compounds exhibit cis-trans isomerism which is a type of geometric isomerism.

A cis isomer has two same ligands lying adjacent to each other whereas a trans isomer has two same ligands lying opposite to each other.

Answer 13

(d)

Interpretation Introduction

Interpretation:

Structure of cis-trans isomer of the following complexes has to be drawn.

(a) [Co(NO2)4(NH3)2]− (b) [Co(NH3)5(NO)2]2+ (c) [Co(NH3)6]3+ (d) [Cr(NH3)5Cl]2+

Concept Introduction:

A compound that has same molecular formula but different structural formula is said to exhibit isomerism. Co-ordination compounds exhibit cis-trans isomerism which is a type of geometric isomerism.

A cis isomer has two same ligands lying adjacent to each other whereas a trans isomer has two same ligands lying opposite to each other.

Answer 14

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Answer 15

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Answer 16

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Answer 17

Ch. 22.3 - Another complex studied by Werner had a...Ch. 22.4 - Prob. 22.1E Ch. 22.4 - Prob. 22.2E Ch. 22.5 - Prob. 22.2CC Ch. 22.5 - Prob. 22.3E Ch. 22.5 - Prob. 22.4E Ch. 22.5 - Prob. 22.3CC Ch. 22.7 - Prob. 22.5E Ch. 22.7 - Prob. 22.6E Ch. 22.7 - Prob. 22.7E

Solution Summary: The author explains the structure of cis-trans isomer of the following complexes.

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Chapter 22 Solutions