Chemistry Atoms First, Second Edition
2nd Edition
ISBN: 9781308211657
Author: Burdge
Publisher: McGraw Hill
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Question
Chapter 22, Problem 22.27QP
Interpretation Introduction
Interpretation: The given terms to be explained.
Concept Introduction:
Crystal field theory: Bonding in coordination compounds accounts for the magnetic property and color of the complex ion.
Crystal field theory is explained in terms of electrostatic interaction of between metal ion and ligands.
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a. Determine whether each of the Followery
Molecules
is in
the R- On the y-
Configuration
1-01"/
1-6-4
Br
4
I
el
Br
b. Draw The Fisher projection For all the
Meso compounds that can
exist FOR
The Following molenle
1- Refer to the monosaccharides below to answer each of the following question(s):
CH₂OH
CHO
CH₂OH
CH₂OH
0
H-
OH
0
0
HO-
H
H-
-OH
HO
H
HO H
H OH
HO- H
CH₂OH
H.
OH
HO
H
HO-
H
CH₂OH
CH₂OH
CH3
a. Sorbose
b. Rhamnose
c. Erythrulose
d. Xylulose
Classify each sugar by type; for example, glucose is an aldohexose.
a. Xylulose is ..
b. Erythrulose is .
c. Sorbose is ..
d. Rhamnose is ..
2- Consider the reaction below to answer the following question(s).
CHO
H
OH
CH₂OH
CH₂OH
HO-
H
HO
HO
+
H.
-OH
HO
OH
HO.
H
OH
OH
H
-OH
H
OH
CH₂OH
Q
Z
a.
Refer to Exhibit 25-11. Place a triangle around the anomeric carbon in compound Q.
Compound Z is:
b.
1. the D-anomer.
2. the a-anomer.
3. the ẞ-anomer.
4. the L-anomer.
c. Which anomer is the LEAST stable?
d. Q and Z are cyclic examples of:
a. acetals
b.
hemiacetals
c. alditols
d.
hemialditols
Chapter 22 Solutions
Chemistry Atoms First, Second Edition
Ch. 22.1 - Prob. 22.1WECh. 22.1 - Give oxidation numbers for the metals in (a)...Ch. 22.1 - Prob. 1PPBCh. 22.1 - Prob. 1PPCCh. 22.1 - Write the names of the following coordination...Ch. 22.1 - Give the correct name for (a) [Co(NH3)4Br2]Cl, (b)...Ch. 22.1 - Prob. 2PPBCh. 22.1 - Prob. 2PPCCh. 22.1 - Prob. 22.3WECh. 22.1 - Prob. 3PPA
Ch. 22.1 - Prob. 3PPBCh. 22.1 - Prob. 3PPCCh. 22.1 - Prob. 22.1.1SRCh. 22.1 - Prob. 22.1.2SRCh. 22.1 - Prob. 22.1.3SRCh. 22.1 - Prob. 22.1.4SRCh. 22.3 - Prob. 22.4WECh. 22.3 - Prob. 4PPACh. 22.3 - Prob. 4PPBCh. 22.3 - Prob. 4PPCCh. 22.3 - Prob. 22.3.1SRCh. 22.3 - Prob. 22.3.2SRCh. 22 - What distinguishes a transition metal from a main...Ch. 22 - Prob. 22.2QPCh. 22 - Prob. 22.3QPCh. 22 - Without referring to the text, write the...Ch. 22 - Write the electron configurations of the following...Ch. 22 - Prob. 22.6QPCh. 22 - Prob. 22.7QPCh. 22 - Prob. 22.8QPCh. 22 - Describe the interaction between a donor atom and...Ch. 22 - Prob. 22.10QPCh. 22 - Prob. 22.11QPCh. 22 - Prob. 22.12QPCh. 22 - Prob. 22.13QPCh. 22 - What are the systematic names for the following...Ch. 22 - Prob. 22.15QPCh. 22 - Write the formulas for each of the following ions...Ch. 22 - Prob. 22.17QPCh. 22 - Prob. 22.18QPCh. 22 - Prob. 22.19QPCh. 22 - Prob. 22.20QPCh. 22 - Prob. 22.21QPCh. 22 - Prob. 22.22QPCh. 22 - Prob. 22.23QPCh. 22 - Prob. 22.24QPCh. 22 - Prob. 22.25QPCh. 22 - Briefly describe crystal field theory.Ch. 22 - Prob. 22.27QPCh. 22 - What is the origin of color in a coordination...Ch. 22 - Prob. 22.29QPCh. 22 - Prob. 22.30QPCh. 22 - Prob. 22.31QPCh. 22 - Prob. 22.32QPCh. 22 - The absorption maximum for the complex ion...Ch. 22 - Prob. 22.34QPCh. 22 - Prob. 22.35QPCh. 22 - Prob. 22.36QPCh. 22 - Prob. 22.37QPCh. 22 - Prob. 22.38QPCh. 22 - Prob. 22.39QPCh. 22 - Prob. 22.40QPCh. 22 - The [Fe(CN)6]3 complex is more labile than the...Ch. 22 - Prob. 22.42QPCh. 22 - Prob. 22.43QPCh. 22 - Prob. 22.44QPCh. 22 - Prob. 22.45QPCh. 22 - Prob. 22.46QPCh. 22 - Prob. 22.47QPCh. 22 - Prob. 22.48QPCh. 22 - Prob. 22.49QPCh. 22 - Prob. 22.50QPCh. 22 - Prob. 22.51QPCh. 22 - Prob. 22.52QPCh. 22 - Prob. 22.53QPCh. 22 - Prob. 22.54QPCh. 22 - A student in 1895 prepared three coordination...Ch. 22 - Prob. 22.56QPCh. 22 - Prob. 22.57QPCh. 22 - Prob. 22.58QPCh. 22 - Prob. 22.59QPCh. 22 - Prob. 22.60QPCh. 22 - Prob. 22.61QPCh. 22 - Hydrated Mn2+ ions are practically colorless (see...Ch. 22 - Which of the following hydrated cations are...Ch. 22 - Prob. 22.64QPCh. 22 - Prob. 22.65QPCh. 22 - Prob. 22.66QPCh. 22 - Prob. 22.67QPCh. 22 - Prob. 22.68QPCh. 22 - Prob. 22.69QPCh. 22 - Prob. 22.70QPCh. 22 - Commercial silver-plating operations frequently...Ch. 22 - Prob. 22.72QPCh. 22 - Prob. 22.73QPCh. 22 - Prob. 22.74QPCh. 22 - Prob. 22.75QPCh. 22 - Prob. 22.76QPCh. 22 - Prob. 22.77QPCh. 22 - Prob. 22.78QPCh. 22 - Prob. 22.79QPCh. 22 - Prob. 22.80QP
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