Chemistry
13th Edition
ISBN: 9781260162370
Author: Chang
Publisher: MCG
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Textbook Question
Chapter 22, Problem 22.42QP
Write a balanced equation for the formation of urea, (NH2)2CO, from carbon dioxide and ammonia. Should the reaction be run at high or low pressure to maximize the yield?
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Solution
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Use retrosynthetic analysis to suggest two paths to synthesize 2-methyl-3-hexanol using the Grignard reaction. (Click and drag
the appropriate image to the correct position in the reactions.)
Route 1
Aldehyde 1
or
+98
Aldehyde 2
Route 2
Q6
+100
Solved in 1 attempt
Q7
+95
Solved in 2 attempts
Q8
+98
Unlimited attempts
possible
+
+
Grignard 1
OH
H3O+
Grignard 2
Answer Bank
Q9
+90
MgBr
Unlimited attempts
possible
CH3CH2CH2MgBr
Q10
Unlimited attempts
Q11
?
?
+100
in 1 attempt
2-methyl-3-hexanol
CH3CH2MgBr
H
H
о
H
Attempt 3
2) (4 pt) After the reaction was completed, the student collected the following data. Crude
product data is the data collected after the reaction is finished, but before the product
is purified. "Pure" product data is the data collected after attempted purification using
recrystallization.
Student B's data:
Crude product data
"Pure"
product data
after
recrystallization
Crude mass: 0.93 g grey solid
Crude mp: 96-106 °C
Crude % yield:
Pure mass: 0.39 g white solid
Pure mp: 111-113 °C
Pure % yield:
a) Calculate the crude and pure percent yields for the student's reaction.
b) Summarize what is indicated by the crude and pure melting points.
Don't used hand raiting
Chapter 22 Solutions
Chemistry
Ch. 22 - Prob. 22.1QPCh. 22 - Prob. 22.2QPCh. 22 - Prob. 22.3QPCh. 22 - Carbon is usually classified as a nonmetal....Ch. 22 - Prob. 22.5QPCh. 22 - Describe two laboratory and two industrial...Ch. 22 - Prob. 22.7QPCh. 22 - Prob. 22.8QPCh. 22 - Prob. 22.9QPCh. 22 - Describe what is meant by the hydrogen economy.
Ch. 22 - Elements number 17 and 20 form compounds with...Ch. 22 - Give an example of hydrogen as (a) an oxidizing...Ch. 22 - Prob. 22.13QPCh. 22 - Prob. 22.14QPCh. 22 - Prob. 22.15QPCh. 22 - Prob. 22.16QPCh. 22 - Prob. 22.17QPCh. 22 - Starting with H2, describe how you would prepare...Ch. 22 - Give an example of a carbide and a cyanide.Ch. 22 - How are cyanide ions used in metallurgy?Ch. 22 - Briefly discuss the preparation and properties of...Ch. 22 - Prob. 22.22QPCh. 22 - Prob. 22.23QPCh. 22 - Describe two chemical differences between CO and...Ch. 22 - Describe the reaction between CO2 and OH in terms...Ch. 22 - Prob. 22.26QPCh. 22 - Prob. 22.27QPCh. 22 - Prob. 22.28QPCh. 22 - Prob. 22.29QPCh. 22 - Magnesium chloride is dissolved in a solution...Ch. 22 - Prob. 22.31QPCh. 22 - Prob. 22.32QPCh. 22 - A piece of red-hot magnesium ribbon will continue...Ch. 22 - Prob. 22.34QPCh. 22 - Describe a laboratory and an industrial...Ch. 22 - Prob. 22.36QPCh. 22 - Prob. 22.37QPCh. 22 - Prob. 22.38QPCh. 22 - Prob. 22.39QPCh. 22 - Prob. 22.40QPCh. 22 - Prob. 22.41QPCh. 22 - Write a balanced equation for the formation of...Ch. 22 - Prob. 22.43QPCh. 22 - At 620 K the vapor density of ammonium chloride...Ch. 22 - Prob. 22.45QPCh. 22 - Prob. 22.46QPCh. 22 - Write a balanced equation for each of the...Ch. 22 - Prob. 22.48QPCh. 22 - Prob. 22.49QPCh. 22 - Predict the geometry of nitrous oxide, N2O, by the...Ch. 22 - Consider the reaction N2(g)+O2(g)2NO(g) Given that...Ch. 22 - From the data in Appendix 2, calculate H for the...Ch. 22 - Prob. 22.53QPCh. 22 - Prob. 22.54QPCh. 22 - Prob. 22.55QPCh. 22 - Prob. 22.56QPCh. 22 - Prob. 22.57QPCh. 22 - Prob. 22.58QPCh. 22 - Describe one industrial and one laboratory...Ch. 22 - Prob. 22.60QPCh. 22 - Prob. 22.61QPCh. 22 - Prob. 22.62QPCh. 22 - Describe the contact process for the production of...Ch. 22 - Prob. 22.64QPCh. 22 - Prob. 22.65QPCh. 22 - One of the steps involved in the depletion of...Ch. 22 - Hydrogen peroxide is unstable and decomposes...Ch. 22 - What are the oxidation numbers of O and F in HFO?Ch. 22 - Prob. 22.69QPCh. 22 - In 2008, about 48 million tons of sulfuric acid...Ch. 22 - Prob. 22.71QPCh. 22 - Prob. 22.72QPCh. 22 - Prob. 22.73QPCh. 22 - Prob. 22.74QPCh. 22 - Prob. 22.75QPCh. 22 - Prob. 22.76QPCh. 22 - Describe two reactions in which sulfuric acid acts...Ch. 22 - Prob. 22.78QPCh. 22 - Prob. 22.79QPCh. 22 - Prob. 22.80QPCh. 22 - Prob. 22.81QPCh. 22 - Prob. 22.82QPCh. 22 - Prob. 22.83QPCh. 22 - Prob. 22.84QPCh. 22 - Prob. 22.85QPCh. 22 - Hydrogen fluoride can be prepared by the action of...Ch. 22 - Prob. 22.87QPCh. 22 - Prob. 22.88QPCh. 22 - Use the VSEPR method to predict the geometries of...Ch. 22 - Iodine pentoxide, I2O5, is sometimes used to...Ch. 22 - Prob. 22.91QPCh. 22 - Prob. 22.92QPCh. 22 - Prob. 22.93QPCh. 22 - What is the change in oxidation number for the...Ch. 22 - Prob. 22.95QPCh. 22 - Prob. 22.96QPCh. 22 - Prob. 22.97QPCh. 22 - Consider the Frasch process. (a) How is it...Ch. 22 - Predict the physical and chemical properties of...Ch. 22 - Prob. 22.100QPCh. 22 - Prob. 22.101QPCh. 22 - Life evolves to adapt to its environment. In this...Ch. 22 - Prob. 22.103QPCh. 22 - As we saw in Section 21.2, the reduction of iron...Ch. 22 - Assuming ideal behavior, calculate the density of...Ch. 22 - A 10.0-g sample of white phosphorus was burned in...
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- A DEPT NMR spectrum is shown for a molecule with the molecular formula of C5H12O. Draw the structure that best fits this data. 200 180 160 140 120 100 一盆 00 40 8- 20 ppm 0 Qarrow_forwardDon't used hand raitingarrow_forwardShown below is the major resonance structure for a molecule. Draw the second best resonance structure of the molecule. Include all non-zero formal charges. H. H. +N=C H H H Cl: Click and drag to start drawing a structure. : ? g B S olo Ar B Karrow_forward
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