(a)
Interpretation: The structures of the final products formed in the following reactions are to be stated.
Concept introduction: Organic compounds are synthesized through organic reactions. The different types of reactions in
To determine: The structure of C5H12.
(a)
Explanation of Solution
Explanation
The structure of C5H12 is shown in Figure 1.
The structure of C5H12 is,
Figure 1
The given reactant is C5H12. As the monochlorination of the given reactant give two pairs of enantiomers. Therefore, the given reactant is 2-methyl-butane which consist of a parent chain of four carbon atoms having methyl group on second carbon whose structure is shown in Figure 1.
(b)
Interpretation: The structures of the final products formed in the following reactions are to be stated.
Concept introduction: Organic compounds are synthesized through organic reactions. The different types of reactions in organic chemistry are elimination reaction, substitution reaction, addition reactions and many more. Addition reactions are takes place when two or more reactants combine to form a single product. Elimination reactions occur when a reactant broke down into two or more products and the substitution reactions takes place by an exchange in the reactants.
To determine: The structure of C4H8.
(b)
Explanation of Solution
Explanation
The structure of C4H8 is shown in Figure 2.
The structure of C4H8 is,
Figure 2
The given reactant reacts with water to form tertiary alcohol as the major product. As tertiary alcohols are formed by the dehydration of
(c)
Interpretation: The structures of the final products formed in the following reactions are to be stated.
Concept introduction: Organic compounds are synthesized through organic reactions. The different types of reactions in organic chemistry are elimination reaction, substitution reaction, addition reactions and many more. Addition reactions are takes place when two or more reactants combine to form a single product. Elimination reactions occur when a reactant broke down into two or more products and the substitution reactions takes place by an exchange in the reactants.
To determine: The two possible structures of C7H12.
(c)
Explanation of Solution
Explanation
The two possible structures of C7H12 are shown in Figure 3.
The two possible structures of C7H12 are,
Figure 3
The given chemical formula is C7H12 and the major product formed in the reaction between C7H12 and hydrochloric acid is 1-chloro-1-methylcyclohexane. As the product contains cyclohexane it shows the presence of cyclohexane in the reactant molecule. The reaction between C7H12 and hydrochloric acid is an electrophilic addition reaction which indicate the reactant should possess double bond. Hence, the possible structures of C7H12 for this reaction are shown in Figure 3.
(d)
Interpretation: The structures of the final products formed in the following reactions are to be stated.
Concept introduction: Organic compounds are synthesized through organic reactions. The different types of reactions in organic chemistry are elimination reaction, substitution reaction, addition reactions and many more. Addition reactions are takes place when two or more reactants combine to form a single product. Elimination reactions occur when a reactant broke down into two or more products and the substitution reactions takes place by an exchange in the reactants.
To determine: The structure of hydrocarbon reacted with H2O.
(d)
Explanation of Solution
Explanation
The structure of hydrocarbon is shown in Figure 4.
The structure of hydrocarbon is,
Figure 4
The given hydrocarbon reacts with water which is further oxidized to give acetone. Therefore, the given hydrocarbon should be alkene which is propene as the major product is 2-propanone. Propene first reacts with water to form isopropyl alcohol which is further oxidized to give acetone as the major product.
(e)
Interpretation: The structures of the final products formed in the following reactions are to be stated.
Concept introduction: Organic compounds are synthesized through organic reactions. The different types of reactions in organic chemistry are elimination reaction, substitution reaction, addition reactions and many more. Addition reactions are takes place when two or more reactants combine to form a single product. Elimination reactions occur when a reactant broke down into two or more products and the substitution reactions takes place by an exchange in the reactants.
To determine: The possible structures for C5H12O.
(e)
Explanation of Solution
Explanation
The first possible structure for C5H12O is shown in Figure 5.
The first possible structure for C5H12O is,
Figure 5
The major product for this reaction is
The second possible structure for C5H12O is shown in Figure 6.
The second possible structure for C5H12O is,
Figure 6
The isomer for the given reactant C5H12O is 3-methylbutanol that is oxidized to give carboxylic acid.
The third possible structure for C5H12O is shown in Figure 7.
The third possible structure for C5H12O is,
Figure 7
The isomer for the given reactant C5H12O is 2-methylbutanol that is oxidized to give carboxylic acid.
The fourth possible structure for C5H12O is shown in Figure 8.
The fourth possible structure for C5H12O is,
Figure 8
The isomer for the given reactant C5H12O is 2,2-dimethylpropanol that is oxidized to give carboxylic acid.
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Chapter 22 Solutions
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