Chemistry: An Atoms-Focused Approach (Second Edition)
2nd Edition
ISBN: 9780393615197
Author: Thomas R. Gilbert, Rein V. Kirss, Natalie Foster, Stacey Lowery Bretz
Publisher: W. W. Norton & Company
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Chapter 22, Problem 22.16QA
Interpretation Introduction
To express:
The given concentrations in parts per billion (ppb).
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Assign all integrated peaks
- Consider the data in the Table below to answer the following questions:
Acidities of Substituted Benzoic and Acetic Acids
pk,s at 25C
Y-CH COOH
Y
Y - CH₂COOH
meta
para
H
4.75
4.19
4.19
2.47
3.64
3.55
3.57
4.09
4.46
CN
OCH 3
A. Draw the structure of the strongest acid in the table above.
B. Explain why cyanoacetic acid and methoxyacetic acid are more acidic than their correspondingly
substituted benzoic acid counterparts.
Draw the curved arrow mechanism for this reaction starting with 2-propanol in sulfuric acid. Show all nonzero formal charges and all
nonbonded electrons in each step. Species not involved in a particular step do not need to be included in that step, and resonance forms
do not need to be shown. Note that the alcohol is in much higher concentration than H₂O in this reaction.
H
Chapter 22 Solutions
Chemistry: An Atoms-Focused Approach (Second Edition)
Ch. 22 - Prob. 22.1VPCh. 22 - Prob. 22.21VPCh. 22 - Prob. 22.31VPCh. 22 - Prob. 22.41VPCh. 22 - Prob. 22.51VPCh. 22 - Prob. 22.61VPCh. 22 - Prob. 22.71VPCh. 22 - Prob. 22.81VPCh. 22 - Prob. 22.91VPCh. 22 - Prob. 22.101VP
Ch. 22 - Prob. 22.11QACh. 22 - Prob. 22.12QACh. 22 - Prob. 22.13QACh. 22 - Prob. 22.14QACh. 22 - Prob. 22.15QACh. 22 - Prob. 22.16QACh. 22 - Prob. 22.17QACh. 22 - Prob. 22.18QACh. 22 - Prob. 22.19QACh. 22 - Prob. 22.20QACh. 22 - Prob. 22.21QACh. 22 - Prob. 22.22QACh. 22 - Prob. 22.23QACh. 22 - Prob. 22.24QACh. 22 - Prob. 22.25QACh. 22 - Prob. 22.26QACh. 22 - Prob. 22.27QACh. 22 - Prob. 22.28QACh. 22 - Prob. 22.29QACh. 22 - Prob. 22.30QACh. 22 - Prob. 22.31QACh. 22 - Prob. 22.32QACh. 22 - Prob. 22.33QACh. 22 - Prob. 22.34QACh. 22 - Prob. 22.35QACh. 22 - Prob. 22.36QACh. 22 - Prob. 22.37QACh. 22 - Prob. 22.38QACh. 22 - Prob. 22.39QACh. 22 - Prob. 22.40QACh. 22 - Prob. 22.41QACh. 22 - Prob. 22.42QACh. 22 - Prob. 22.43QACh. 22 - Prob. 22.44QACh. 22 - Prob. 22.45QACh. 22 - Prob. 22.46QACh. 22 - Prob. 22.47QACh. 22 - Prob. 22.48QACh. 22 - Prob. 22.49QACh. 22 - Prob. 22.50QACh. 22 - Prob. 22.51QACh. 22 - Prob. 22.52QACh. 22 - Prob. 22.53QACh. 22 - Prob. 22.54QACh. 22 - Prob. 22.55QACh. 22 - Prob. 22.56QACh. 22 - Prob. 22.57QACh. 22 - Prob. 22.58QACh. 22 - Prob. 22.59QACh. 22 - Prob. 22.60QACh. 22 - Prob. 22.61QACh. 22 - Prob. 22.62QACh. 22 - Prob. 22.63QACh. 22 - Prob. 22.64QACh. 22 - Prob. 22.65QACh. 22 - Prob. 22.66QACh. 22 - Prob. 22.67QACh. 22 - Prob. 22.68QACh. 22 - Prob. 22.69QACh. 22 - Prob. 22.70QACh. 22 - Prob. 22.71QACh. 22 - Prob. 22.72QACh. 22 - Prob. 22.73QACh. 22 - Prob. 22.74QACh. 22 - Prob. 22.75QACh. 22 - Prob. 22.76QACh. 22 - Prob. 22.77QACh. 22 - Prob. 22.78QACh. 22 - Prob. 22.79QACh. 22 - Prob. 22.80QACh. 22 - Prob. 22.81QACh. 22 - Prob. 22.82QACh. 22 - Prob. 22.83QACh. 22 - Prob. 22.84QACh. 22 - Prob. 22.85QACh. 22 - Prob. 22.86QA
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